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95 个结果
  • 简介:Anewfinitedifferencescheme-SCSDschemehasbeenpropsedbasedonCD(CentralDifference)schemeandSUD(Second-orderUpwindDifference)scheme.Itsbasicfeatureiscontrollableconvectivestabilityandalwayssecond-orderaccuracy(Stability-ControllableSecond-orderDifference),IthasbeenproventhatthisSchemeisconvective-StableifthegridPecletnumber|PΔ|≤2/β(0≤β≤1).TheadvantageofthisnewschemehasbeendiscussedbasedonthemodifiedwavenumberanalysisbyusingFouriertransform.Thisschemehasbeenappliedtothe2-Dincompressibleconvective-diffusiveequationand2-DcompressibleEulerequation,andcorrespondingfinitedifferenceequationshavebeenderived.Numericalexamplesof1-DBurgersequationand2-Dtransportequationhavebeenpresentedtoshowitsgoodaccuracyandcontrollableconvectivestability.

  • 标签: 流体动力学 对流稳定性 SCSD 热传导
  • 简介:ALaplacedecompositionalgorithmisadoptedtoinvestigatenumericalsolutionsofaclassofnonlinearpartialdiferentialequationswithnonlineartermofanyorder,utt+auxx+bu+cup+du2p1=0,whichcontainssomeimportantequationsofmathematicalphysics.Threedistinctinitialconditionsareconstructedandgeneralizednumericalsolutionsaretherebyobtained,includingnumericalhyperbolicfunctionsolutionsanddoublyperiodicones.Illustrativefiguresandcomparisonsbetweenthenumericalandexactsolutionswithdiferentvaluesofpareusedtotesttheefciencyoftheproposedmethod,whichshowsgoodresultsareachieved.

  • 标签: 非线性偏微分方程 LAPLACE 非线性项 任意阶 分解法 求解
  • 简介:Thedoubleconstraintequationsintheself-dualgravitationaltheorycontainingthecosmologicaltermarederivedin3+1gravity.Furthermore,inordertodeeplystudytheLorentzianandEuclideanrealityconditionsforthistheory,therelationsbetweenconstraintsarediscussedbyintroducingthedoubleconstantconformaltransformationandthedoublecomplexfunctionmethod.

  • 标签: 引力理论 约束方程 宇宙项 伍形变换
  • 简介:研究了不同风速下激光辐照C/C复合材料的氧化速率,利用温度场计算结果,结合氧气在空气中的传质速率,计算了激光辐照下C/C复合材料氧化放热.结果表明,在亚音速的风速下,氧化对C/C复合材料烧蚀的贡献很小,因此,作为激光防护材料,可以忽略C/C复合材料在激光辐照期间的氧化烧蚀.

  • 标签: 氧化烧蚀 氧化放热 C/C复合材料 风速 激光辐照
  • 简介:Anenvironmentallyfriendlyprecursor,adenosine,hasbeenusedasadualsourceofCandNtosynthesizenitrogen-dopedcarboncatalystwith/withoutFe.Ahydrothermalcarbonizationmethodhasbeenusedandwateristhecarbonizationmedia.Themorphologyofsampleswith/withoutFecomponenthasbeencomparedbyHRTEM,andtheresultshowsthatFecanpromotethegraphitizationofcarbon.Furtherelectro-chemicaltestshowsthattheoxygenreductionreaction(ORR)catalyticactivityofFe-containingsample(C–FeN)ismuchhigherthanthatoftheFe-freesample(C–N).Additionally,theintermediatesofC–FeNformedduringeachsyntheticprocedurehavebeenthoroughlycharacterizedbymultiplemethods,andthefunctionofeachprocedurehasbeendiscussed.TheC–FeNsampleexhibitshighelectro-catalyticstabilityandsuperiorelectro-catalyticactivitytowardORRinalkalinemedia,withitshalf-wavepotential20mVlowerthanthatofcommercialPt/C(40wt%).Itisfurtherincorporatedintoalkalinepolymerelectrolytefuelcell(APEFC)asthecathodematerialandledtoapowerdensityof100mW/cm~2.

