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486 个结果
  • 简介:Thisworkreportsafeasiblesynthesisofhighly-dispersedPtandPt-Fenanoparticlessupportedonmultiwallcarbonnanotubes(MWCNTs)withoutFeandmultiwallcarbonnanotubeswithiron(MWCNTs-Fe)whichappliedaselectrocatalystsformethanolelectrooxidation.APtcoordinationcomplexsaltwassynthesizedinanaqueoussolutionanditwasusedasprecursortopreparePt/MWCNTs,Pt/MWCNTs-Fe,andPt-Fe/MWCNTsusingFeCl24H2OasironsourcewhichwerenamedS1,S2andS3,respectively.Thecoordinationcomplexofplatinum(TOA)2PtCl6wasobtainedbythechemicalreactionbetween(NH4)2PtCl6withtetraoctylammoniumbromide(TOAB)anditwascharacterizedbyFT-IRandTGA.ThematerialswerecharacterizedbyRamanspectroscopy,SEM,EDS,XRD,TEMandTGA.TheelectrocatalyticactivityofPt-basedsupportedonMWCNTsinthemethanoloxidationwasinvestigatedbycyclicvoltammetry(CV)andchronoamperometry(CA).Pt-Fe/MWCNTselectrocatalystsshowedthehighestelectrocatalyticactivityandstabilityamongthetestedelectrocatalystsduetothattheadditionof'Fe'promotestheOHspeciesadsorptionontheelectrocatalystsurfaceatlowpotentials,thus,enhancingtheactivitytowardthemethanoloxidationreaction(MOR).

  • 标签: 多壁碳纳米管 铁纳米粒子 电催化剂 甲醇氧化 氧化反应 纳米颗粒
  • 简介:Graphiteintercalationcompounds(GIC)weretestedasanexperimentalmodelforstudyingtheelectroniceffectofcarbonsupportonthecatalyticactivityandpoisoningtoleranceofPtcatalystfordirectmethanolfuelcells.TheGICsampleswithdifferentintercalationdegreeswerepreparedbyelectrolyzinggraphiteflakeinH2SO4forvaryingtheperiodsoftime.TheGIC-supportedPtcatalystwasdepositedelectrochemically.ThecatalyticactivityandpoisoningtoleranceoftheGIC-supportedPtcatalystswereevaluated.ItwasfoundthatGICwithsulfateanionasintercalatewasabletocatalyzemethanolelectrooxidation,whichcouldberelatedtothepositivechargesgeneratedonthegraphitelayeruponintercalation.Asintercalationdegreeincreased,thecatalyticactivityoftheGIC-supportedPtcatalystdecreasedwhilethepoisoningtoleranceimproved.ThissuggeststhatelectrondonationfromsupporttocatalysthadgreateffectonbothcatalyticactivityandpoisoningtoleranceofPtcatalyst.Andintercalationcanbeadoptedasanotherimportantwaytomakemodificationoncarboneouscatalystsupport.

  • 标签: 铂催化剂 插层复合 电子效应 碳石墨 催化剂中毒 直接甲醇燃料电池
  • 简介:ThesinteringofPtnanoparticlesisoneofthemainreasonsforcatalystdeactivationduringthehigh-temperaturepropanedehydrogenation(PDH)reaction.Promotersandsupportshavebeenintroducedtoprolongthecatalystlife.However,itisstillnecessarytodevelopnovelcatalystswithrobuststability.Herein,thephosphorus-modifiedcarbonnanotube-supportedPtnanoparticleswereemployedforthePDHprocess.PhosphorusmodificationimprovesthePtdispersion,effectivelypromotingtheactivityofPt/P-CNTs.Additionally,thephosphorus-modifiedCNTscaninteractstronglywithPtnanoparticlesbyimprovingtheelectrontransferorhybridization,stabilizingPtnanoparticlesfromagglomeration,andsignificantlyenhancingthecatalyststability.

  • 标签: PROPANE DEHYDROGENATION phosphorus-modified carbon NANOTUBES PLATINUM
  • 简介:Theaerobicoxidationofglycerolprovidesaneconomicallyviableroutetoglyceraldehyde,dihydroxyacetoneandglycericacidwithversatileapplications,forwhichmonometallicPt,AuandPdandbimetallicAu–Pt,Au–PdandPt–PdcatalystsonTiO2wereexaminedunderbase-freeconditions.PtexhibitedasuperioractivityrelativetoPd,andAu–PdandPt–PdwhileAuwasessentiallyinactive.ThepresenceofAuontheAu–Pt/TiO2catalystsledtotheirhigheractivities(normalizedperPtatom)inawiderangeofAu/Ptatomicratios(i.e.1/3–7/1),andtheonewiththeAu/Ptratioof3/1exhibitedthehighestactivity.SuchpromotingeffectisascribedtotheincreasedelectrondensityonPtviatheelectrontransferfromAutoPt,ascharacterizedbythetemperature-programmeddesorptionofCOandinfra-redspectroscopyforCOadsorption.Meanwhile,thepresenceofAuonAu–Pt/TiO2,mostlikeduetotheobservedelectrontransfer,changedtheproductselectivity,andfacilitatedtheoxidationofthesecondaryhydroxylgroupsinglycerol,leadingtothefavorableformationofdihydroxyacetoneoverglyceraldehydeandglycericacidthatwerederivedfromtheoxidationoftheprimaryhydroxylgroups.ThesynergeticeffectbetweenAuandPtdemonstratesthefeasibilityintheefficientoxidationofglyceroltothetargetedproducts,forexample,byrationaltuningoftheelectronicpropertiesofmetalcatalysts.

