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29 个结果
  • 简介:Highspinstatesintheodd-oddnucleus124Cshavebeeninvestigatedthroughthefusion-evaporationreaction116Sn(11B,3n)124Cswithabeamenergyof45MeV.Anewrotationalbandisestablishedandassignedasthehigh-kconfigurationofπg9/2[404]9/2+νh11/2[523]7/2.Somestructureslinkingtothisbandhavealsobeenobserved.Accordingtotheresultsoftheexcitationenergysystematics,thelowestlevelofthisbandisassignedas9,andthe8isomerbandheadhasnotbeenobserved.Anotherisomerwithahalflifeof6.3shasalsobeenobservedwithitsnewdecaypathsestablished.Itsexcitationenergyisraisedby79keV,butitsIπisnotchanged.

  • 标签: k结构 电子束能量 熔合蒸发反应 激发能量 高自旋态 系统分类
  • 简介:K3±δC60多晶薄膜进行了同步辐射光电子谱研究。入射光子能量为17-86cV。实验发现K3±δC60光电子谱的HOMO-1,HOMO及LUMO等导出能带的谱峰强度均随入射光子能量的增加而呈现振荡的性质,与纯C60的光电子谱峰随入射光子能量变化的趋势相似。结果C60分子独特的笼状几何结构,认为其电离截面的变化是由于K3±δC60的末态电子在C60分子笼内形成球状驻波引起的。以驻波的边界条件为基础进行理论计算,得到的电离截面极小值对应的光子能量与实验得到的结果符合良好。

  • 标签: K3C60 光电离截面 电子角动量 球状驻波 多晶薄膜 富勒烯
  • 简介:根据K在C60晶体中的扩散系数分析了在C60(111)单晶解理面上制备K3C60单晶膜的实验条件。对制备出的样品进行了角分辨光电子谱研究。结果表明样品确实为K3C60单晶,并首次观察到K3C60的能带色散。

  • 标签: 制备 表征 K3C60 单晶薄膜 角分辨光电子谱 能带色散
  • 简介:本文采用XRD,EXAFS等手段考察Co载量对催化剂结构的影响,并关联其合成醇活性。活性炭担载的硫化态Co-Mo-K样品中,Mo主要以MoS2物种形式存在于活性炭的表面上,而Co在低Co载量时主要形成“Co-Mo-S”相,在高Co负载量时会有部分类Co9S8的物相出现。经Co助剂修饰后的催化剂显示出良好的合成醇催化性能,Co助剂有利于合成C2+醇。Co/Mo原子比为0.5时表面“Co-Mo-S”相可能达到饱和,合成醇的收率也最高。Co物种是和MoS2物相以协同的方式起作用的。

  • 标签: 硫化态 Co-Mo-K/AC 合成 催化剂 EXAFS
  • 简介:AseriesofoxideizedCO-K-Mo/γ-Al2O3catalystsamples,preparedbyimpregnatingoxidizedK-Mo/γ-Al2O3sampleswithanaqueoussolutionofcalculatedCo(NO3)2andthencalcininginairattemperaturesof350℃,500℃65℃and800℃respectively,weresulfidedandtheninvestigatedfortheactivityinthesynthesisofmixedalcoholsfromCOhydrogenationunderconditionsofp=5.0MPa,T=350℃andGHSV=4800h^-1.TheresultsdemonstratethattheadditionofcobaltpromoterisfavorabletotheformationofhigheralcoholsandtheopimumcalcinationtemperaturesafterimpregnatingwithCo^2+areabout500-650℃.ThestructureofCoandMospeciesontheoxidizedandsulfidedsampleswasdeterminedbyX-raydiffraction(XRD),laserRamanspectrum(LRS)andextendedX-rayabsorptionfinestructure(EXAFS).Foroxidizedsamplecalcinedat350℃,cobaltexistsasCo3O4spectiesandcoversthesurfaceofK-Mo-Ospecies,thestructureofK-Mo-OspeciesisthesameasthatinK-Mo/Al2O3sample.TheinteractionbetweencobaltandK-Mo-Ospeciesisrelativelyweak.Aftersulfidation.Cobaltexistsassulfidecrystalliteswithanoctahedralcoordinatedstructure,andmolybdenumasMoS2crystallites.Foroxidizedsamplescalcinedat500-650℃,CocomponentinteractswiththeK-Mo-Ospeciesanddestroysthelong-rangeorderoftheK-Mo-Ospectesgradually,Aftersulfidation.CotendstoexistasasulfidewithtetrahedralcoordinatedstructureandMostillasMoS2crystallites.Foroxidizedsamplecalcinedat800℃,CocomponentexistsmainlyasCoAl2O4species,mostofwhichcannotbesultidedduringsulfidation.

