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简介:StudiesontheZnO/La0.5Pr0.2Sr0.3MnO3(LPSMO)/SrNb0.002Ti0.998O3(SNTO)heterostructurehavingvaryingthicknessofp-typeLPSMO(100nm—LP1)and(200nm—LP2)manganitearecarriedout.ZnO/LPSMO(n—p)andLPSMO/SNTO(p—n)junctionsofboththeheterostructuresexhibitgoodrectifyingbehaviorinawiderangeoftemperatureandappliedfield.Forwardandreversebiascharacteristicsofboththejunctionsofheterostructuresshowoppositebehavior.Theobservationofnegativemagnetoresistance(MR)at5KandpositiveMRat300K,inboththeheterostructures,hasbeenexplainedinthecontextofinterfaceregioneffectsandfillingofenergybandsofLPSMOmanganite.Further,athightemperature,theheterostructuresexhibitlargetemperature(46%K-1)andfield(40%T-1)sensitivities.Dependenceoftransport,magnetotransport,I—Vandsensingpropertiesoftheheterostructures,onthetemperature,fieldandfilmthicknesseshavebeendiscussedinthiscommunication.
简介:煤苍蝇灰是为精力生产在煤的燃烧期间产生的一个工业副产品。由于增加煤电源的年度消费和煤苍蝇灰的严肃的潜在的环境威胁,关于煤苍蝇灰的利用的研究的可观的数量全球被承担了。玻璃化似乎是为再使用这工业废物的最有希望的选择之一。这篇论文作为原料用煤苍蝇灰给出唯一的高效眼镜陶艺的生产的短概述。对为从煤苍蝇灰和主要水晶阶段,相应性质和那些材料的可能的用法的眼镜陶艺的合成的方法论的详细描述被介绍。调查揭示了那变换的煤苍蝇灰进高效眼镜陶器的材料是一条有希望的新途径改进这个工业副产品的利用。这变换不仅与处理减轻这些问题而且把废物材料变换成高增值可销售的商品。
简介:CONTENTSA.Physicsofmetalandmetallography(1-14)B.Testingandanalysis(1-2)C.Mechanical,physicalandchemicalproperties(1-15)D.Metallurgy(1-16)E.Metalworking(1-7)
简介:CONTENTSA:Physicsofmetalandmetallography(36-46)B:Testingandanalysis(7)C:Mechanical,physicalandchemicalproperties(58-74)D:Metallurgy(46-61)E:Metalworking(31-50)90A0036PlasticDeformationandDislocationStructureInγ′-phaseofaDirectionallySolidifiedNi-baseSuperalloyThedislocationsubstructureofdirectionallysolidifiedRene80
简介:A:Physicsofmetalandmetallography(68-78)B:Testingandanalysis(27-28)C:Mechanical,physicalandchemicalproperties(64-78)D:Metallurgy(111-141)E:Metalworking(50-59)89A0068ObservationofEpitaxialOverlayerofMetalsatAtomicLevelEpitaxialoverlayerofmetalsatatomiclevelhasbeensuccessfully
简介:Thelargesize,crack-freeZr55Cu30Al10Ni5bulkmetallicglass(BMGs)withthediameterof54mmandtheheightof15mmwasbuiltbylasersolidformingadditivemanufacturingtechnology,whosesizeislargerthanthecriticaldiameterbycasting.Themicrostructure,tensileandcompressivedeformationbehaviorsandfracturemorphologyoflasersolidformedZr55Cu30Al10Ni5BMGswereinvestigated.Itisfoundthatthecrystallizationmainlyoccursintheheat-affectedzonesofdepositionlayers,whichconsistofAl5Ni3Zr2,NiZr2,ZrCu,CuZr2phases.Thecontentofamorphousphaseinthedepositisabout63%.Underthecompressiveloading,thedepositpresentsnoplasticitybeforefractureoccurs.Thefractureprocessismainlycontrolledbytheshearstressandthecompressiveshearfractureanglesofabout39.Thecompressivestrengthreaches1452MPa,whichisequivalenttothatofas-CastZr55Cu30Al10Ni5BMGs,andthereexistvein-likepatterns,river-likepatternsandsmoothregionsatthecompressivefractography.Underthetensileloading,thedepositpresentsthebrittlefracturepatternwithoutplasticdeformation.Thefractureprocessexhibitsnormalfracturemodel,andthetensileshearfractureangleofabout90°.Thetensilestrengthisonlyabout609MPa,andthetensilefractographymainlyconsistsofmicro-scaledcoresandvein-likepatterns,dimple-likepatterns,chocolate-likepatternsandsmoothregions.Theresultsfurtherverifiedthefeasibilityandlargepotentialoflaseradditivemanufacturingonfabricationandindustrialapplicationoflarge-scaleBMGsparts.