  • 标签: 铂催化剂 二氧化钛 双金属 游离氧 铂钯催化剂 二羟基丙酮
  • 简介:大音阶的第五音胶化旋转涂层在Pt/Ti/SiO2/Sisubstrate上准备的Pb(Zr0.4Ti0.6)O-3电影作为最高的电极与磅或Ru被用于铁电体电容器。为thePt/PZT/Pt和Ru/PZT/Pt铁电体电容器,尽管与一样的铁电体他,不同最高的电极材料招致PZT电容器的不同性质例如疲劳,漏,残余、浸透的极化,除了PZTfilm的类似的水晶取向。在(10)10交换周期以后,Ru/PZT/PtPt/PZT/Ptcapacitors的残余的极化分别地减少到70%和84%。在(8)10交换周期以后,后者的漏水流密度在积极偏爱显然增加,与前者相比。为最高的电极的Differentmaterials在PZT/top电极接口带不同条件。在PZT/electrode接口和在到充电注射的PZT/electrode接口的电极材料的氧化物的影响的氧空缺集中的Theinfluence能作为最高的电极与磅或Ru解释PZT电容器的性质的差别。

  • 标签: 铁电物质 电容器 Pb(Zr0.4Ti0.6)O3薄膜 溶胶体-凝胶体自旋覆盖层 顶电极
  • 简介:Abicentralpolymer-supportedphasetransfercatalyst,polystyrene-supportedpolyethyleneglycolandpyridiniumsalt(PS-Py-PEG-400),synthesizedwithchloromethylatedpolystyreneassupporteronwhichPEGandpyridiniumsaltwereimmobilizedsuccessively.ItscatalyticactivitywastestedforthereactionofsolidpotassiumacetateandbenzylbromidebyGCanalysis.ItwasfoundthatthebicentralcatalystperformedhigheractivitythanthemonocentralPS-PEG-400andPS-Py.

  • 标签: 两中心聚合物 支撑相转移催化剂 聚苯乙烯 聚乙烯乙二醇 吡啶盐
  • 简介:从中国证监会获悉,证券市场上新的退市办法已经出台,并将于2002年1月1日起实施。在新的退市办法中,取消了PT制度。上市公司暂停上市后,股票即停止交易,证券交易所不提供转让服务。此外,现今实行的宽限期申请的有关程序也被取消。

  • 标签: PT制度 中国 证券市场 上市公司 亏损额 宽限期
  • 简介:PT(D)型喷油器是康明斯N-855型发动机配装的喷油器。它具有计时、定量和喷射的多重作用,结构上与一般的喷油器有很大的不同。为了使每次喷射时喷油器的柱塞针阀与喷嘴头中的燃油能被全部喷射出去,确保计量准确,同时避免喷油器内部积炭,要求PT(D)喷油器在每次喷射完毕后,柱塞针阀应以一定的预紧力压向喷油器嘴头,这就需要调整喷油器的压紧力,即调整喷油器的落座压力。

  • 标签: PT燃油系 喷油器 调整 压力 喷射 发动机
  • 简介:摘要电磁式电压互感器的铁磁谐振是非有效接地系统中常见的一种现象,电磁式电压互感器引起铁磁谐振后,其介质击穿或爆炸都会导致母线故障。本文针对铁磁谐振对中性点非有效接地系统带来的影响,对电磁式电压互感器铁磁原理及现有的消谐措施进行分析,在各种情况下选择合适的消谐方式。

  • 标签: 不接地系统 电压互感器 铁磁谐振 消谐措施
  • 简介:ThemetaloxidesCuMnCeandCeYwashcoatsoncordieritewerepreparedusinganimpregnationmethod,andthenusedassupportfortheactivePtcomponenttopreparethePt/CuMnCeandPt/CeYmonolithiccatalystsforthedeepoxidationofVOCs.IncomparisonwiththePt/CeY,CuMnCe,andCeYmonolithiccatalysts,thePt/CuMnCemonolithiccatalystshowsanexcellentperformancefortoluene,ethylacetate,andn-hexaneoxidationandtheT90%islowto216,200and260℃,respectively.TheactivecomponentsPt/PtOandCuMnCeresultinabettersynergeticinteraction,whichpromotethecatalystreducibility,increasetheoxygenmobility,andenhancetheadsorptionandactivationoforganicmolecules.

