Low temperature sintering behavior of La-Co substituted M-type strontium hexaferrites for use in microwave LTCC technology

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摘要 TheLa-CosubstitutedSr_(1–x)La_xFe_(12–x)Co_xO_(19)(x=0–0.5)ferriteswithappropriateBi_2O_3additivewerepreparedbyconventionalsinteringmethodandmicrowavesinteringmethodatlowsinteringtemperaturescompatiblewithLTCC(lowtemperatureco-firedceramics)systems,andtheirsinteringbehaviorwaschieflyinvestigated,includingthecrystalstructure,saturationmagnetizationMs,magneticanisotropyfieldHa,intrinsiccoercivityHci,andCurietemperatureTC.ExperimentresultsclearlyshowedthatthepureM-typecrystalphasewassuccessfullyobtainedwhentheLa-Cosubstitutionamountxdidnotexceed0.3.However,thesingleM-typephasestructuretransformedtomultiphasestructurewithfurtherincreasedx,wheretheM-typephasecoexistedwiththenon-magneticphasesuchasα-Fe_2O_3phase,La_2O_3phase,andLaCoO_3phase.AppropriateLa-CosubstitutionimprovedtheMs(〉62emu/g),Ha(〉1400kA/m),andHci(〉320kA/m)fortheferriteswithxvaryingfrom0.1to0.3,buttheTCdecreasedwithincreasingsubstitutionamount.Moreover,themicrowavesinteredferritescouldprovidelargerHciandsimilarMscomparedwiththeconventionalsinteredferrites.
机构地区 不详
出版日期 2016年02月12日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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