简介:AdditivelymanufacturedTi-6Al-4Vlatticestructureshavefoundimportantnicheapplications.However,theyoftenshowinsufficientcompressiveductilityorinsufficientstructuralintegrity.Inthisstudy,abatchof45octahedralTi-6Al-4Vlatticestructureswasmanufacturedinthreedifferentstrutdiameters(0.5,1.0,1.5mm)byselectiveelectronbeammelting(SEBM).Theinfluenceofpost-SEBMannealingonthecompressivedeformationcharacteristicsofthelatticestructurewasinvestigated.Theas-builtTi-6AI-4Vlatticesfragmentedwhenthecompressivestrainreached13%-23%dependingonstrutdiameter.Annealingat950℃(Ptransustemperature:995℃)onlyslightlyimprovedthecompressiveductilityofthelatticestructures.However,annealingat1050℃(p-annealing)fundamentallychangedthecompressivedeformationmodeofthelatticestructures.Theresultantcompressivestress-straincurvewasfeaturedbyalongsmoothplateauandnofactureoccurredevenaftersignificantdensificationofthelatticestructurehadtakenplace(>50%ofcompressivestrain).
简介:Thevolatilizationkineticsofantimonytrisulfideinsteamatmospherewasstudiedwiththermogravimetryattemperaturesfrom923to1123K.Atheoreticalmodelwasdevelopedtocalculatetheoverallrateconstantandthemasstransfercoefficientingasphases.Theexperimentalresultsshowthatthevolatilizationrateisenhancedwithincreasingtemperatureandsteamflowrate.Thevolatilizationrateismainlycontrolledbythemasstransportingasphases.Theapparentactivationenergyfortheprocessisfoundtobe59.93kJ/mol.ItisdemonstratedthatSb2S3isdominantlyoxidizedintoSb2O3andH2Sbywatervaporinthevolatilizationprocess.Someantimonymetalisformed.Thereactionmechanismisdiscussedinaccordancewithexperimentaldata.
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简介:Inpursuingexcellentsupercapacitorelectrodes,wedesignedaseriesofM0S2/C0S2compositesconsistingofflower-likedMoS2andoctahedron-shapedCoS2throughafacileone-stephydrothermalmethodandinvestigatedtheelectrochemicalperformanceofthesampleswithvarioushydrothermaltime.Duetothecouplingoftwometalspeciesandabigamountofwell-developedCoS2andMoS2,theresultsindicatedthattheMoS2/CoS2compositeselectrodesexhibitedthebestelectrochemicalperfor-mancewithalargespecificcapacitanceof490F/gat2mV/sor400F/gat10A/gamongallsamplesasthehydrothermaltimereached48h(MCS48).Furthermore,theretentionofMCS48is93.1%after10000cyclesat10A/g,whichmanifeststheexcellentcyclingstability.TheoutstandingelectrochemicalperformanceofMCS48indicatesthatitcouldbeaverypromisingandnovelenergystoragematerialforsupercapacitorsinthefuture.