简介:Thisworkreportsafeasiblesynthesisofhighly-dispersedPtandPt-Fenanoparticlessupportedonmultiwallcarbonnanotubes(MWCNTs)withoutFeandmultiwallcarbonnanotubeswithiron(MWCNTs-Fe)whichappliedaselectrocatalystsformethanolelectrooxidation.APtcoordinationcomplexsaltwassynthesizedinanaqueoussolutionanditwasusedasprecursortopreparePt/MWCNTs,Pt/MWCNTs-Fe,andPt-Fe/MWCNTsusingFeCl24H2OasironsourcewhichwerenamedS1,S2andS3,respectively.Thecoordinationcomplexofplatinum(TOA)2PtCl6wasobtainedbythechemicalreactionbetween(NH4)2PtCl6withtetraoctylammoniumbromide(TOAB)anditwascharacterizedbyFT-IRandTGA.ThematerialswerecharacterizedbyRamanspectroscopy,SEM,EDS,XRD,TEMandTGA.TheelectrocatalyticactivityofPt-basedsupportedonMWCNTsinthemethanoloxidationwasinvestigatedbycyclicvoltammetry(CV)andchronoamperometry(CA).Pt-Fe/MWCNTselectrocatalystsshowedthehighestelectrocatalyticactivityandstabilityamongthetestedelectrocatalystsduetothattheadditionof'Fe'promotestheOHspeciesadsorptionontheelectrocatalystsurfaceatlowpotentials,thus,enhancingtheactivitytowardthemethanoloxidationreaction(MOR).
简介:Graphiteintercalationcompounds(GIC)weretestedasanexperimentalmodelforstudyingtheelectroniceffectofcarbonsupportonthecatalyticactivityandpoisoningtoleranceofPtcatalystfordirectmethanolfuelcells.TheGICsampleswithdifferentintercalationdegreeswerepreparedbyelectrolyzinggraphiteflakeinH2SO4forvaryingtheperiodsoftime.TheGIC-supportedPtcatalystwasdepositedelectrochemically.ThecatalyticactivityandpoisoningtoleranceoftheGIC-supportedPtcatalystswereevaluated.ItwasfoundthatGICwithsulfateanionasintercalatewasabletocatalyzemethanolelectrooxidation,whichcouldberelatedtothepositivechargesgeneratedonthegraphitelayeruponintercalation.Asintercalationdegreeincreased,thecatalyticactivityoftheGIC-supportedPtcatalystdecreasedwhilethepoisoningtoleranceimproved.ThissuggeststhatelectrondonationfromsupporttocatalysthadgreateffectonbothcatalyticactivityandpoisoningtoleranceofPtcatalyst.Andintercalationcanbeadoptedasanotherimportantwaytomakemodificationoncarboneouscatalystsupport.
简介:ThesinteringofPtnanoparticlesisoneofthemainreasonsforcatalystdeactivationduringthehigh-temperaturepropanedehydrogenation(PDH)reaction.Promotersandsupportshavebeenintroducedtoprolongthecatalystlife.However,itisstillnecessarytodevelopnovelcatalystswithrobuststability.Herein,thephosphorus-modifiedcarbonnanotube-supportedPtnanoparticleswereemployedforthePDHprocess.PhosphorusmodificationimprovesthePtdispersion,effectivelypromotingtheactivityofPt/P-CNTs.Additionally,thephosphorus-modifiedCNTscaninteractstronglywithPtnanoparticlesbyimprovingtheelectrontransferorhybridization,stabilizingPtnanoparticlesfromagglomeration,andsignificantlyenhancingthecatalyststability.
