简介:利用密度泛函理论(DensityFunctionalTheory)中的B3LYP方法在6-311+G(d,p)的计算水平上研究了Fe/Fe_2与NO反应的相关微观机理.全参数优化了Fe+NO和Fe_2+NO反应体系在不同重态反应势能面上各驻点的几何结构,并用频率分析法以及内禀反应坐标(IntrinsicReactionCoordinate)方法对过渡态进行了验证,得到了相对应的反应的微观反应路径.用"两态反应"分析反应机理,计算结果表明2个体系的优先选择路径均为低自旋态进入和高自旋态离开反应.通过对2个体系反应活化能的比较,Fe_2+NO体系更易进行.
简介:摘要目的探讨近年来血吸虫病流行地区血吸虫性阑尾炎的病理特点及其意义。方法收集2011年至2015年,什邡市人民医院收治的203例术后病理诊断确诊为血吸虫性阑尾炎的病例的临床病理资料,并与同时期内的非血吸虫性阑尾炎1260例进行比较。结果研究组203例病理切片中均可见阑尾管腔狭窄及陈旧性血吸虫卵钙化、沉积,但未发现新鲜的血吸虫卵及虫卵肉芽肿等特异性变化;从患者年龄来看,较为集中在40~80岁,且经两组比较发现,坏疽性及慢性阑尾炎所占比例有差异。结论血吸虫性阑尾炎更易发生坏疽穿孔。通过开展积极有效的血防工作,急性血吸虫病已很少见,但陈旧性血吸虫卵对人体某些器官仍会造成很大的危害,应引起我们的重视。
简介:Pr2Fe14B-La2Fe14B系统被衍射(XRD),微分扫描热量测定(DSC)和扫描电子显微镜学(SEM)与精力装备了的X光检查粉末调查散X光检查光谱学(版本)。水晶结构参数被完整侧面的Rietveld精炼决定。结果揭示了那所有合金(Pr1-xLax)2Fe14B使Nd2Fe14有空格组P42/mnm的B类型结构并且形成了连续固体在x=0.0之间的解决方案并且1.0。格子参数一,c,单位房间体积V和c/a比率与La集中线性地增加了。由thermogravimetry分析决定了,居里温度(TC),阶段转变温度和融化的温度(Pr1-xLax)2Fe14B在La内容之上线性地减少了。基于DSC大小和X光检查粉末衍射考试的结果,Pr2Fe14B-La2Fe14B系统被建立。
简介:Theadsorptiveremovalofarsenicbysynthetically-preparednanoFe-Mnbinaryoxides(FM)wasinvestigated.AnovelmethodusingpotassiumpermanganateandferricchlorideasrawmaterialswasusedtosynthesiseFM.ThemolarratioofFeandMninthesyntheticFe-Mnbinaryoxideswas4:3.TheFM-1andFM-2(preparedatdifferentactivationtemperatures)havinghighspecificsurfaceareas(358.87and128.58m2/g,respectively)wereamorphousandofnanoparticletypes.TheamountofarsenicadsorbedonFM-1washigherthanthatadsorbedonFM-2particles.AfteradsorptionbyFM-1,residualarsenicconcentrationdecreasedtolessthan10μg/L.Theadsorptionkineticsdatawereanalyzedusingdifferentkineticmodelsincludingpseudofirst-ordermodel,pseudosecond-ordermodel,Elovichmodelandintraparticlediffusionmodel.Pseudosecond-orderkineticmodelwasthemostappropriatemodeltodescribetheadsorptionkinetics.TheadsorptionpercentageofAs(Ⅲ)increasedinthepHrangeof2–3whileitdecreasedwiththeincreaseofpH(3
简介:Thediffusionmechanismofboroninbcc-Fehasbeenstudiedbyfirst-principlescalculations.Thediffusioncoefficientsoftheinterstitialmechanism,theB–monovacancycomplexmechanism,andtheB–divacancycomplexmechanismhavebeencalculated.ThecalculateddiffusioncoefficientoftheinterstitialmechanismisD0=1.05×10-7exp(-0.75eV/kT)m2·s-1,whilethediffusioncoefficientsoftheB–monovacancyandtheB–divacancycomplexmechanismsareD1=1.22×10-6f1exp(-2.27eV/kT)m2·s-1andD2≈8.36×10-6exp(-4.81eV/kT)m2·s-1,respectively.Theresultsindicatethatthedominantdiffusionmechanisminbcc-Feistheinterstitialmechanismthroughanoctahedralinterstitialsiteinsteadofthecomplexmechanism.ThecalculateddiffusioncoefficientisinaccordancewiththereportedexperimentresultsmeasuredinFe–3%Si–Balloy(bccstructure).Sincethenon-equilibriumsegregationofboronisbasedonthediffusionofthecomplexesassuggestedbythetheory,ourcalculationreasonablyexplainswhythenon-equilibriumsegregationofboronisnotobservedinbcc-Feinexperiments.
