简介:Dithia-monoaza18-Crown-6anditsimmobilizationproduct,silica-bound1,7-dithia-4-aza-10,13,16-trioxa-cyclooctadecaneviaaspacerofthreecarbonatoms,anditsplatinumcomplexhavebeensynthesized.Itisfoundthattheplatinumcomplexisanefficienthydrosilylationcatalystforolefins.TheXPSdataoftheplatinumcomplexarereported.
简介:Thecopolymerizationsofethylenewith10-undecen-1-olhavebeeninvestigatedusingvanadiumprecatalysts,bis(imino)pyrrolylvanadium(III)complexes1-3,2,5-C4H2N(CH=NR)2VCl2(THF)2[R=C6H5(1),2,6-iPr2C6H3(2),C6F5(3)],andtheiminopyrrolylandβ-diketiminateonesforcomparison.Thepolarmonomerwaspretreatedbydiethylaluminiumchloride(presentalsoasthecocatalyst)beforethecopolymerization.ThemonomerreactivityratioswereevaluatedusingtheFineman-Rossmethod.Theligandstructureconsiderablyinfluencedthecatalyticactivityandtolerancetowardsthepolarmonomer,thepolarmonomerincorporationandthemolecularweightsoftheresultantcopolymers.Thebis(imino)pyrrolylvanadiumcomplexesexhibitedpromisingcatalyticperformanceforthecopolymerization,andahighcatalyticactivityupto3.84kg/mmolv·hwithahighcomonomerincorporationof14.0mol%wasachievedbycomplex3undermildconditions.
简介:无论是以前的村民代表大会,还是现在的议事会,其面临的主要问题,都是如何解决决策权的虚设问题高仁天被逼着做了一次"官"。这个已经做了14年司机的邛崃市油榨乡马岩村农民,去年3月底被同组村民推举