简介:氧化铝弥散强化铜合金是国际热核实验堆(ITER)的备选热沉材料之一,氘在其中的渗透滞留行为关系到ITER运行的安全性。通过气体驱动渗透平台测定了实验温度621~803K时氘气在氧化铝弥散强化铜合金中的渗透参数;通过热脱附谱实验平台记录了2种氧化铝弥散强化铜合金以及CuCrZr的热脱附曲线。结果表明:在相同温度区间内,氘气在氧化铝弥散强化铜合金中的渗透系数与纯铜及CuCrZr接近,说明氧化铝弥散相对氘气在氧化铝弥散强化铜合金中的渗透系数基本没有影响,而扩散系数比在纯铜和CuCrZr中都低,且在低温时显著降低;2种氧化铝弥散强化铜合金均有3个脱附峰,而CuCrZr合金只有1个脱附峰。
简介:Theelasticwavepropagationphenomenaintwo-dimensionalperiodicbeamlatticesarestudiedbyusingtheBlochwavetransform.Thenumericalmodelingisappliedtothehexagonalandtherectangularbeamlattices,inwhich,boththein-plane(withrespecttothelatticeplane)andout-of-planewavesareconsidered.ThedispersionrelationsareobtainedbycalculatingtheBlocheigenfrequenciesandeigenmodes.Thefrequencybandgapsareobservedandtheinfluenceoftheelasticandgeometricpropertiesoftheprimitivecellonthebandgapsisstudied.ByanalyzingthephaseandthegroupvelocitiesoftheBlochwavemodes,theanisotropicbehaviorsandthedispersivecharacteristicsofthehexagonalbeamlatticewithrespecttothewavepropagationarehighlightedinhighfrequencydomains.OneimportantresultpresentedhereinisthecomparisonbetweenthefirstBlochwavemodestothemembraneandbending/transverseshearwavemodesoftheclassicalequivalenthomogenizedorthotropicplatemodelofthehexagonalbeamlattice.Itisshownthat,inlowfrequencyranges,thehomogenizedplatemodelcancorrectlyrepresentboththein-planeandout-of-planedynamicbehaviorsofthebeamlattice,itsfrequencyvaliditydomaincanbepreciselyevaluatedthankstotheBlochmodalanalysis.Asanotherimportantandoriginalresult,wehavehighlightedtheexistenceoftheretropropagatingBlochwavemodeswithanegativegroupvelocity,andofthecorresponding'retro-propagating'frequencybands.
简介:Inthispaper,MPt/C(M=La,Nd)catalystsofPEMFCweresynthesizedbymicrowaveradiationprocess.ThecrystallinityandstructureofcatalystswererespectivelyanalyzedbyXRDandnitrogenadsorptiontests.Theactivityofcatalystswasinvestigatedbyelectrochemistryexperiment.Theresultsshowedthat:1)comparedwithPt/Ccatalystpreparedbytypicalimpregnation-reductionprocess,thesizeofMPt/CcatalystparticledecreasedandtheavailablecrystalforO2reductionincreased;2)theMPt/CcatalystshadrelativelyhighBETsurfaceareas;and3)thesecrystaltransformationsoftheMPt/Ccatalystbroughthightheelectrocatalyticactivity,andasaresult,improvedthepowerofPEMFC.
简介:TheNd2O3nanoparticleswhichmodifiedbyAOTwaspreparedusingmicrioemulsionmethodinthesystemofwater/xylene.L3edgeXAFSwasusedtodeterminethedifferenceofthelocalstructurearundNd^3+ionandtheelectricalstructurebetweenthenanocystallineNd2O3andthecoarsebulkmicrocrystallineNd2O3.ItwasfoundthatNd-Odistanceincreasedwiththeformofnanocrystalliteandtheintensityofabsorptionedgealsoenhancedatthesametime.
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简介:ThisworkdemonstratestheNd:YAGwaveguidelaserasanefficientplatformforthebio-sensingofdextrosesolutionsandtumorcells.ThewaveguidewasfabricatedinanNd:YAGcrystalwiththecooperationofultrafastlaserwritingandionirradiation.ThelaseroscillationintheNd:YAGwaveguideisultrasensitivetotheexternalenvironmentofthewaveguide.Evenaweakdisturbanceleadstoalargevariationoftheoutputpowerofthelaser.Accordingtothisfeature,anNd:YAGwaveguidecoatedwithgrapheneandWSe2layersisusedassubstrateforthemicrofluidicchannel.WhenthemicroflowcrossestheNd:YAGwaveguide,thelaseroscillationinthewaveguideisdisturbedandinducesfluctuationoftheoutputlaser.Accordingtothefluctuation,themicroflowisdetectedwithasensitivityof10mW/RIU.
简介:UltrasonicvelocitieshavebeenmeasuredinsinglephaseBi1.7Pb0.3Sr2CaCu2O8+xandBi1.7Pb0.3Sr2Ca2O10+xpolycrystallinesamples.Anomalouschangesofbothlongitudinalandtransversevelocitieswereobservednear200K,whichindicatesthatsomestructuralphasetransitiomightoccur.Theelasticconstantsofthesesampleshavebeendeterminedfromthemeasuredultrasonicvelocitydata,whicharemuchsmallerthanthoseofYBa2Cu3O7-yandBaTiO3,manifestingthattheinterlayercoup-lingwilldramaticallydecreasewhenthec-axesoftheunitcellsoftheseperovstite-likemultilayerceramicsincrease.ThevaluesofPoissonratio,however,ofthoseceramicsareveryclose,implyingsimilarinteratomicbondingforces.Correctedtovoid-freestate,theDebyetemperatureofthesematerialsisestirnatedas270±20k.ThetemperaturedependenceofDebyetemperaturesforthesematerialsisalsocalculatedbyusingthesamemethodandreportedforthefirsttime.