简介:Anewmacrocycliccompoundhasbeensynthesizedbycondensationofpyridine-1-oxide-2,6-dialdehydewithdiethylenetria-mine.Theself-assemlybehaviourswerestudiedbyX-raydiffraction.Theresultsshowthattheself-assemblywerecontrolledbyintermolecularhydrogenbondsandπ-πstackingeffects.
简介:MultilayerthinfilmsofalternatelyadsorbedlayersofpolyelectrolytesPDDAandPS-119wereformedonbothplanarsilicasubstratesandopticalfibersthroughtheionicself-assemblytechnique.IntrinsicFabry-Perotcavitieswerefabricatedbystepwiseassemblingthepolyelectrolytesontotheendsofopticalfibersforthepurposesoffiberopticaldeviceandsensordevelopment.Ionicallyassembledpolyelectrolytemultilayerthinfilms,inwhichtherearehydrophilicsidegroupswithstrongaffinitytowardswatermolecules,areacategoryofhumidity-sensitivefunctionalmaterials.ThepolyelectrolytemultilayerthinfilmFabry-Perotcavity-typefiberopticalhumiditysensorcanworkoverawiderangefromabout0%RHtoabout100%RHwitharesponsetimelessthan1s.
简介:Thispaperreports,forthefirsttime,thatArchaerhodopsin-4(AR4)couldbereconstitutedintophospholipidliposomesbyself-assembly.AR4isanewmembraneproteinisolatedfromhalobacteriaH.sp.xz515inasaltlakeofTibet,China.Thisisabacteriorhodopsin(bR)likeprotein,functionasalight-drivenprotonpump.ExperimentalmeasurementsverifiedthatsimilartobR,ARnotonlyremainsitsbiologicalactivityinpmteoliposome,butalsokeepsapreferredorientationinself-assembly.
简介:Self-assemblednanostructuresoflipidsandnanoparticlesholdgreatpromiseforapplicationsinsuchfieldsasnanomedicine.Thispaperusestheself-consistentfieldtheorytoinvestigatetheself-assemblybehavioroflipidmoleculesandnanoparticleswithdifferentshapesinanaqueoussolution.Itisfoundthatthelipidmoleculescanformmonolayeredandbilayerednanostructuresaroundthenanoparticleswithdifferentshapes(e.g.,triangular,square,hexagonalandoctangular).Withdecreasingthesizeofnanoparticlesorincreasingthenumberofpolygonedges,theshapeoflipidlayerswillapproachanapproximatelysphericalshape.Thesefindingsmayhelptopredictanddesignnoveldrugdeliverynanocarriers.
简介:Inthispaperwereviewourworkonself-assemblyofthesystem,poly(ethyleneoxide)-poly(propyleneoxide)-poly(ethyleneoxide)(PEO-PPO-PEO)blockcopolymers,whichisakindofmacromolecularcomplexfluids.Thecontrolofself-assemblycouldbeobtainedbyaddinginorganicsaltsoraliphaticalcohols.Byself-assemblyofamphiphilicblockcopolymers,amicroemulsionphaseisformed,whichcouldbeappliedinmicelleextraction,suchashollow-fibermembranemicelleextraction,magneticmicelleextractionandimmobilizedmicelleextraction.
简介:Hereinwedemonstratetheconstructionofthreetypesofparallelgoldnanorod(AuNR)clustersusingaDNAorigamirod(DOR)asthetemplate.BasedontheprecisecontroloverthepositionofcapturestrandsonDOR,numberandorientationoftheAuNRclusterscanbewellengineered,asevidencedbybiologicaltransmissionelectronmicroscope(TEM).Importantly,theAuNRclustersexhibitchiropticalresponseswhicharestronglyaffectedbythenumberofAuNRonrod-likeDNAorigami.
简介:Electrostaticlayer-by-layerself-assemblymultilayerfilmsweresuccessfullyfabricatedfromC60-ethylenediamineadduct(C60-EDA)andDNA.Undervisiblelightirradiation,DNAisreadytobecleavedandthefilmsaredestroyed.
简介:钛氧化物(TiO2)上的Ag簇的形成nanoparticles被完成由selfassembly过程和锻烧。获得的nanoparticles被X光检查描绘衍射(XRD),传播电子显微镜学(TEM),和紫外可见光谱学(紫外力),并且常规技术(XRD,TEM并且紫外力)被用来在TiO2表面上识别Ag粒子。结果证明Ag-TiO2粒子能被使用改进苯乙烯氧化物的epoxidation的催化活动。苯乙烯氧化物作为由把Ag-TiO2nanoparticles用作催化剂的氧化剂是有H2O2的催化反应的主要产品。苯乙烯氧化物的高催化的activitity能在80el是可获得的被锻烧在1000
简介:这篇文章介绍一条灵巧的途径给聚苯乙烯/银(PS/Ag)的准备不对称的混合粒子。在这个方法,polystyrene/polyglycidylmethacrylate(PS/PGMA)Janus粒子经由dichloromethane(DCM)的蒸发从PS/PGMA/DCM-in水乳剂微滴触发的内部阶段分离被综合。然后,Janus粒子是aminated并且顺序获得PS/PGMA-NH2和PS/PGMA-COOH粒子的carboxylated。在由与amine/carboxyl协调的functionalizedPS/PGMA粒子的PGMA半球的表面上自我装配的Ag+。有Ag的7.29wt%的PS/Ag不对称的混合粒子被Ag+的减小获得。扫描电子显微镜学,精力散的X光检查光谱学和传播电子显微镜学结果证实Ag在聚合物粒子的表面上是不均匀地分布式的。
简介:Thenanomaterialsoftenexhibitveryinterestingelectrical,optical,magnetic,andchemicalproperties,whichcannotbeachievedbytheirbulkcounterparts[1-7].Thedevelopmentofuniformnanometersizedparticleshasbeenintensivelypursuedbecauseoftheirtechnologicalandfundamentalscientificimportance[8-15].Itissignificantthatnanostructuredmaterialscanbecontrollablyassembledintotherequiredgeometryontosubstrates,becomingthebasisofthenextgenerationofcomponentsanddevices[16-31].Thedevelopmentofnewmethodsandstrategiesfororganizingthenanoparticlebasicbuildingblocksintothedesiredstructuresisrequired.Superlatticesmadefromthesebuildingblocksgiveustheopportunitytostudynotonlythepropertiesoftheindividualbuildingblocks,butalsocollectiveeffects.Thesuperparamagneticironoxidenanocrystals(NCs)havebeenusedinthefieldsofbio-medicine,ferrofluids,refrigerationsystem,catalysis,particularlyinmagneticresonanceimaging,tissueengineering,anddrugdeliveryapplications[32-42].
简介:Inthiswork,wereporttheconstructionofthree-dimensional(3D)CdSnanosphere/graphenenetworksbyaone-stephydrothermalself-assemblyroute.The3Dgraphenenetworksnotonlyenhancethelightscattering,thankstotheinterconnected3Darchitecture,butalsoimprovethecrystallinityofdepositedCdSnanospheres,andatthesametimeprovideadirectelectronpathwaytoquicklyseparatethephotogeneratedelectron-holepairsfromCdS,whichthusdramaticallyimprovethephotocatalyticactivity.Theoptimized3DCdSnanosphe/graphenenetworkswith2wt%ofgraphenecouldproducemolecularhydrogenatarateof2310pmolgcatalyst^-1h^-1undervisible-lightillumination(λ>400nm).