简介：Supernova(SN)neutrinosdetectedontheEartharesubjecttotheshockwaveeffects,theMikheyev–Smirnov–Wolfenstein(MSW)effects,theneutrinocollectiveeffectsandtheEarthmattereffects.Consideringtherecentexperimentalresultaboutthelargemixingangleθ13(■8.8°)providedbytheDayaBayCollaborationandapplyingtheavailableknowledgefortheneutrinoconversionprobabilityinthehighresonanceregionofSN,PH,whichisintheformofhypergeometricfunctioninthecaseoflargeθ13,wededucetheexpressionofPHtakingintoaccounttheshockwaveeffects.ItisfoundthatPHisnotzeroinacertainrangeoftimeduetotheshockwaveeffects.Afterconsideringallthefourphysicaleffectsandscanningrelevantparameters,wecalculatetheeventnumbersofSNneutrinosforthe"Garching"distributionofneutrinoenergyspectrum.Fromthenumericalresults,itisfoundthatthebehaviorsofneutrinoeventnumbersdetectedontheEarthdependontheneutrinomasshierarchyandneutrinospectrumparametersincludingthedimensionlesspinchingparameterβα(whereαreferstoneutrinoflavor),theaverageenergy,andtheSNneutrinoluminositiesLα.Finally,wegivetherangesofSNneutrinoeventnumbersthatwillbedetectedattheDayaBayexperiment.

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简介：Thereactionmechanismsofdienepolymerizationwithhomogeneousrareearthcatalystarestudiedbymeansofthespectraof1H-NMR,one-andtwo-dimensions13C-NMR.BasedonthedataofaboveNMRspectra,itisproposedthatthepolymerizationreactionproceedsaccordingtothefollowingmechanism:η4-diene（cis-（?）trans-）andη3-allyl（syn-（?）anti-）.

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简介：Theresearchworkonpreparationprocessofactivematerialsoftherareearthionselectiveelectrodesandthevalenceoftheelectrodemembranewerereported.Theactivematerialswerechacterizedbyinfraredspectrum,elementalanalysisandXPS.Wehadstudiedtherareearthionselectiveelectrodesinwhichtheactivematerialsconsistoffunctionalpolymers.Inthispaper,theresearchworkonpreparationprocessandthevalenceoftheelectrodemembranewerereported,whichhasnotbeenseeninliteratureyet.

简介：Theself-diffusionofEu^3+ioninporousresinsD72andD751wasstudiedbyisotopeexchangereaction.ApplyingKataoka'sbidisperseporemodel,theintraparticleeffectivediffusivityDewereresolvedintoasoliddiffusivityDgandamacroporediffusivityDp.TheexperimentsshowthatDe.DpandDgallincreasewiththeincreaseofreactiontemperature;theresponseDpandDgofD751resinissmallerthanthatofD72resin;thediffusivityofEu^3+ioninsolutionislargerthanDp,whichleadstotheconclusionthatthediffusionofionintheporeofresincannotcompletelybeequaltothatinsolution.

简介：DrivenbycuriosityaboutpossibleflightoptionsfortheChang’e-2spacecraftafteritremainsattheSun-EarthL2point,effectiveapproachesweredevelopedfordesigningpreliminaryfuel-optimalnear-Earthasteroidflybytrajectories.Theapproachesincludetheuseofmodifiedunstablemanifolds,gridsearchofthemanifolds’parameters,andatwo-impulsemaneuverfororbitalphasematchingandz-axisbiaschange,andaredemonstratedtobeeffectiveinasteroidtargetscreeningandtrajectoryoptimization.Asteroidflybysareexpectedtobewithinadistanceof2×107kmfromtheEarthowingtotheconstrainedEarth-spacecraftcommunicationrange.Inthiscase,thespacecraft’sorbitalmotionissignificantlyaffectedbythegravitiesofboththeSunandtheEarth,andtherefore,theconceptofthe"heliocentricoscillating-Keplerorbit"isproposed,becausetheclassicalorbitalelementsoftheflybytrajectoriesreferencedintheheliocentricinertialframeoscillatesignificantlywithrespecttotime.Theanalysisandresultspresentedinthisstudyshowthat,amongtheasteroidswhoseorbitsarethemostaccuratelypredicted,"Toutatis","2005NZ6",or"2010CL19"mightbeencounteredbyChang’e-2inlate2012or2013withtotalimpulseslessthan100m/s.