  • 标签:
  • 简介:Variousagriculturalcropresiduesincludingcornstover,corncob,andsorghumstalkwithamoisturecontentof75wt%weresubjectedtoalongpretreatment(12-60h)withsupercriticalCO2(scCO2),atlowtemperature(50-80℃)andapressureof17.5-25.0Mpa.Thesugaryieldsfromtheenzymatichydrolysis(EH)ofthepretreatedsampleswereasmuchasthree-tofourfoldgreaterthanthoseaffordedbytherawmaterials.However,whenpretreatmentwasconductedwithinashorttime(e.g.0.5h),aspreviouslyreportedintheliterature,onlyaslightincreaseintheEHsugaryieldswasobserved.TheproposedscCO2pretreatmentmechanismdemonstratedtheroleofmoistureinthesystem.Wetting,softening,andswellingwereobservedtomainlyaffectthelignocellulosewhenasuitableamountofwaterwasadded.Finally,thesampleswereanalysedbyX-raydiffractionandscanningelectronmicroscopy,beforeandafterpretreatment,toinvestigatethechangesinthemicroscopicstructureofthebiomass.

  • 标签: LIGNOCELLULOSE scCO2 PRETREATMENT ENZYMATIC HYDROLYSIS SUGAR
  • 简介:分子的动态模拟被执行在交流上调查事件精力的效果:从C和H的H电影生长原子流动。我们的模拟证明在低事件精力(1eV)的电影生长被H和C原子的吸附统治。在中等事件精力(10和20eV),有在表面吸附的H原子的事件H原子的抽象反应变得重要。在高事件精力(30和40eV),交流:H电影生长是一个二拍子的圆舞过程:一个人是吸附和C原子的浅培植,并且其它是H原子的深培植。[从作者抽象]

  • 标签: 分子动力学模拟 薄膜生长 入射能量 H原子 交流 流量
  • 简介:Anovelgas-phaseelectrocatalyticcellcontainingalow-temperatureprotonexchangemembrane(PEM)wasdevelopedtoelectrochemicallyconvertCO2intoorganiccompounds.TwodifferentCu-basedcathodecatalysts(CuandCu-C)werepreparedbyphysicalvapordepositionmethod(sputtering)andsubsequentlyemployedforthegas-phaseelectroreductionofCO2atdifferenttemperatures(70-90℃).ThepreparedelectrodesCuandCu-CwerecharacterizedbyX-raydiffraction(XRD),X-rayphotoemissionspectroscopy(XPS)andscanningelectronmicroscopy(SEM).Asrevealed,CuispartiallyoxidizedonthesurfaceofthesamplesandtheCuandCu-Ccathodiccatalystswerecomprisedofaporous,continuous,andhomogeneousfilmwithnanocrystallineCuwithagrainsizeof16and8nm,respectively.Theinfluenceoftheappliedcurrentandtemperatureontheelectro-catalyticactivityandselectivityofthesematerialswasinvestigated.Amongthetwoinvestigatedelectrodes,thepureCucatalystfilmshowedthehighestCO2specificelectrocatalyticreductionratesandhigherselectivitytomethanolformationcomparedtotheCu-Celectrode,whichwasattributedtothehigherparticlesizeoftheformerandlowerCuO/Curatio.Theobtainedresultsshowpotentialinterestforthepossibleuseofelectrical「enewableenergyforthetransformationofCO2intovaluableproductsusinglowmetalloadingCubasedelectrodes(0.5mgCucm2)preparedbysputtering.

