学科分类
/ 2
40 个结果
  • 简介:Theadsorptionprocessesofantibioticsofthetetracylinegroup(ATG)byseveralhome-madesulfocationitesarestudiedinthispaper.TheresultsshowthattheadsorptionmaybeofnonequivalentnormalityundercertainpHcondition.Theadsorptionmechanismisdiscussedwithinfraredspectrometry.ItcanbeconcludedthatATGcaninteractwithsulfocationitesbyionexchangemechanismorion-transfermechanismorbothofthem.

  • 标签: 吸附性 抗菌素 抗生素 四环素 磺基阳离子交换剂 离子交换机理
  • 简介:Theadsorptionof2,4-dinitrophenoland2,6-dinitrophenolonnon-polarandpolaradsorbentswasstudied.TheresultsshowedthattheequilibriumadsorptiondidnotcomplywiththeLangmuirequationandwasnotmono-layeradsorption.ItisofinteresttonoticethattheeffectofpHontheadsorptionof2,4-or2,6-dinitrophenolontoADS-7andADS-21wasverysmall,Theresultisexplainedbyhydrogenbondinginteractionbetween2,4-or2,6-dinitrophenolandtheadsorbentADS-21.ThelargeadsorptioncapacityofdinitrophenolontoADS-21,whichwasabout500mg/gatanequilibriumconcentrationof400mg/L,andthesmalldinitrophenolleakageintheeffluentfromADS-21columnpresentedagoodprospectfortreatmentofwastewatercontainingdinitrophenolwithadsorbentADS-21.

  • 标签: 聚合吸附剂 二硝基苯酚 吸收
  • 简介:在这篇论文,在另外的事情之中,作者学习弱*关上的左翻译半组代数学和组代数学的不变的补充潜水艇空间。另外,作者学习在设计和顺从之间的关系。

  • 标签: 代数 余格 平移运动 子空间
  • 简介:Inthispaper,theradiationgraftcopolymerofMgO,SiO2andY-molecularsieveontoorganiccompounds,suchasmethacrylate,styreneandacrylomitrileobtainedbyper-radiationmethodwerecharacterizedbyX-raydiffraction,pyrolysisgaschromatography,GPCandX-rayphotoelectronspectroscopy.

  • 标签: 辐射接枝共聚物 无机化合物 烯烃 有机化合物
  • 简介:Sphericalcrosslinkedpolystyrene-isocyanuricacidresinwassynthesizedbyreactionofchloromethylatedpolystryenewithisocyanuricacid.Thesorptionisothermsofphenolfromaqueoussolutionandcyclohexanesolutionontotheresinweremeasured.Itisofinteresttonoticethattheresinsorbedphenolefficientlythoughitsspecificsurfaceareawas0anddidnotswellinwater,andthesorptioncapactityfromaqueoussolutionwasclosetothatofphenolontoXAD-4atthesameequilibriumconcentration.SorptionenthalpiescalculatedfromtheisothermsaccordingtotheClausius-Clapeyronequationwere-21-25kJ/moland-39-41kJ/molrespectively.Thesevaluesimpledthatthesorptionprocesseswerebasedonhydrogenbonding.Inaddition.thedetailsofthehydrogenbondingbetweentheactivesitesoftheresinandphenolweresuggested.

  • 标签: 树脂 苯酚 吸收
  • 简介:在神经氧化铝上支持的Tungstophosphoric酸(HPW)催化剂被学习。它借助于平衡和早期的湿受精技术被准备。在50%V/V乙醇水的HPW的答案被用来在25℃使Al_2O_3妊娠。在500℃由锻烧包含30%PW的催化剂在缩荃或ketals的合成显示出更高的催化活性,这被发现。处于下列条件,也就是说臼齿的比率ofaldehyde/ketone到乙二醇是1:1.5,使用的催化剂的集体部分是0.5%,并且在那里,行动时间是1.0h;ketals和缩荃的收益能到达直到60.5%-86.7%。而且,它能容易被恢复并且再使用。

  • 标签: 钨磷杂多酸 中性氧化铝载体 催化特性 缩醛 缩酮 合成
  • 简介:SYSWELDwasusedtosimulatein-serviceweldingprocessofgaspipelineofX70pipelinesteel.Weldingthermalcycle,stressanddeformationofin-serviceweldedjointwerestudied.Theresultsshowthatpeaktemperatureofcoarsegrainheat-affectedzone(CGHAZ)ofin-serviceweldingontogaspipelineisthesamewithroutinewelding,butt_(8/5),t_(8/5)andt_(8/1)decreaseatcertaindegree.Forthezonenearweldedseam,axialstressandhoopstressintheinnerpipewallarecompressivestresswhenweldingsourcepassesthroughthecross-sectionthatisstudied,butresidualaxialstressandresidualhoopstressafterweldedarealltensilestress.Transientdeformationandresidualdeformationareallconvexdeformationcomparedwiththeoriginalpipediametersize.Deformationachievesmaximumwhenweldingthermalsourcepassesthroughthecross-sectionthatisstudiedandthendecreasesduringthecoolingprocessafterwelding.