简介：Thetetravalentmetalsaltsofmonoalkylphosphates[M(R-OPO3)2]areanewkindofstationaryphasesofchromatography-homogeneousbondedphases.Thestudiesonpreparation,structureandgaschromatographicefficiencyofceriumbis(octylphosphate)(COPP)arereportedinthispaper.Byusingchemicalanalysis,infraredspectra,x-raydiffractionanalysis,thestrongevidencethatCOPPhasalayeredstructureoftheα-zirconiumphosphatetypewasdemonstrated,therepetitiveunitisC8H17OPO3CeO3POC8H17andthereisalittlebendingorinterpenetrationofthealkylchainswithinthelayers.ThethermogravimeticanalysisoftheCOPPindicatedthatithasmuchmorethermalstabilitythansilica-basedpackings.ThethermodynamicparametersΔHandmolecularconnectivityindexesx′fortheadsorptionofseveraldozencompoundsontheCOPPhavealsobeendeterminedbygaschromatographicmethod,andthefinelinearitybetweenthemwasshown.

简介：Thecopolymerizationofl-octenewithstyrenecatalyzedbyrareearthcoordinationcatalystshasbeenstudiedforthefirsttime.Somefeaturesandkineticbehavioraredescribed.Theoverallactivationenergyofthecopolymerizationwas22.2KJ/molandthecopolymerizationratecouldbeexpressedasRp=Kp[Nd][M]2.(=1.68×10-3L2/mol2.S,50℃,[Oct]/[St]=1).ThecatalyticactivityofvariousrareearthelementsinLn（naph）3forthecopolymerizationwascomparedandshowsthefollowingsequence:Dy,Y,Yb>Ho>Sm,Gd,Nd>Pr>Ce>La>Tm.Bothmonomersofl-octeneandstyreneinthecopolymerizationbyNd（naph）3-AlEt3havethetendencyofconstantproportioncopolymerization.Thestructureofthecopolymerswasstudiedby1H-NMR.

简介：AnovelSchiffbase(TAMET)wassynthesizedbythecondensationoftetraglycolaldehydewithmethionineandamildoxidantCrO3·(C5H5N)2wasselectedforthereaction.SevennewrareearthcomplexeswiththisSchiffbasehavebeensynthesizedandcharacterizedbyelementalanalysis,TG-DTA,molarconductivity,magneticsusceptibilityandIR,especially1HNMRspectra.Informationwasobtainedfromreflectancespectraandthecoordinationofsulfuratomtorareearthswasdiscussed.TheexperimentalresultsshowthatthesecompoundshavesomebiologicalactivityandcoulddisposeofO2.

简介：稳定的几何学，电子结构，和磁性(8,0)并且(4,4)做与的围单人赛的BNnanotubes(BNNT)稀土元素(RE)原子与密度用第一原则的pseudopotential飞机波浪方法被调查功能的理论(DFT)。结果证明这些RE原子能有效地与有利精力在BNNT被做。因为弯曲效果，为RE-atomdoped(4,4)BNNT的有约束力的精力的价值比一样的原子在上的那些大(8,0)BNNT。在RE-5d，6s，和B-2p之间的电子转移，N-2porbitals也被观察。而且，BNNT的电子结构和磁性能被如此的做修改。结果证明Ce，下午，Sm，和Eu原子的吸附能导致磁化，当当BNNT与La被做时，没有磁力被观察时。这些结果为spintronics应用程序并且为开发磁性的nanostructures是有用的。

简介：Thispaperappliesthestochasticfiniteelementmethodtoanalysethestatisticsofstressesinearthdamsandassessthesafetyandreliabilityofthedams.Formulationsofthestochasticfiniteelementmethodarebrieflyreviewedandtheprocedureforassessingdam’sstrengthandstabilityisdescribed.Asanexample,adetailedanalysisforanactualdam-Nululindamisperformed.Apracticalmethodforstudyingbuilt-damsbasedontheprototypeobservationdataisdescribed.