  • 标签: 催化剂 催化活力 混合醇合成
  • 简介:在C60单晶(111)解理面上制备出厚度约30mm的K3C60单晶膜。利用同步辐射光源,在低温下(约150K)测量了样品法向发射的角分辨光电子谱。观察到K3C60导带和价带明显的色散。导带的光电子谱峰可清晰分辨出4个子峰,这些子峰的最大色散超过0.5eV,并且色散曲线与K3C60的一维无序晶体结构模型下的能带理论基本吻合,只是子带间隔差异较大。

  • 标签: K3C60 单晶薄膜 同步辐射 角分辨光电子谱 导带结构 能带理论
  • 简介:Oneofthetechnicalbottlenecksoftraditionallaser-inducedbreakdownspectroscopy(LIBS)isthedifficultyinquantitativedetectioncausedbythematrixeffect.Totroubleshootthisproblem,thispaperinvestigatedacombinationoftime-resolvedLIBSandconvolutionalneuralnetworks(CNNs)toimproveKdeterminationinsoil.Thetime-resolvedLIBScontainedtheinformationofbothwavelengthandtimedimension.Thespectraofwavelengthdimensionshowedthecharacteristicemissionlinesofelements,andthoseoftimedimensionpresentedtheplasmadecaytrend.Theone-dimensionaldataofLIBSintensityfromtheemissionlineat766.49nmwereextractedandcorrelatedwiththeKconcentration,showingapoorcorrelationofR^2c=0.0967,whichiscausedbythematrixeffectofheterogeneoussoil.Forthewavelengthdimension,thetwo-dimensionaldataoftraditionalintegratedLIBSwereextractedandanalyzedbyanartificialneuralnetwork(ANN),showingR^2v=0.6318andtherootmeansquareerrorofvalidation(RMSEV)=0.6234.Forthetimedimension,thetwo-dimensionaldataoftime-decayLIBSwereextractedandanalyzedbyANN,showingR^2v=0.7366andRMSEV=0.7855.Thesehigherdeterminationcoefficientsrevealthatboththenon-KemissionlinesofwavelengthdimensionandthespectraldecayoftimedimensioncouldassistinquantitativedetectionofK.However,duetolimitedcalibrationsamples,thetwo-dimensionalmodelspresentedover-fitting.Thethree-dimensionaldataoftime-resolvedLIBSwereanalyzedbyCNNs,whichextractedandintegratedtheinformationofboththewavelengthandtimedimension,showingtheR^2v=0.9968andRMSEV=0.0785.CNNanalysisoftime-resolvedLIBSiscapableofimprovingthedeterminationofKinsoil.

  • 标签: quantitative DETECTION potassium(K) SOIL TIME-RESOLVED LASER-INDUCED
  • 简介:采用类凝胶法和超界流体干燥技术制得了一组具有不同Co/Mo比的超细非负载型Mo-Co-K催化剂,考察了其合成低碳醇性能,并运用EXAFS技术对还原态催化剂的局域结构进行了研究。结果表明,还原态催化剂中Co以CoMoO4的形式存在,Co的配位数低于标样CoMoO4的配位数,且随着Co/Mo比的减小而减小,由于催化剂中Mo与Co与Co之间的相互作用,使得Co-O键长被不同程度地拉长,研究表明,催化剂中具有低配位Co且较弱的Mo,Co之间相互作用的类CoMoO4结构物相可以促进低碳醇的生成。

  • 标签: 合成 低碳醇 超细Mo-Co-K催化剂 局域结构 EXAFS