Synthesis and Complexation Properties of Novel Chiral Calix[4]-1,3-aza-crown and Calix[4]arene Hydrazone Derivative

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摘要 Refluxingcalix[4]-1,3-substitutedbenzaldehydederivative(4)withglycinehydrazidederivative,weobtainedanovelcalix[4]arenehydrazonederivative(5)via'1+2'condensationinayieldof78%.Inthereactionofcompound4withL-leucinehydrazidederivativeatroomtemperature,lariatcalix[4]-1,3-aza-crown(6)withchiralaminoacidgroupasbranchedchainwassynthesizedvia'1+1'additioninayieldof70%.Thepreliminaryextractionexperimentssuggestedthathostingcompounds5and6possessedgoodcomplexationabilitiesforα-aminoacids.
机构地区 不详
出版日期 2010年04月14日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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