简介:Theaerobicoxidationofglycerolprovidesaneconomicallyviableroutetoglyceraldehyde,dihydroxyacetoneandglycericacidwithversatileapplications,forwhichmonometallicPt,AuandPdandbimetallicAu–Pt,Au–PdandPt–PdcatalystsonTiO2wereexaminedunderbase-freeconditions.PtexhibitedasuperioractivityrelativetoPd,andAu–PdandPt–PdwhileAuwasessentiallyinactive.ThepresenceofAuontheAu–Pt/TiO2catalystsledtotheirhigheractivities(normalizedperPtatom)inawiderangeofAu/Ptatomicratios(i.e.1/3–7/1),andtheonewiththeAu/Ptratioof3/1exhibitedthehighestactivity.SuchpromotingeffectisascribedtotheincreasedelectrondensityonPtviatheelectrontransferfromAutoPt,ascharacterizedbythetemperature-programmeddesorptionofCOandinfra-redspectroscopyforCOadsorption.Meanwhile,thepresenceofAuonAu–Pt/TiO2,mostlikeduetotheobservedelectrontransfer,changedtheproductselectivity,andfacilitatedtheoxidationofthesecondaryhydroxylgroupsinglycerol,leadingtothefavorableformationofdihydroxyacetoneoverglyceraldehydeandglycericacidthatwerederivedfromtheoxidationoftheprimaryhydroxylgroups.ThesynergeticeffectbetweenAuandPtdemonstratesthefeasibilityintheefficientoxidationofglyceroltothetargetedproducts,forexample,byrationaltuningoftheelectronicpropertiesofmetalcatalysts.
简介:大音阶的第五音胶化旋转涂层在Pt/Ti/SiO2/Sisubstrate上准备的Pb(Zr0.4Ti0.6)O-3电影作为最高的电极与磅或Ru被用于铁电体电容器。为thePt/PZT/Pt和Ru/PZT/Pt铁电体电容器,尽管与一样的铁电体他,不同最高的电极材料招致PZT电容器的不同性质例如疲劳,漏,残余、浸透的极化,除了PZTfilm的类似的水晶取向。在(10)10交换周期以后,Ru/PZT/Pt和Pt/PZT/Ptcapacitors的残余的极化分别地减少到70%和84%。在(8)10交换周期以后,后者的漏水流密度在积极偏爱显然增加,与前者相比。为最高的电极的Differentmaterials在PZT/top电极接口带不同条件。在PZT/electrode接口和在到充电注射的PZT/electrode接口的电极材料的氧化物的影响的氧空缺集中的Theinfluence能作为最高的电极与磅或Ru解释PZT电容器的性质的差别。
简介:Abicentralpolymer-supportedphasetransfercatalyst,polystyrene-supportedpolyethyleneglycolandpyridiniumsalt(PS-Py-PEG-400),synthesizedwithchloromethylatedpolystyreneassupporteronwhichPEGandpyridiniumsaltwereimmobilizedsuccessively.ItscatalyticactivitywastestedforthereactionofsolidpotassiumacetateandbenzylbromidebyGCanalysis.ItwasfoundthatthebicentralcatalystperformedhigheractivitythanthemonocentralPS-PEG-400andPS-Py.
简介:ThemetaloxidesCuMnCeandCeYwashcoatsoncordieritewerepreparedusinganimpregnationmethod,andthenusedassupportfortheactivePtcomponenttopreparethePt/CuMnCeandPt/CeYmonolithiccatalystsforthedeepoxidationofVOCs.IncomparisonwiththePt/CeY,CuMnCe,andCeYmonolithiccatalysts,thePt/CuMnCemonolithiccatalystshowsanexcellentperformancefortoluene,ethylacetate,andn-hexaneoxidationandtheT90%islowto216,200and260℃,respectively.TheactivecomponentsPt/PtOandCuMnCeresultinabettersynergeticinteraction,whichpromotethecatalystreducibility,increasetheoxygenmobility,andenhancetheadsorptionandactivationoforganicmolecules.