  • 标签: C02 VALORIZATION ELECTRO-REDUCTION CU catalyst PEM
  • 简介:Carbon-supportedPdnanoparticleswerepreparedbymicrowaveheating-glycolreductionmethod,andcharacterizedbyawidearrayofexperimentaltechniquesincludingX-raydiffractionspectroscopy(XRD)andtransmissionelectronmicroscopy(TEM).TheelectrooxidationbehaviorsofethanolonthePd/Celectrodeinalkalinemediawereinvestigatedusingcyclicvoltammetry(CV),chronoamperometry(CA),electrochemicalimpedancespectroscopy(EIS)andsinglecellperformancemethods.Pd/Celectrodeforethanoloxidationshowedhighelectro-catalyticactivityandlongtermstability.However,itisobservedthatthecurrentdensitydecreaseswiththeincreasingofthepotentialandnegativeimpedancepresentsinthepotentialfrom-0.1to0.1V.Thedecreasingcurrentdensityandthenegativeimpedancecouldbeduetotheadsorbedintermediatesspeciesthatinhibitedthefurtheroxidationofethanol.BasedonthechemicalreactionanalysisandEISspectra,equivalentcircuitsrelatingtovariouspotentialzoneshavebeenobtained.TheseresultsrevealthedynamicadsorptionofintermediatesspeciesonPdsurfaces.Significantly,itisclarifiedthattheadsorptionbehaviorbeginsfromthemaximumcatalysisofelectro-catalysisandendsintheformationofthepalladium(II)oxidelayerontheelectrodesurface.

  • 标签: 纳米颗粒 碱性介质 氧化钯 乙醇 X射线衍射谱 电化学阻抗谱
  • 简介:TheCprogramminglanguageisexpressiveandflexible,butnotsafe;asitsexpressivepowerandflexibilityareobtainedthroughunsafelanguagefeatures,andimproperuseofthesefeaturescanleadtoprogrambugswhosecausesarehardtoidentify.SinceCiswidelyused,anditisimpracticaltorewriteallexistingCprogramsinsafelanguages,sowaysmustbefoundtomakeCprogramssafe.ThispaperdealswiththeunsafefeaturesofCandpresentsasurveyonexistingsolutionstomakeCprogramssafe.Wehavestudiedbinary-levelinstrumentationtools,sourcecheckers,source-levelinstrumentationtoolsandsafedialectsofC,andpresentacomparisonofdifferentsolutions,summarizedthestrengthsandweaknessesofdifferentclassesofsolutions,andshowmeasuresthatcouldpossiblyimprovetheaccuracyoralleviatetheoverheadofexistingsolutions.

  • 标签: C语言 程序设计语言 信息安全 编译工具
  • 简介:Basedonafirstordernonlinearordinarydifferentialequationwithatmostasixth-degreenonlineartermwhichisextendedfromatypeofellipticequation,andbyconvertingitintoanewexpansionform,thispaperproposesanewalgebraicmethodtoconstructexactsolutionsfornonlinearevolutionequations.Beingconciseandstraightforward,themethodisappliedtomodifiedBenjamin-Bona-Mahony(mBBM)model,andsomenewexactsolutionstothesystemareobtained.Thealgorithmisofimportantsignificanceinexploringexactsolutionsforothernonlinearevolutionequations.

  • 标签: 非线性方程式 新扩展方法 mBBM模式 正合解法
  • 简介:ThefirststarsintheearlyUniversewereformedabout400millionyearsafterthebigbang.VerificationoftheexistenceofthesestarsisimportantforourunderstandingoftheevolutionoftheUniverse[1].IthasbeenpredictedthatforPopulation-IIIstellarproductionyields,theabundancesofodd-Zelementsareremarkablydeficientcomparedtotheiradjacenteven-Zelements[2].Astronomersaresearchingforlong-lived,lowmassstarswiththeuniquenucleosyntheticpatternmatchingthepredictedyields[3].

  • 标签: FIRST DIRECT MEASUREMENT
  • 简介:当用于含能材料的表面涂层时,ParyleneC涂层优良的电绝缘性能,使得涂层后的炸药表面容易产生静电积累,因此可能会降低炸药的静电安全性。通过试验初步考核了ParyleneC涂层后炸药的静电摩擦感度,并与未涂层炸药以及带聚氨酯复合涂层的炸药进行对比。实验简易装置如图1所示。

  • 标签: PARYLENE 表面涂层 静电性能 炸药 电绝缘性能 含能材料