简介:Theadsorptionprocessesofantibioticsofthetetracylinegroup(ATG)byseveralhome-madesulfocationitesarestudiedinthispaper.TheresultsshowthattheadsorptionmaybeofnonequivalentnormalityundercertainpHcondition.Theadsorptionmechanismisdiscussedwithinfraredspectrometry.ItcanbeconcludedthatATGcaninteractwithsulfocationitesbyionexchangemechanismorion-transfermechanismorbothofthem.
简介:Theadsorptionof2,4-dinitrophenoland2,6-dinitrophenolonnon-polarandpolaradsorbentswasstudied.TheresultsshowedthattheequilibriumadsorptiondidnotcomplywiththeLangmuirequationandwasnotmono-layeradsorption.ItisofinteresttonoticethattheeffectofpHontheadsorptionof2,4-or2,6-dinitrophenolontoADS-7andADS-21wasverysmall,Theresultisexplainedbyhydrogenbondinginteractionbetween2,4-or2,6-dinitrophenolandtheadsorbentADS-21.ThelargeadsorptioncapacityofdinitrophenolontoADS-21,whichwasabout500mg/gatanequilibriumconcentrationof400mg/L,andthesmalldinitrophenolleakageintheeffluentfromADS-21columnpresentedagoodprospectfortreatmentofwastewatercontainingdinitrophenolwithadsorbentADS-21.
简介:Sphericalcrosslinkedpolystyrene-isocyanuricacidresinwassynthesizedbyreactionofchloromethylatedpolystryenewithisocyanuricacid.Thesorptionisothermsofphenolfromaqueoussolutionandcyclohexanesolutionontotheresinweremeasured.Itisofinteresttonoticethattheresinsorbedphenolefficientlythoughitsspecificsurfaceareawas0anddidnotswellinwater,andthesorptioncapactityfromaqueoussolutionwasclosetothatofphenolontoXAD-4atthesameequilibriumconcentration.SorptionenthalpiescalculatedfromtheisothermsaccordingtotheClausius-Clapeyronequationwere-21-25kJ/moland-39-41kJ/molrespectively.Thesevaluesimpledthatthesorptionprocesseswerebasedonhydrogenbonding.Inaddition.thedetailsofthehydrogenbondingbetweentheactivesitesoftheresinandphenolweresuggested.
简介:SYSWELDwasusedtosimulatein-serviceweldingprocessofgaspipelineofX70pipelinesteel.Weldingthermalcycle,stressanddeformationofin-serviceweldedjointwerestudied.Theresultsshowthatpeaktemperatureofcoarsegrainheat-affectedzone(CGHAZ)ofin-serviceweldingontogaspipelineisthesamewithroutinewelding,butt_(8/5),t_(8/5)andt_(8/1)decreaseatcertaindegree.Forthezonenearweldedseam,axialstressandhoopstressintheinnerpipewallarecompressivestresswhenweldingsourcepassesthroughthecross-sectionthatisstudied,butresidualaxialstressandresidualhoopstressafterweldedarealltensilestress.Transientdeformationandresidualdeformationareallconvexdeformationcomparedwiththeoriginalpipediametersize.Deformationachievesmaximumwhenweldingthermalsourcepassesthroughthecross-sectionthatisstudiedandthendecreasesduringthecoolingprocessafterwelding.
简介:Dual-platestructureisveryeffectiveintheprotectionofspacevehiclefromhypervelocityim-pact.TheexperimentsofA1projectileimpactingA1dualtargetsatthevelocityrangingover2.5—7.0km/sweresystematicallyconducted.Thedamageeffectswereexamined,includingtheperforationoftheshield,thedevelopmentofdebriscloudandthegeneraldamagecharacteristicsofthesubplate.Manyvaluableexperi-mentaldataandphenomenahavebeenobtained
简介:WepresentaparalleliterativealgorithmtofindtheshortestdistanceprojectionofagivenpointontotheintersectionofafinitenumberofclosedconvexsetsinarealHilbertspace;thenumberofsetsusedateachiterationsteptcorrespondingtothenumberofavailableprocessors,maybesmallerthanthetotalnumberofsets.TherelaxationcoefficientateachiterationstepisdeterminedbyageometricalconditioninanassociatedHilbertspace,whilefortheweightsmildconditionsaregiventoassurenormconvergenceoftheresultingsequence.Thesemildconditionsleaveenoughflexibilitytodeterminetheweightsmorespecificallyinordertoimprovethespeedofconvergence.