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简介：Theisothermsforsorptionoffulvicacidfromweatheredcoal,andthedistributionratios,Rd,of^169YbatvariousconcentrationoffulvicacidonNa-bentoniteandNa-Kaolinitehavebeenmeasured.Meantime,thedependencesofRdof^169YbonpHvaluesataconstantinitialconcentrationofFAwereobtained.Itwasnotfoundthattheparallelrelationshipbetweenthehighaffinityofhumicsubstancetotheclayandthehighuptakeofmetalwhichhasstrongabilitytocomplexwiththishumicsubstance.

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简介：ＯｘｉｄａｔｉｖｅＤｅｈｙｄｒｏｇｅｎａｔｉｏｎｏｆＩｓｏｂｕｔａｎｅｔｏＩｓｏｂｕｔｙｌｅｎｅｏｖｅｒＦ￣－ＭｏｄｉｆｉｅｄＲａｒｅＥａｒｔｈＭｅｔａｌＯｘｉｄｅＣａｔａｌｙｓｔｓＺＨＡＮＧＷｅｉ－ｄｅ，ＴＡＮＧＤｉｎｇ－ｌｉａｎｇ，ＬＡＩＷｅｎ－...

简介：Recently,bismuthsulfide(Bi2S3)hasattractedmuchattentioninthethermoelectriccommunityowingtoitsabundance,lowcost,andadvancedproperties.However,itspoorelectricaltransportpropertieshavepreventedBi2S3devicesfromrealizinghighthermoelectricperformance.Inthiswork,ourmotivationistodecreasethelargeelectricalresistivity,whichisrecognizedastheoriginofthelowZTvalueinundopedBi2S3.Wecombinedmeltingandsparkplasmasintering(SPS)inacontinuousfabricationprocesstoproduceBi2S3–xSex(x=0,0.09,0.15,0.21)andBi2S2.85–ySe0.15Cly(y=0.0015,0.0045,0.0075,0.015,0.03)samples.OurresultsshowthatSealloyingatSsitescannarrowthebandgapandactivateintrinsicelectronconduction,leadingtoahighpowerfactorof~2.0μW·cm–1·K–2atroomtemperatureinBi2S2.85S0.15,about100timeshigherthanthatofundopedBi2S3.Moreover,ourfurtherintroductionofClatomsintotheSsitesresultedinasecond-stageoptimizationofcarrierconcentrationandsimultaneouslyreducedthelatticethermalconductivity,whichcontributedtoahighZTvalueof~0.6at723KforBi2S2.835Se0.15Cl0.015.OurresultsindicatethathighthermoelectricperformancecouldberealizedinBi2S3withearth-abundantandlow-costelements.

简介：稀土元素aryloxides由各种各样的烷基组代替了[行(浆)3]例如甲基，isopropyl和tertbutyl，被用作单个部件催化剂影响L减水乳酸(LLA)的戒指洞聚合。催化活动，聚合特征，聚合动力学和机制被学习。稀土元素aryloxides的催化活动被结构和烷基组的数字在苯基戒指上影响，这被发现。越强壮烷基组的电子捐赠能力，催化活动将是越多higher。代用品组的数字的增加将导致一项更高催化的活动。镧tris(2,4,6-tri-tert-butylphenolate)[La(OTTBP)3]在所有镧aryloxides之中展出最高的活动。根据1H-NMR数据，LLA聚合经由包含减水乳酸的酰氧债券的劈开的协作插入机制继续了，这被建议。关键词戒指洞聚合-L减水乳酸-稀土元素aryloxides这个工作被山西省(号码2006011069)的自然科学基础和山西省(号码2009011059-7)的关键实验室的开的基础支持。

简介：Arareearthcoordinationsystemwasfirstinvestigatedasanewtypeofcatalystforthering-openingpolymerizationofα-aminoacidN-carboxyanhydrides（NCAs）.Theresultsforthepolymerizationofγ-stearyl-α,L-glutamate（SLG）NCAusingneodymiumacetylacetonate（Nd（acac）3）-orneodymiumtris（2-ethylhexylphosphonate）(Nd(P204)3)-triethylaluminum-waterascatalystswerecomparedwiththoseusingconventionalcatalysts.Itwasfoundthatthehelicalpoly（γ-stearyl-L-glutamate）withhighmolecularweightaswellasnarrowmolecularweightdistributioncanbeobtainedinthepresenceofNd（acac）3/AlEt3-1/2H2O.ThepolymerobtainedwascharacterizedbyIRandNMRspectroscopy.