简介:EffectofaddedCo2+(aq)oncopperelectrowinningwasstudiedusingdopedpolyaniline(Pani)andPb-Ag(1%)anodesandastainlesssteelcathode.ThepresenceofaddedCo2+(aq)intheelectrolytesolutionwasfoundtodecreasetheanodepotentials.TheoptimumlevelofCo2+(aq)concentrationintheelectrolyte,withrespecttothemaximumsavingofpowerconsumptionwasestablished.Linearsweepvoltammetry(LSV)wasusedtostudytheinfluenceofaddedCo2+(aq)ontheanodicprocessesinacoppersulfate-sulfuricacidelectrolyte.Theoxygen-evolutionpotentialforPanianodeisdepolarisedatlowercurrentdensities(≤0.01A/cm2)andattainssaturationatρ(Co2+)o≈0.789g/L;whilsttheoxygen-evolutionpotentialforPb-Ag(1%)anodeisdepolarisedathighercurrentdensities(≤0.02A/cm2)andattainssaturationatρ(Co2+)o≈1.315g/L.Thepreferredorientationsofthecopperdepositschangefrom(220)to(111)withtheadditionof0.394?0.789g/LCo2+buthigherconcentrationsfavor(220)orientationagain.
简介:CopperdepositisoneofthemostimportantandwidespreadoresinChina.ThecoppermetalogenyinChinarevealsacomplicatedtectonicevolutionhi...
简介:Thecrystalstructureofthetitlecomplex{[Co(TCB)2/2-(IMI)2(H2O)2][Co(IMI)4(H2O)2]}(H2O)4(whereTCB=1,2,4,5-benzenetetracarboxylicanion;IMI=imidazole)hasbeendeterminedbyX-raydiffractionmethod.Crystaldatafor{[Co(TCB)2/2(IMI)2(H2O)2][Co(IMI)4(H2O)2]}-(H2O)4:triclinic,spacegroupP1,a=1.0647(2)nm,b=1.1165(1)nm,c=1.00361(1)nm,α=91.56(1)°,β=111.34(1)°,γ=115.642(10)°,V=0.9772(3)nm5,Z=1.Thepolymercobalt(II)complexhasanovelthree-dimensionnetworkstructure.Co(1)atomandCo(2)atombotharecoordinatedinanoctahedralarrangementandlocatedinthecenterofthecoordinationanionandthecenterofthecoordinationcation,respectively.MoreoverfourcarboxylgroupsofTCBaredividedintotwotypes,twopara-carboxylgroupsbridgeCo(1)atominmonodentatefashionandothertwopara-carboxylgroupsareinfree.
简介:ChinaDevelopsCopperBeadsIUDAnewtypeofintra-uterinedevice(IUD),CopperBeadsIUD,hasbeendevelopedrecentlyinChina.Ithasbeenapprove...
简介:IntroductionInAnatolia,thebirthandthedevelopmentofmetallurgyintervenedbetweenthe9thand3rdmillenniumsaswellastestifythemoreandmorefrequentapparitionsofmetalsartefactsintheinventoryofthearcheologicalobjectsofthisperiod.
简介:StudiesonElectrolyticCodepositionofLanthanum-CobaltinUreaMeltQiuKairong(丘开容),YangQiqin(杨绮琴)(DepartmentofChemistry,ZhongshanUn...
简介:
简介:Thesixmultiimidazolecopper(Ⅰ)complexesareutilizedtomimictyrosinase.Themainproductis3,5-di-t-butylcatecholfromo-hydroxylationofthesubstrate2,4-di-t-butylphenol.Thehighestyieldofcatecholisupto82.2%andselectivity94.8%by[Cu(I)_(3b)(MeCN)_2](ClO_4)_2andO_2undermildconditions,whicharefoundtobemoreefficientthanthatalreadyreported.
简介:Thisresearchreportsthepreparationandcharacterizationofcoppernanoparticlesmodifiedbydidecylbenzenesulfonate(DBS),TheCunanoparticles'sizewasdeterminedtobe40nmbytransmissionelectronmicroscope(TEM).TheX-rayphotoelectronspectrometry(XPS)resultsshowthatthereareinteractionsbetweenthecoppernanoparticlesandDBSfunctiongroup.Thenonlinearopticalpropertieswerestudiedbythefour-wavemixingmethod.Thevalueofx^(3)/α0wasfoundtobe6.9×10^-11esucm.
简介:Theso-called“Yangtze-type”copperdepositsinclude:(1)Cu-bearingmassivepyritebed,(2)Cu-bearingskarnandmagnetite-typeoredeposits,withreplacementCu-vein-typedepositsnearthemetasomaticzone,and(3)mineralizedintrusivebodiesandbrecciapipes,someofwhichareknownasporphyrycopperores(e.g.Chengmenshan).ThistypeoforedepositsisatypicalexampletoverifythepolygenesisofinostofthedepositsinChina,ashasbeenpromotedbyProf.TuGuangchiinviewofthepolycyclicdevelopmentofthegeologicalhistoryinChina.Thispaperiscon-cemedwithonesub-typeofsuchdeposits.
简介:Theuseofmoreandmoreelectronproductsrequiresinteriorwoodproductstohavetheperformanceofelectromagneticshielding.Oneofthewaystorealizeitistointroducethechemicalplatingwhichhasalreadybeendevelopedinelectronindustryintowoodprocessing.Thepaperclarifiesthemechanismofelectrolesscopperandgoldplatinganditsapplicationtowood.Itemphasizesthedevelopmentandtechnologyofelectrolesscopperandgoldplatingonwood.Meanwhile,itpointsoutthatitishighlyfeasibletotakethistechnologyintoeffect.
简介:HydrolysisofDNAisanimportantenzymaticreaction,butitisexceedinglydifficulttomimicinthelaboratorybecauseofthestabilityofhydrolysisofDNA.Inthispaper,thecleavageactivityofcomplexesformedbetweenCu(Ⅱ)andfourdifferentaminoacidoraminoacidmethylesteronDNAisstudiedbygelelec-trophoresis.ItisfoundthatDNAcouldbecleavedbyCu(Ⅱ)-L-HisandCu(Ⅱ)-L-Hismethylestercomplexesandtheefficiencyofcleavageislargelydependentonthemetalion-to-ligandratio.FurtherexperimentsshowthatthecleavageofDNAmediatedbyCu(Ⅱ)-L-HiscomplexesoccursviaahydrolyticmechanismandtheactivechemicalspeciesthataffectsDNAcleavageisproposedtobeMI2H+andML2H22+.
简介:AccordingtoAWPAE11-2006standard,copperfixationratesofseveralcopper-basedformulations,suchasammoniacalcopper,aminecopper,andammoniacal-ethanolaminecopper,aswellasalkalinecopperquaternary(ACQ),weretestedandcomparedinthispaper.Andthefixationratesoftebuconazole(TEB)andpropiconazole(PPZ)inseveralformulations,suchascopperazole,emulsifiedtypeandsolventtype,werealsocompared.Thedeterminationofcoppercontentintheleachatewasanalyzedbyatomicabsorptionspectrom...