简介：Thetitlecopolymer(PDEBO)wassynthesized.ThethermalcharacteristicsofthepolymerweredeterminedbymeansofDSCandTGA,revealingthatthepolymerhasagoodthermalstability.TheX-raydiffractionmeasurementsofthethinfilmsshowedthatthepolymerisdisorder.Electroluminescence(EL)inthegreenregionofthespectrumwithamaximumat500nmwasobservedfromthepolymerfilmssandwichedbetweenindium-tin-oxideandanAlelectrode.

简介：利用天然气脱硫厂的酸气、氢氧化钠、对二氯苯和助剂磷酸钠，在六甲基苯磷酰三胺溶剂中，常压下缩聚４～６小时，制备了线型结晶性高分子量聚苯硫醚（ＨＭＷＰＰＳ）。该方法具有的明显优点是：设备简单、容易操作、活性高、溶剂稳定、产品收率高、成本低、适宜于大规模工业生产。

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简介：Theapparentsolubility（S）,concentration-averagediffusivity（D）,andpermeability（P）,forC02,CH4andN2throughPPOandaryl-brominatedPPOat35℃forpressurerangingfrom1to26atmarereported.ItisfoundthatP,D,andSofthemembranestoallthethreegasesvarywiththeextentofbromination.Sincreaseswiththeincreaseofthepercentofbromineineachcase,butDtoCO2increasesremarkablyonlyathigherdegreeofbrominafion,andtherefore,PtoCO2isincreasedbymorethan100%overawiderangeofpressureinthecase.Thesolubilitydataarewelldescribedbythedualmodesorptionmodel.ItisfoundthatthegasmoleculessorbedbytheLangmuirmodearerelativelymoreimmobilizedandthecontributionofthenonequilibrinmcharacterofthepolymertogaspermeationincreasesobviouslyforCO2andishardlychangedforCH4withincreasingbrominecontent.Theseobservationsareinterpretedintermsofchangesinspecificfreevolume（SFV）andthecohesiveenergydensity（CED）ofthepolymers.

简介：单独螺旋状的碳的材料为潜在的应用的变化吸引了许多注意。此处，单独螺旋状1，4苯撑衔接了polybissilsesquioxanenanofibers用一双enantiomers通过一条超分子的templating途径被准备。在在是为获得激活的最普通的方法的700一方法的碳化以后，精力，和TGA的试验性的条件如下被设置：在氮气氛，与20mL/min的煤气的流动率，加热5-50的率??????????????????六吗？？

简介：Dispersionofmulti-walledcarbonnanotubesinpoly(p-phenylene)compositeexposedtotoluenewasexperimentallyinvestigated.3mgofmulti-walledcarbonnanotubeswithnominalsizeof20nmwascompoundedwith30mgofpoly(p-phenylene)withthepresenceofterpineolasbindinginitiator.Toinvestigateanoptimalconditionforhomogenizingallconstituents,ultrasonicationwithanoutputpowerof750Wwasemployedwithcompoundingtimeof3,10,20and30min.WithFTIRanalyses,itcouldbeconfirmedthathomogeneouscompositeofmulti-walledcarbonnanotubesandpoly(p-phenylene)couldbeprepared.SEManalyseswerealsoconductedtoexaminethedispersionofmulti-walledcarbonnanotubesinthepolymermatrix.Thenintrinsicelectricalresistanceofthecompositesafterbeingexposedtotoluenewasalsoinvestigated.Itwasfoundthatthecompositefilmpreparedwithultrasonicationfor20mincouldprovidesufficientlysensitiveresponsewithrespecttovariedconcentrationoftoluene.

简介：Fluorescencespectraofladderlikepolyphenylsilsesquioxane(LPPS)andladderlike1,4-phenylene-bridgedpolyvinylsiloxane(LPPVS)havebeenmeasuredasafunctionoftemperature(4-55℃),indilutetetrahydrofuransolution.Theexcimer(IE)tomonomer(IM)intensityratio(IE/IM)ofLPPSdilutesolutionshowsadoublelinearArrheniusplotwithabreakpointascribabletoatransitiontemperatureTr.Thisbehaviorhasnotbeenfoundforsinglechainpolyorganosiloxanes.WhenIn/EofLPPSwasplottedagainst1/T,italsogaveadoublelinearplotwithonebreakpoint,whichwasfoundinsinglechainpolyorganosiloxanes.ThedifferentbehaviorsbetweenLPPSandsinglechainpolyorganosiloxanesmaybemainlyattributedtotherelativelyrigiddouble-chainmacromolecularbackboneofLPPS.However,theln(IE/IM)ofdiluteLPPVSsolutionversus1/Tshowsasimplelinearvariationwithapositiveslopewhichconfirmsourproposition.ThedifferencebetweenthefluorescenceresultsofLPPSandthoseofLPPVSmaypossiblyderivefromtheirstructuredifferencesandcooperativemotioninbackbonechainbonds.

简介：The1,1'-binaphtholbasedoligomers3and7with3,3'-acetylene-phenylene-acetylenespacerwerepreparedfromBINOL1.ThehighopticalrotationvalueandCDspectrademonstratedthemainchainchiralityoftheoligomermolecule.TheUV-VISandfluorescentspectraevidencethecharacteristicsofconjugatedstructure.Incomparisonwitholigomer2bearing3,3'-acetylenespacer,theoligomers3and7havelongerefficientconjugationsegment,andtheirfluorescentquantumyields(φ)increased(0.60-0.65versus0.14).Extendingtheeffectiveconjugationsegmentwouldimprovethephotophysicalpropertiesofchiralconjugatedpolymers.``

简介：一个非水的暂停polycondensation方法被建议继续为准备的p-phenylenediamine和terephthaloyl氯化物的反应poly(p苯撑terephthalamide)(PPTA)。系统与NMP-CaCl被操作<潜水艇class=“a-plus-plus”>是的2答案驱散的阶段和是的惰性的液体石蜡连续阶段。每NMP-CaCl<潜水艇class=“a-plus-plus”>在石蜡推迟的2答案microdroplet用作polycondensation发生了的microreactor。根据TGA，XRD，红外，SEM和EA的结果，有好质量的PPTA通过这个新奇方法被获得，并且影响这个过程的很多个主要因素被调查为PPTA的准备决定最佳条件。而且，这个二阶段的polycondensation系统与常规解决方案polycondensation方法相比带给许多唯一的优点，包括使反应物离开氧和水的封上的反应环境，HCl到的容易的移动支持更少的精力花费了工具的反应，控制得好的温度和低粘性。