简介:Thediblockcopolymersintercalatedlayeredsilicatewaspreparedviaameltdispersiontechnique.Thentheeffectofintercalatedhybridasfilleronacrylonitrile-butadiene-styreneresinwascharacterizedbyX-raydiffraction,transmissionelectronmicroscopy,stress-strainmeasurementsinelongation.
简介:PositronannihilationtechniquewasusedtostudythemicellebehaviorsoftwoSBStriblockcopolymersinMEKsolventatdifferenttemperatures.Annihilationlifetimeτ3ofortho-positronium(o-Ps)exhibitedanobvioustransitionfromshorterlifetimetolongerlifetimewithtemperature.ItwasattributedtothechangeofmicellebehaviorofSBScopolymermoleculesinthesolution.Experimentalresultsofsedimentationvelocityofultracentrifugewerealsoreported.
简介:Styreneisextensivelyusedinindustry,butitsototoxicity,inparticularinthepregnantfemaleandtheoffspring,isstillnotwellunderstood.Inthecurrentstudy,youngadultmaleratsandpregnantfemaleratswereexposedtostyrenebygavageatdifferentdoses.Theyoungadultmaleratsreceivedatotalof12g/kgstyrenewithindifferentperiods(800mg/kg/dayfor5days/weekfor3weeks,400mg/kg/dayfor5days/weekfor6weeks,200mg/kg/dayfor5days/weekfor12weeks,and100mg/kg/dayfor5days/weekfor24weeks)andthepregnantfemaleratsreceivedstyreneatadoseof400mg/kg/dayfor5days/weekfor6weeksstartingfromthegestationday-4.Hearinglossandhaircelllosswereassessed5daysafterthestyrenetreatmentintheyoungadultmaleratsandinthemotherrats.Thecochlearimpairmentsintheratpupswereexamined2monthsaftertheirbirth.Thestyreneexposurecausedhearinglossandhaircelllossstartingfromthemid-frequencyregioninthethirdrowofouterhaircells(OHCs)andtheimpairmentsappearedtoberelatedtothedosinglevelineachsingleday.Significantly,thestyreneexposuretothepregnantratsinterferedwithauditoryfunctionaldevelopmentoftheirfetus,leadingtoadeficitofcochlearamplification,althoughtheOHCsappearedtodevelopwell.Theresultsindicatethatashort-termhigh-levelstyreneexposuremaybemoreototoxicthanalong-termlow-levelexposureforasimilartotalstyrenedoseandthestyreneinthepregnantwoman'sbodymayinterferewithauditorydevelopmentoftheirfetus.
简介:Thecharacteristicsofstyrene-acrylicacidcopolymersupportedlanthanidecomplexes(SAACLn)(Ln=La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tin,Yb,andLu)weredescribed.AcomparisonoftheactivitiesofSAAC·Lnwasmade.Itwasfoundthatinthepolymerizationofbutadiene,apeakinactivityappearedatNdandPr,Sin,Euandtheheavylanthanidesexhibitedlowornoactivities.Theeffectsofsomefactorsontheactivitieswerediscussed.Themicrostructureofthepolymersobtainedwithallthelanthanidesintheserieswerethesameandthecontentofcis-1,4polybutadieneattainedwasmorethan98%.
简介:Ethyl-cyanoethylcellulose((E-CE)C)/styrenesolutioncouldformanisotropicsystemwhentheconcentrationwashighenough.The(E-CE)C/polystyrene(PS)multiphasepolymercouldbeobtainedbyradicalpolymerizationofthestyreneinthesolution.The(E-CE)C/PSmultiphasepolymermaintainedboththecrystallinestructureofthe(E-CE)CandtheamorphousstructureofthePS.Inthemultiphasepolymerproducedfromtheisotropicsolution,however,the(E-CE)CformedspherulitesandspreadinthePSamorphousphase.While,inthemultiphasepolymerproducedfromtheanisotropicsolution,the(E-CE)formedcylindericcrystallineaggregates.Moreover,theorderedlamellartexturewasalsoobservedinthemultiphasepolymerproducedfromtheanisotropicsolution.
简介:Externalmagneticfieldincreasesthephoto-inducedpolymerizationrateofstyrenemicroemulsion.Thetypeofphotoinitiatorplaysanimportantrole.Thephotoinitiators,usedaredimethoxyphenylacetophenone(DMPA),1-hydroxycyclohexylphenylketone(Irgacure184)anddimethylhydroxyacetophenone(Darocur1173).Nomagneticeffectwasobservedbyusingdibenzylketone(DBK)asphotoinitiator.Themolecularweightofthepolymerisslightlyaffectedbymagneticfield.Theinfluenceoftemperaturehasalsobeeninvestigated.
简介:Thefirstdomesticstyreneextractionunit,a30kt/aunitforextractionofstyrenefrompyrolysisgasoline(pyro-gas),intheconstructionofwhichtheGuangdongNewHua’aoPetrochemicalCompany,arestructuredenterpriseaffiliatedtotheMaomingPetrochemicalCompany,hasinvested160millionRMB,hasbeencontinuouslyandsafelyoperatingfor430dayssinceMay2011.
简介:Polymerboundpalladium(Pd)complexcatalystswithgraftingacrylonitrileoninorganiccompound(MgO,Y-molecularsieveandSiO2)bypre-radiationmethodwerestudies.Thepalladium-graftingpolymershavebeeninvestigatedbyX-rayphotoelectronspectrscopy(XPS).ItisindicatedthatpeakwidthofC1sandO1sspectraofMgO-g-PAN-Pd(radiation-inducedgraft)iswiderthanthatofMgO-PAN-Pd(chemicalmethod)andPeaknumbersofformerareonemorethanlater.Accordingtothereportinreference,thispeakisattributedto-O-Cgroup.Thus,thegraftacrylonitrileonMgOmaycompletethroughoxygenatomsimMgOandβ-carbonatomsinacrylonitrile.Thepolymercatalystobtainedbyradiationgraftingisahigheractivehydrogenationcatalystforolefinesandbetterantioxicthanthatofoneobtainedbychemicalmethod,andithasselectivityforhydrogenationcatalyst.
简介:Polymerizationofacrylonitrile(AN)inaqueousnitricacidinitiatedbypolypropylene-basedpolyamidoxime(PPAO)-thiourea(TU)combinationhasbeeninvestigated.Theoverallrateofpolymerization(R_p)undertheconditionsof[TU]/[PPAO]<0.5molarratioisThemolecularweightsofthepolymerswerefoundtobeinverselyproportionalto3/2-powerofnitricacidconcentrationand1-powerofthioureaconcentration.Inaddition,itisindependentwiththeconcentrationsofmonomerandPPAO,anddecreaseswithincreasingtemperature.Onthebasisoftheseexperimentalresults,acoordination-protontransfermechanismfortheinitiationwasproposedanddiscussed.