简介:与钾每硫酸盐(KPS)作为开始者,ethylacrylate(EA)的接枝共聚化合物在水介质被调查到水溶性的hydroxypropyl纤维素甲醚(HPMC)上。grafting(G)和grafting效率(G_E)的百分比上的单体集中,开始者集中,矩阵集中,和反应温度的效果被学习。结果显示出价值两个都增加与的那G和G_EEA集中andKPS集中的增加;当从0提起HPMC集中时。12mmol/L到0.47mmol/L,G减少,当G_E增加时;并且当从50℃提起反应温度到65℃时,G增加,但是G_Edecreases。另外,接枝共聚物被Fourier变换描绘红外线(英尺红外)系列和传播电子显微镜学(TEM)方法。
简介:Immobilizingbiocomponentsonsolidsurfacesisacriticalstepinthedevelopmentofnewdevicesforfuturebiological,medical,andelectronicapplications.Therefore,numerousintegratedfilmswererecentlydevelopedbyimmobilizingdifferentproteinsorenzymesonelectrodesurfaces.Inthiswork,hemeproteinsweresafelyimmobilizedontomacroporousnickel-basedelectrodeswhilemaintainingtheirfunctionality.Suchmodifiedelectrodesshowedinterestingpseudo-capacitivebehavior.Amonghemeproteins,hemoglobin(Hb)filmhasahigherelectrochemicalperformanceandgreatercharge/dischargecyclingstabilitythanmyoglobin(Mb)andcytochromeC(CytC).Thehemegroupinanalkalinemediumcouldinducetheformationofsuperoxidesontheelectrodesurface.Thesecapacitivefeaturesofhemeprotein-NielectrodewererelatedtostrongbindingsitesbetweenhemeproteinsandporousNielectrode,theaccumulationofsuperoxideorradicalsontheNisurface,andfacileelectrontransferandelectrolytediffusionthroughthethree-dimensionalmacroporousnetwork.Thus,thesenewprotein-basedsupercapacitorshavepotentialuseinfree-standingplatformtechnologyforthedevelopmentofimplantableenergy-storagedevices.
简介:HeparinwascovalentlyimmobilizedontopolyurethanesurfaceviaaPEGspacerbyamicrowave-assistedapproachtoimprovebloodcompatibility.Firstly,amino-terminatedpoly(ethyleneglycol)(APEG)wasrapidlygraftedontoPUsurfacewithin20minbyatwo-stepmethodinvolvingmicrowave-assistedMDI-functionalizationandsubsequentmicrowave-assistedAPEGcoupling.Then,heparinwascovalentlyimmobilizedthroughanamidelinkagebythedirectcouplingofthecarboxylicacidofheparinwiththeaminogroupofAPEGonPUsurfaceusingcarbodiimidecouplingreaction.ThesurfacestructureandpropertieswerecharacterizedbyX-rayphotoelectronspectroscopy(XPS),atomicforcemicroscopy(AFM)andwatercontactanglemeasurements.Theresultsrevealedthatheparin-immobilizedPUsurfacehadslightlyincreasedroughnessandsignificantlyimprovedhydrophilicityincomparisontotheoriginalPUsurface.Theanticoagulantactivityoffilmswasevaluatedbywholebloodclottingtime(CT)andprothrombintime(PT).Complementactivationwasassessedbydetectingcomplementfragment3aconcentrationsofserumexposedtothefilms.Theresultsrevealedthatthemicrowave-assistedheparin-immobilizedPUfilmshadexcellentantithrombogenicityandsuppressedcomplementactivation,indicatingimprovedbloodcompatibility.