简介:磁性的元素Fe,公司和Ni的线性热扩大(CLE)的系数用与MATLAB计算相结合的理论模型从试验性的信息被估计。模型参数能精确地被决定,并且估计的数据在对试验性的结果的好同意。便于评价,热扩大的理论被使用把CLE分开成它的无磁性、磁性的部件。对CLE的无磁性的贡献的计算基于MnBi/NdFeB混血儿的修改Grc性质结合的磁铁都逐渐地减少,当混合磁铁的密度几乎线性地改善时。在293-398的一个温度范围?K,混合磁铁的coercivity温度系数从0.59逐渐地改善?%比较。建模和频率与二低角落频率认为压力消除阀门是一个秒顺序系统是合理的试验性的结果表演。PID控制,死了的乐队赔偿控制和鷸?鷸??
简介:Understandingtheeffectsoforganicacids(OA)onthetransformationofFeandMntosurfacewaterfromtheweatheringcoalgangueisofgreatbene?ttoriskassessmentandremediationstrategiesforcontaminatedwaterandsoil.BasedontheinvestigationonsurfacewaterinthecentralcoaldistrictsoftheGuizhouProvince,18watersampleswerecollectedforheavymetalanalysis.TheresultsindicatedthatthepHvalueofsurfacewaterislow(3.11–4.92),andFeconcentration(1.31–5.55mgL-1)andMnconcentration(1.90–5.71mgL-1)were,onaverage,10.86and34.33timesthelimitofSurfaceWaterQualityStandards,respectively.InordertoevaluatetheeffectsoftheOAonthedissolutionofFeandMnfromtheweatheringcoalgangue,columnelutionandbatchleachingexperimentswereconducted.Theresultsshowthatthelowmolecularweightoforganicacids(LMWOAs,i.e.,oxalic,tartaric,malicandcitricacids)andfulvicacidssigni?-cantlyacceleratedthedissolutionofFeandMn;inaddition,whentheconcentrationofOAreached25mmolL-1,theconcentrationsofFe,andMnwere1.14–67.08and1.11–2.32timesashighasthosein0.5mmolL-1OA,respectively.Furthermore,themigrationofFeandMnwassigni?cantlyin?uencedbythepHandEh,especiallyforFe;theionMnwasdissolvedfromtheganguemoreeasilythantheionFeinthecolumnleaching,whichwascontrarytotheresultsofbatchleaching.
简介:磁铁矿(Fe3有不同尺寸和形状的O4)nanoparticles被热分解方法综合。二条途径,非注射一个壶和热注射的方法,被设计详细调查生长机制。nanoparticles的尺寸和形状被调整先锋集中和持续时间时间决定,这被发现,它能好在我们的合成系统基于LaMer模型由机制解释了。monodisperseFe3O4nanoparticles从5nm有一条吝啬的直径到16nm,和形状进化从对球形三角形、立方。磁性是尺寸依赖者,和Fe3在关于在房间温度和最大的浸透磁化的5nm展览superparamagnetic性质的小尺寸的O4nanoparticles来临到78emu/g,而Fe3O4nanoparticles当直径增加到大约16nm时,开发铁磁性的性质。
简介:Inordertosolvethehigh-priceandshort-lifetimeproblemsofthecutterofagriculturalmachinery,andimprovethewearresistanceofthecutter,theTiCN/FemetalceramiccompositecoatingwaspreparedonthesubstrateofQ235steelbyreactionnitrogenarccladdingtechnique.ThemixturepowderoftitaniumandgraphitewaspreplacedontheQ235steelsurfaceafterintensivemixingbyplanetaryballmillandgluingwithstarchbinder.Themicrostructureandphaseofthecoatings,interfacebehaviorbetweencoatingsandthesubstratewereinvestigatedbyscanningelectronicmicroscopeandX-raydiffractometer.Themicro-hardnessdistributionofthecoatingsectionwastestedbymicro-hardnesstester.Frictioncoefficientandwearweightlossweremeasuredbyabrasionmachine.Wearingsurfacemorphologywasinvestigatedbyscanningelectronicmicroscope.TheresultsshowthatanexcellentbondingbetweenthecoatingsandtheQ235steelsubstrateisensuredbythestrongmetallurgicalinterfaceandphaseofthecoatings.ThecoatingsaremainlycomposedofTiCN.Thehighestmicrohardnessofthecoatingsreaches1089HVO.2,whilethemicro-hardnessofQ235steelsubstrateisonlyabout286HVO.2.Theanti-abrasivetestresultsshowthatthewearresistanceofthecladdingcoatingisbetterthanthatofquenchedandtempered65Mnsteelwhichisoftenusedascutterofagriculturalmachinery.ThefieldtestresultsshowthattheTiCN/Femetalceramiccompositecoatingpreparedbyreactionnitrogenarccladdingisfeasibletothemanufactureandremanufactureofthecutterofagriculturalmachinery.