简介:Electrolysisofammoniainalkalineelectrolytesolutionwasappliedfortheproductionofhydrogen.BothPt-loadedNifoamandPt-IrloadedNifoamelectrodeswerepreparedbyelectrodepositionandservedasanodeandcathodeinammoniaelectrolyticcell,respectively.TheelectrochemicalbehaviorsofammoniainKOHsolutionwereindividuallyinvestigatedviacyclicvoltammetryonthreeelectrodes,i.e.bareNifoamelectrode,Pt-loadedNifoamelectrodeandPt-IrloadedNifoamelectrode.ThemorphologyandcompositionofthepreparedNifoamelectrodewereanalyzedbyscanningelectronmicroscopy(SEM)andX-raydiffraction(XRD).Effectsoftheconcentrationofelectrolytesolutionandtemperatureofelectrolyticcellontheelectrolysisreactionwereexaminedinordertoenhancetheefficiencyofammoniaelectrolysis.Thecompetitionofammoniaelectrolysisandwaterelectrolysisinthesamealkalinesolutionwasfirstlyproposedtoexplainthechangesofcellvoltagewiththeelectrolysisproceeding.Atvaryingcurrentdensities,differentcellvoltagescouldbeobtainedfromgalvanostaticcurves.Thelowcellvoltageof0.58V,whichislessthanthepracticalelectrolysisvoltageofwater(1.6V),canbeobtainedatacurrentdensityof2.5mA/cm2.Basedonsomeexperimentalparameters,suchastheappliedcurrent,theresultingcellvoltageandoutputofhydrogengas,thepowerconsumptionpergramofH2producedcanbeestimated.
简介:Theprocessingoffine-grainedparticleswithdiametersbetween1and10micronsisdifficultduetostrongvan-der-Waalsattractionforces.Inordertoimprovethehandlingproperties,thefine-grainedparticles,i.e.host-particles,arecoatedwithvariousnanoparticles,i.e.guest-particles.Themixingoffine-grainedpowdersisinfluencedbyparticle-particleinteractions.Iftheseforcesaredistinctivelyused,bothinteractiveandorderedmixtu.rescanbeproduced.Theseparticlemixturesconsistofcomposite-particlesthathavenewphysicalproperties.Thesemodifiedpropertiesdependstronglyonthecoatingprocess,thediameter-andmass-relationshipoftheguest-andthehost-particles.Thepropertiesofthecomposite-particlescansystematicallybeadjustedtotherequirementsofindustrialapplications.Forexample,alaboratorybubblingfluidizedbedcanbeusedtodescribetheconveyingbehaviorofthefunctionalizedhost-particles.Applicationsforthefunctionalizedparticlesareinthepharmaceuticalandthepowdercoatingindustries,e.g.enhanceddrypowderinhalersandthinlacquerfilms.Thepresentresearchcomparesthreedifferentmixing/coatingprocesses.Thecomposite-particlesarecharacterizedbyTEM,SEMandwiththeirfluidizationcharacteristics.Thecoatingprocessitselfismonitoredbytheelectrostaticchargeoftheparticles.
简介:Ageneralprocedureforconstructingmultivariatenon-tensor-productwaveletsthatgen-erateanorthogonaldecompositionofL~2(R~),s≥1,isdescribedandappliedtoyieldexplicitformulasforcompactlysupportedspline-waveletsbasedonthemultiresolutionanalysisofL~2(R~s),1≤s≤3,generatedbyanyboxsplinewhosedirectionsetconstitutesaunimodularmatrix.Inparticular,whenunivariatecardinalB-splinesareconsidered,theminimallysup-portedcardinalspline-waveletsofChuiandWangarerecovered.Arefinedcomputationalschemefortheorthogonalizationofspaceswithcompactlysupportedwaveletsisgiven.Arecursiveapproximationschemefor“truncated”decompositionsequencesisdevelopedandasharperrorboundisincluded.Aconditiononthesymmetryoranti-symmetryofthewaveletsisappliedtoyieldsymmetricbox-splinewavelets.