简介:本文从观测常规产品Ni70Mn25Co5触媒合金片的表面缺陷入手,讨论了触媒片表观质量对金刚石合成效果的影响,从而也为触媒产品质量标准的制定提供了某些参考依据。
简介:TheballmillingofFe-24MnandFe-24Mn-6Simixedpowdershasbeenperformedbythehighenergyballmillingtechnique.ByemployingX-raydiffractionandMoessbauermeasurements.Theccmpositionevolutionduringthemillingprocesshasbeeninvestigated.TheresultsindicatetheformationofparamagneticFe-MnorFe-Mn-Sialloyswithametastablefccphaseasfinalproducts.whichimplythattheFeandMnproceedaco-diffusionmeenanismthroughthesurfaceoffragmentedpowders.Thethermalstabilityandcompositionevolutionoftheas-milledalloyswerediscussedcomparingwiththebulkalloy,.
简介:LayeredcathodematerialLiCo1/3Ni1/3Mn1/3O2wassynthesizedbyPechiniprocess,andinvestigatedusingX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andgalvanostaticcharge/dischargecycling.Thesampleiswell-crystallizedandhasaphase-purea-NaFeO2structure.Theparticlesizesareuniform,anddistributedintherangeof20-200nm.TheinitialdischargecapacityoftheLi/LiCo1/3Ni1/3Mn1/3O2cellwasabout149mAh·g-1whenitwascycledatavoltagerangeof4.5-2.3Vwithaspecificcurrentof0.25mA.Theresultisbetterincomparisonwithsolid-statesolutionmethod.Thesyntheticprocedurewasdiscussed.Threemajorreactions:chelation,esterification,andpolymerizationsuccessivelyoccurred.
简介:研究了Al-1Mn-1Mg合金不同变形下的流变应力曲线和微观结构特征,探讨了该铝材在热变形过程中的动态软化行为。结果表明,应变速率为0.1s-1时,若变形温度较低,则发生了动态回复;若变形温度高于723K,产生明显的动态再结晶;变形温度为673K时,在低应变速率条件下,产生动态再结晶,应变速率高于0.1s-1,软化过程具有动态回复和动态再结晶的混合特征。当应变速率高于5.0s-1时,产生几何动态再结晶。
简介:HighlytexturedHeusleralloyMn46Ni42Sn11Sb1ribbonswerepreparedbymeltspinning.TheannealedhighMncontentMn46Ni42Sn11Sb1ribboncross-sectionmicrostructure,crystalstructure,martensitictransformation(MT),andmagnetoresistance(MR)propertieswereinvestigated.TheMRintheannealedribbonwasassessedbythemagneticfielddirectionperpendiculartotheribbonsurfacewiththemagneticfieldupto30kOe.Thelargenegativevalueof25%forMRwasobtainedat244K.Theexchangebias(EB)effectsoftheas-spunandannealedribbonswereinvestigated.Afterannealing,theEBeffectshavebeenimprovedbyabout25Oeatthetemperatureof50K.Themagnetizationshaveincreasedapproximatelyby10%morethantheas-spunribbon.
简介:采用共沉淀法制备了不同Zn掺杂量的Li(Ni1/3Co1/3Mn1/3)1-xZnxO2(x=0-0.08)固溶体,通过X射线衍射(XRD)和光电子能谱(XPS)分析,研究了不同Zn掺杂量对Li(Ni1/3Co1/3Mn1/3)1-xZnxO2固溶体晶体结构和过渡金属表面化学状态的影响。实验结果表明:当Zn掺杂量x小于0.006时,固溶体材料具有稳定的层状结构;微量Zn的掺杂能够增强晶体材料的整体键能。
简介:考察了温度对合成材料的影响,并对材料进行不同倍率的过充电测试。经过XRD、恒流充放电、循环伏安等测试得出,800℃保温16h时合成的LiNi1/3Co1/3Mn1/3O2具有稳定的α-NaFeO2层状晶体结构,材料电化学性能最好,最大放电容量为158.9mAh/g(2.4~4.3V),110次循环后,容量保持率为96.69%,显示良好的循环性能。过充电测试结果表明,材料在小倍率循环时具有一定的耐过充性能。过充电时Co4+的出现和材料结构发生变化、阳离子混排严重是引起容量衰减的原因。
简介:Treatmentof4-amino-3-(1-aryl-5-methyl-1,2,3-triazol-4-yl)-5-mercapto-1,2,4-triazoles/2-amino-5-(1-aryl-5-methyl-1,2,3-triazole-4-yl)-1,3,4-thiadiazoleswithbenzaldehyde,acetoneandω-bromoacetophenonewastestedandcompared.ThetitlecompoundsSchiffbases,amides,imidazolo[2,1-b]-1,3,4-thiadiazolesand7H-s-triazolo[3,4-b]-1,3,4-thiadiazineshavebeenconfirmedbyelementalanalyses,^1HNMR,IRandMSspectra.AllthecompoundshavealsobeenscreenedfortheirantibacterialactivitiesagainstB.subtilis,S.aureusandE.coli.