简介:TheeffectofCdionsonsalmonspermDNAwasstudiedbymeansofcirculardichroism(CD),Ramanspectroscopy,X-rayphotoelectronspectroscopy(XPS)andfluorescencespectroscopy.TheCDspectralandfluorescentprobe-acriflavineresultsindicatethattheDNAunderwentaconformationchangeupontheadditionofCdions.XPSandRamanstudiesrevealthatthereexistedinteractionsbetweenCdionsandthephosphategroupsoftheDNA.Inaddition,anewbandappearedat803cm-1intheRamanspectra,whichcanbeattributedtocharacterizing"marker"bandofA-DNA.ItisconcludedthatCdionscanbecoordinatedbythephosphategroupsoftheDNAandinducetheconformationchangesoftheDNAfromB-DNAtoA-DNA.
简介:Naturalfreshwatersurfacecoatings(biofilmsandassociatedminerals),whichweredevelopedintheNanhuLake,Changchun,P.R.China,wereusedasanefficientbiosorbentfortheremovalofCd(Ⅱ)fromaqueoussolutions.ThebatchexperimentswerecarriedouttodeterminetheadsorptionpropertiesofCd(Ⅱ)ontothenaturalsurfacecoatings.TheclassicalLangmuiradsorptionisothermwasappliedtoestimatingtheequilibriumcoefficientsofCd(Ⅱ)adsorbedonthesurfacecoatings.Theresultsshowthatthemaximumadsorptioncapacityofthesurfacecoatingsis434.78μmolCd/m2(beingequalto0.17mmolCd/gofsurfacecoatingsor10.38mmolCd/gFe)andtheCd(Ⅱ)removalfromsolutionmediabythenaturalsurfacecoatingswasshowntobestronglyaffectedbysolutionpHandionstrength.TheresultedinformationalsoindicatesthatthemaximumCdremovalefficiency(CRE)wasdeterminedtobeapproximately90%atinitialCdmassconcentrationof0.1mg/L(theconcentrationlimitofCd(Ⅱ)inwastewatersfordischargeinaquaticmediainChineselegislation),andthekineticadsorptionofCd(Ⅱ)ontothesurfacecoatingsisfastwitharound70%ofthetotaladsorption-takingplacein150mininsolutionunderthecontrolledlaboratoryconditions(mineralsaltssolutionwithdefinedspeciation,ionicstrength0.05mol/L,and25℃).WiththeadvantageofhighCdadsorptioncapacity,thenaturalsurfacecoatingsappeartobeapotentiallyeffectivebiosorbentfortheremovalandrecoveryofCd(Ⅱ)frompollutedwater.
简介:SodiumdithioniteinitiatedsulfinatodehalogenationofBrCF2CF2Risstudied.
简介:新奇分子地印的合成nanofiber被一种简单electrospinning技术准备在哪个polyvinylbutyral(PVB)被选择为矩阵,-cyclodextrin(-CD)作为模板分子被用作功能的单体和naringin(NG)。在由hexamethylenediisocyanate(HMDI)的cross-linked以后,合成nanofiber展出了一个高特定的有约束力的能力。nanofibers的词法结构借助于红外线的光谱(红外)被学习,X光检查衍射(XRD),和扫描电子显微镜学(SEM)。没有形成阶段,CD分子同类地主要在PVBnanofiber以内被散布分开的水晶的总数。与传统的印的CD聚合物相比,有约束力的实验证明分子地印的合成nanofiber为NG显示出特定的有约束力的地点和选择有约束力的能力。没有任何损失,分子地印的nanofiber能在有约束力的能力被使用至少六次。
简介:Bothenantiomersoffluoxetineweresynthesizedinfivestepsfromethylbenzoylacetate(1)usingmicrobial-chemicalapproachwithoverallyieldsof59%and62%respectively.(S)-Enan-tiomercanbeobtainedin>99%e.e.byrestingcellofbaker’syeastandtheRformwasproducedin81%e.e.byimmobilizedGeotrichumsp.G38.
简介:AseriesofdoubleperovskitesRSrMnFeO_6(R=La,Pr,Nd,Sm)wassynthesizedundermildhydrothermalconditions.Crystalgrowthsofthesamplesweresensitivetoalkalinity,temperature,fillingfraction,andcompositionofinitialreactionmixture.ThedesiredseriesofcompoundsbelongstotheclassofAA'BB'O_6perovskiteswitharandomdistributionofMnandFeatomsovertheB-cationsub-lattice.TheirstructuresshowthedistortedorthorhombicsymmetrywithspacegroupPnma.TheshapesandsizesofthecrystalswereanalyzedonaRigakuJSM-6700Fbyscanningelectronmicroscopy.AnalysisdonebyXPS,MssbauerspectroscopyandiodometrictitrationrevealsthatMnandFeionshave+4and+3oxidationstates,respectively.
简介:Bothenantiomersofdenopamineweresynthesizedusingmicrobial-chemicalapproachviabioreductionof1-(acetoxyphenyl)ketone4(R=CH2C1)and5(R=CO2Et)withfungusGeotrichumsp.G38.
简介:Toexaminetheeffectivenessofirondust-zeolitecompositeasanadsorbentfortheremovalofheavymetalionsfromaqueoussolutions,theadsorptionisotherms,thekinetic,thermodynamicandoptimumconditions,suchasinitialconcentration,pH,contacttime,adsorbentdosageandcompetitiveadsorptionconditionsofheavymetalswereinvestigated.ThecharacterizationofthecompositewascharacterizedviaFTIR,SEM,XRFandXRDmethods.Kineticresultsontheremovalofheavymetalionsfromaqueoussolutionshavebeenwelldescribedbythepseudo-second-ordermodel.TheadsorptiondataforCdandNiionswerefittedwellwiththeLangmuirandFretm-dlichisothermmodels,respectively.Themaximumadsorptioncapacitiesofirondust-zeoliteforCdandNiionswereequalto78.125and76.33mg/g,respectively.Thethermodynamicparameterssuchasenthalpy,entropyandfreeenergyofadsorptionofmetalionsweredetermined.Itwasfoundthattheprocessisendothermic,favorableandspontaneous.ThecompetitiveadsorptionabilityofheavymetalionsinthebinarysystemonthecompositeshowedthatCdionshadasynergisticeffectontheadsorotionofNiandNiionshadthenegativeeffectonCdadsorption.
简介:Thenovelcomplex[K(18-C-6)]2[Cd(mnt)2][18-C-6-18-crown-6,nmt=1,2-dicyanoethene-1,2-dithiolate,C2S2-(CN)2^2-]wassynthesizedandcharacterizedbyelementalanalysis,IRspectrumandX-raydiffractionanalysis.Thecomplexdisplaystwo-dimensionalnetworkstructureof[K(18-C-6)]complexsegmentsand[Cd(nmt)2]complexsegmentbridgedbyS-K-S,S-K-NandN-K-Ninteractionsbetweenadjacent[K(18-C-6)]and[Cd(mnt)2]units.
简介:Startedfrom5-hydroxy-2-pentanone,(R)(E)-3,7-dimethyl-2-octene-1,8-dioicacid,callosobruchusicacid,wassynthesizedviafivestepswithD-(-)-camphorsultamasthechiralauxiliary.Itwasofgoodopticalpurityandyield.
简介:(R)-N-乙酰四氢噻唑-2-硫酮-4-羧酸在三乙胺存在下同乙酰氯反应得到光学活性产物(R)-N-乙酰四氢噻唑-2-硫酮-4-羧酸.用半经验的量子化学方法研究反应物及产物的电子结构和反应热焓.