Ni(OH)2-Ni/C for hydrogen oxidation reaction in alkaline media-中国期刊网

摘要 Thedevelopmentofthehydrogenelectrodeisvitalfortheapplicationofalkalinepolymerelectrolytefuelcells(APEFCs).Inthisstudy,aseriesofNi(OH)2decoratedNi/Ccatalysts(Ni(OH)2-Ni/C)werepreparedbyathree-stepelectrochemicaltreatmentofNi/C.TheexistenceofNi(OH)2wasdemonstratedbyX-rayphotoelectronspectroscopy(XPS),andthesurfacemolarratioofNi(OH)2/Niofthesampleswasestimatedviaanelectrochemicalmethod.TheHORcatalyticactivityofthecatalystswasevaluatedbyarotationdiskelectrode(RDE)method,anda'volcanoplot'wasestablishedbetweentheHORexchangecurrent(j0)andthesurfacemolarratioofNi(OH)2/Ni.Ontopofthe'volcano',thesurfacemolarratioofNi(OH)2/Niis1.1:1,thej0ofwhichwas6.8timesofthatofNi/C.ThestabilityofthesamplestowardHORwasevaluatedtobegood.OurstudyaddedasystematicexperimentalevidencetotheHORresearch,showingthattheHORcatalyticactivityofNicanbedeliberatelycontrolledviadecorationofNi(OH)2,whichmayhelpunderstandingtheHORmechanismonNi.

1WANGWei-ping WANGZhi-fei DINGYan LUGong-xuan. Effect of La on Partial Oxidation of Ethanol to Hydrogen over Ni／Fe Catalysts.化学,2003-02.
2TANG Yougen SHEN Jianbin XU Yijun JIANG Jinzhi. Effects of chemical coating with Ni on electrochemical properties of Mg2Ni hydrogen storage alloys.金属材料,2007-06.
3. 稳定性Ni（OH）2研究进展.无机化工,2001-06.
4Fangfang Zhang;Debi Zhou;Mingda Zhou. Ethanol electrooxidation on Pd/C nanoparticles in alkaline media.物理,2016-01.
5徐甲强;夏同驰;张海林;赵留岸;邢立军. β-Ni（OH）2纳米材料的水热制备及性能研究.电力电子与电力传动,2007-03.
6Chatla Anjaneyulu;Velisoju Vijay Kumar;Suresh K.Bhargava;Akula Venugopal. Characteristics of La-modified Ni-Al2O3 and Ni-SiO2 catalysts for COx-free hydrogen production by catalytic decomposition of methane.物理,2013-06.
7张羊换;赵栋梁;李保卫;郭世海;祁焱;王新林. Influence of rapid quenching on hydrogen storage characteristics of nanocrystalline Mg_2Ni-type alloys.金属材料,2010-08.
8Ying Liang;Mingyue Liu;Jixin Chen;Xiaoxia Liu;Yanchun Zhou. Electrodeposition and Characterization of Ni/TiaSi（Al）C2 Composite Coatings.材料科学与工程,2011-11.
9ZHANG Yanghuan;YANG Tai;CHEN Licui;XU Chao;REN Huiping;ZHAO Dongliang. Eleetroehemieal Hydrogen Storage Performanees of the Si Added La-Mg-Ni-based A2B7-type Electrode Alloys for Ni/MH Battery Application.材料科学与工程,2015-01.
10张胜利;韩周祥. 平均晶粒度对Ni(OH)_2电化学性能的影响.电力电子与电力传动,1999-04.

Ni(OH)2-Ni/C for hydrogen oxidation reaction in alkaline media

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Ni(OH)2-Ni/C for hydrogen oxidation reaction in alkaline media

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