简介:ThestrongadaptabilityofBroussonetiapapyrifera(L.)Vent.tolowphosphorus(P)conditionscanbeattributedtothelargeamountofroot-exudedorganicacidsandthehighef?ciencyofPextraction.However,microelementcontentsarein?uencedbylow-Pstress,andtheireffectsonthephotosyntheticcapabilityofB.papyriferaremainunknown.Inthisstudy,weinvestigatedtheeffectsoflow-Ptreatmentonnetphotosyntheticrate(P_N);chlorophylla?uorescence(ChlF)characteristics;andFe,Mn,Cu,andZncontentsofB.papyriferaandMorusalbaL.seedlings.ResultsshowthatB.papyriferaexhibitedbetterphotosyntheticcapabilityundermoderatePde?-ciency(0.125,0.063,and0.031mmol/LPtreatments),whereasthephotosyntheticcapabilityofM.albadecreasedundermoderateandseverePde?ciency(0.016and0mmol/LPtreatments).UndermoderatePde?ciency,thedecreaseinCuandZncontentsinB.papyriferawaslowerthanthatinM.alba.UnderseverePde?ciency,aconsiderabledecreaseofphotosyntheticcapabilityinB.papyriferaandM.albawasassociatedwithlowCuandZncontents.ThePNofthetwoMoraceaespeciesexhibitedabettercorrelationwithCuandZncontentsthanwithFeorMncontent.Pde?ciencycouldnotonlydecreasecyclicphotophorylationandphotosyntheticef?ciency,butcouldalsoaffectthestabilityofthylakoidmembranestructureandelectrontransportef?ciencybyin?uencingthecontentsofCuorZn,therebyaffectingphotosynthesis.
简介:有软磁性的层(Fe)或antiferromagnetic层(Mn,FeMn或MnO)的各向异性的Pr-Fe-B电影被准备由直流(DC)磁控管在Si(100)底层上劈啪作响在650点加热了?te是由有90的一个方向的热伪造?%塑料变丑。然后,前进状态的微观结构合成被观察,并且机械性质的变化法律和磨擦表演在以后并且在塑料使变形前被比较。结果显示艾尔3增强Zr的粒子旋转并且闯入10-20的更小的尺寸?ng可溶的biopolymer有三个转变金属离子的牛的浆液白朊(BSA)(M,M=Cu,公司,Mn)。白朊一定的金属离子的有约束力的模式和比率被调查。BSA-M建筑群被紫外力的、圆形的二色性(CD)描绘系列和polyacrylamide胶化电气泳动(页)。当聚合物支架和金属建筑群作为催化活跃中心工作了,BSA服务了。当到BSA的转变金属离子建筑群的有约束力的比率是5:1时,结果证明BSA的结构仍然保持未改变。而且,清除superoxide一??
简介:一篇小说荧光灯为H2PO4-基于碳dots/Fe3+被设计并且制作合成。碳点被一个确定的一个壶综合热水的方法并且由传播电子显微镜,X光检查衍射计,紫外力的吸收分光计和荧光分光光度计描绘了。碳dots/Fe3+合成被碳点和FeCl3,的水的混合获得,它的荧光性质被荧光分光光度计描绘。碳点的荧光被水的Fe3+阳离子熄灭,导致碳dots/Fe3+的低荧光紧张合成。在另一方面,H2PO4-由化学反应减少了Fe3+的集中并且提高了碳dots/Fe3+的荧光合成。Stern-Volmer方程被介绍描述在合成的碳dots/Fe3+和H2PO4-,和好线性(R2=0.997)在H20.4-12公里的PO4-集中。
简介:CaTiO3的形成行为在钛铁矿的electro-deoxidization期间专注准备FeTi合金被实验和模拟调查。结果显示中间的产品的形成和分解,CaTiO3,在钛铁矿的electro-deoxidization期间是不可避免的步专注。CaTiO3能在电气化学的过程期间通过熔融的盐和电气化学反应的hydrolyzation被产生。为CaTiO3的产生的主要原因在阴极是在从熔融的盐和TiO2的Ca2+之间的电气化学反应。与electro-deoxidization继续,CaTiO3是进一步的electrolyzed形成钛低值氧化物。当在由在sintering期间增加CaCO3的阴极的CaTiO3形式处理时,当前的效率能被改进。