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Asymmetric catalyzed intramolecular aza-Michael reaction mediated by quinine-derived primary amines

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摘要氨基甲酸酯，硫安类药剂和乙酰胺到的intramolecularorganocatalyticenantioselectiveaza-Michael反应，不饱和的酉同类被开发。这个过程被9-amino-9-deoxy-epi-quinine和diphenyl氢磷酸盐支持与优秀enantioselectivity(92%-97.5%ee)和很好的收益(多达99%)负担得起几综合地有用的五成员、六成员的heterocycles的直接、迅速的合成。

DOI 0dp91y0wj2/1762793

作者 Xian-Dong Zhai;Zhong-Duo Yang;Zhi Luo;Hong-Tao Xu

机构地区不详

出处《中国化学快报：英文版》 2017年8期

关键词不对称催化分子内反应对映选择性合成六元杂环化合物介导

分类 [理学][化学]

出版日期 2017年08月18日（中国期刊网平台首次上网日期，不代表论文的发表时间）

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来源期刊

中国化学快报：英文版

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不对称催化分子内反应对映选择性合成六元杂环化合物介导

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