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  • 简介:说起电影下载,我们首先会想到BT、电驴、迅雷等下载方式。实际上,除此之外,目前还有一种新兴的下载方式正在日益受到广大视频爱好者,特别是高清Fans们的喜爱,这就是PT下载。那么,这个看上去还比较陌生的东东.究竟是何方神圣,它有什么让人眼球发亮的优点,我们又该怎样利用它将心仪的大片搬回家,在本文,我们将给大家一个满意的答案。

  • 标签: 电影下载 下载方式 FANS BT 电驴 迅雷
  • 简介:Electrolysisofammoniainalkalineelectrolytesolutionwasappliedfortheproductionofhydrogen.BothPt-loadedNifoamandPt-IrloadedNifoamelectrodeswerepreparedbyelectrodepositionandservedasanodeandcathodeinammoniaelectrolyticcell,respectively.TheelectrochemicalbehaviorsofammoniainKOHsolutionwereindividuallyinvestigatedviacyclicvoltammetryonthreeelectrodes,i.e.bareNifoamelectrode,Pt-loadedNifoamelectrodeandPt-IrloadedNifoamelectrode.ThemorphologyandcompositionofthepreparedNifoamelectrodewereanalyzedbyscanningelectronmicroscopy(SEM)andX-raydiffraction(XRD).Effectsoftheconcentrationofelectrolytesolutionandtemperatureofelectrolyticcellontheelectrolysisreactionwereexaminedinordertoenhancetheefficiencyofammoniaelectrolysis.Thecompetitionofammoniaelectrolysisandwaterelectrolysisinthesamealkalinesolutionwasfirstlyproposedtoexplainthechangesofcellvoltagewiththeelectrolysisproceeding.Atvaryingcurrentdensities,differentcellvoltagescouldbeobtainedfromgalvanostaticcurves.Thelowcellvoltageof0.58V,whichislessthanthepracticalelectrolysisvoltageofwater(1.6V),canbeobtainedatacurrentdensityof2.5mA/cm2.Basedonsomeexperimentalparameters,suchastheappliedcurrent,theresultingcellvoltageandoutputofhydrogengas,thepowerconsumptionpergramofH2producedcanbeestimated.

  • 标签: AMMONIA elelctrolysis nickel ELECTRODE hydrogen produciton
  • 简介:Theprocessingoffine-grainedparticleswithdiametersbetween1and10micronsisdifficultduetostrongvan-der-Waalsattractionforces.Inordertoimprovethehandlingproperties,thefine-grainedparticles,i.e.host-particles,arecoatedwithvariousnanoparticles,i.e.guest-particles.Themixingoffine-grainedpowdersisinfluencedbyparticle-particleinteractions.Iftheseforcesaredistinctivelyused,bothinteractiveandorderedmixtu.rescanbeproduced.Theseparticlemixturesconsistofcomposite-particlesthathavenewphysicalproperties.Thesemodifiedpropertiesdependstronglyonthecoatingprocess,thediameter-andmass-relationshipoftheguest-andthehost-particles.Thepropertiesofthecomposite-particlescansystematicallybeadjustedtotherequirementsofindustrialapplications.Forexample,alaboratorybubblingfluidizedbedcanbeusedtodescribetheconveyingbehaviorofthefunctionalizedhost-particles.Applicationsforthefunctionalizedparticlesareinthepharmaceuticalandthepowdercoatingindustries,e.g.enhanceddrypowderinhalersandthinlacquerfilms.Thepresentresearchcomparesthreedifferentmixing/coatingprocesses.Thecomposite-particlesarecharacterizedbyTEM,SEMandwiththeirfluidizationcharacteristics.Thecoatingprocessitselfismonitoredbytheelectrostaticchargeoftheparticles.

  • 标签: 颗粒物质 带电纳米粒子 悬浮液 混合方法 范德瓦尔斯引力
  • 简介:Ageneralprocedureforconstructingmultivariatenon-tensor-productwaveletsthatgen-erateanorthogonaldecompositionofL~2(R~),s≥1,isdescribedandappliedtoyieldexplicitformulasforcompactlysupportedspline-waveletsbasedonthemultiresolutionanalysisofL~2(R~s),1≤s≤3,generatedbyanyboxsplinewhosedirectionsetconstitutesaunimodularmatrix.Inparticular,whenunivariatecardinalB-splinesareconsidered,theminimallysup-portedcardinalspline-waveletsofChuiandWangarerecovered.Arefinedcomputationalschemefortheorthogonalizationofspaceswithcompactlysupportedwaveletsisgiven.Arecursiveapproximationschemefor“truncated”decompositionsequencesisdevelopedandasharperrorboundisincluded.Aconditiononthesymmetryoranti-symmetryofthewaveletsisappliedtoyieldsymmetricbox-splinewavelets.

  • 标签: SPLINE SYMMETRY symmetric univariate MULTIVARIATE refined