  • 标签: 油气管道 在役焊接 数值模拟 热循环 应力 形变
  • 简介:Dual-platestructureisveryeffectiveintheprotectionofspacevehiclefromhypervelocityim-pact.TheexperimentsofA1projectileimpactingA1dualtargetsatthevelocityrangingover2.5—7.0km/sweresystematicallyconducted.Thedamageeffectswereexamined,includingtheperforationoftheshield,thedevelopmentofdebriscloudandthegeneraldamagecharacteristicsofthesubplate.Manyvaluableexperi-mentaldataandphenomenahavebeenobtained

  • 标签: HYPERVELOCITY impact dual-plate structure PERFORATION damage
  • 简介:WepresentaparalleliterativealgorithmtofindtheshortestdistanceprojectionofagivenpointontotheintersectionofafinitenumberofclosedconvexsetsinarealHilbertspace;thenumberofsetsusedateachiterationsteptcorrespondingtothenumberofavailableprocessors,maybesmallerthanthetotalnumberofsets.TherelaxationcoefficientateachiterationstepisdeterminedbyageometricalconditioninanassociatedHilbertspace,whilefortheweightsmildconditionsaregiventoassurenormconvergenceoftheresultingsequence.Thesemildconditionsleaveenoughflexibilitytodeterminetheweightsmorespecificallyinordertoimprovethespeedofconvergence.

  • 标签:
  • 简介:与钾每硫酸盐(KPS)作为开始者,ethylacrylate(EA)的接枝共聚化合物在水介质被调查到水溶性的hydroxypropyl纤维素甲醚(HPMC)上。grafting(G)和grafting效率(G_E)的百分比上的单体集中,开始者集中,矩阵集中,和反应温度的效果被学习。结果显示出价值两个都增加与的那G和G_EEA集中andKPS集中的增加;当从0提起HPMC集中时。12mmol/L到0.47mmol/L,G减少,当G_E增加时;并且当从50℃提起反应温度到65℃时,G增加,但是G_Edecreases。另外,接枝共聚物被Fourier变换描绘红外线(英尺红外)系列和传播电子显微镜学(TEM)方法。

  • 标签: 接枝共聚 乙烷基丙烯酸脂 羟基丙基甲基纤维素 过硫酸钾 引发剂
  • 简介:Immobilizingbiocomponentsonsolidsurfacesisacriticalstepinthedevelopmentofnewdevicesforfuturebiological,medical,andelectronicapplications.Therefore,numerousintegratedfilmswererecentlydevelopedbyimmobilizingdifferentproteinsorenzymesonelectrodesurfaces.Inthiswork,hemeproteinsweresafelyimmobilizedontomacroporousnickel-basedelectrodeswhilemaintainingtheirfunctionality.Suchmodifiedelectrodesshowedinterestingpseudo-capacitivebehavior.Amonghemeproteins,hemoglobin(Hb)filmhasahigherelectrochemicalperformanceandgreatercharge/dischargecyclingstabilitythanmyoglobin(Mb)andcytochromeC(CytC).Thehemegroupinanalkalinemediumcouldinducetheformationofsuperoxidesontheelectrodesurface.Thesecapacitivefeaturesofhemeprotein-NielectrodewererelatedtostrongbindingsitesbetweenhemeproteinsandporousNielectrode,theaccumulationofsuperoxideorradicalsontheNisurface,andfacileelectrontransferandelectrolytediffusionthroughthethree-dimensionalmacroporousnetwork.Thus,thesenewprotein-basedsupercapacitorshavepotentialuseinfree-standingplatformtechnologyforthedevelopmentofimplantableenergy-storagedevices.

  • 标签: 超级电容器 蛋白质固定 电极表面 泡沫材料 大孔 镍基
  • 简介:HeparinwascovalentlyimmobilizedontopolyurethanesurfaceviaaPEGspacerbyamicrowave-assistedapproachtoimprovebloodcompatibility.Firstly,amino-terminatedpoly(ethyleneglycol)(APEG)wasrapidlygraftedontoPUsurfacewithin20minbyatwo-stepmethodinvolvingmicrowave-assistedMDI-functionalizationandsubsequentmicrowave-assistedAPEGcoupling.Then,heparinwascovalentlyimmobilizedthroughanamidelinkagebythedirectcouplingofthecarboxylicacidofheparinwiththeaminogroupofAPEGonPUsurfaceusingcarbodiimidecouplingreaction.ThesurfacestructureandpropertieswerecharacterizedbyX-rayphotoelectronspectroscopy(XPS),atomicforcemicroscopy(AFM)andwatercontactanglemeasurements.Theresultsrevealedthatheparin-immobilizedPUsurfacehadslightlyincreasedroughnessandsignificantlyimprovedhydrophilicityincomparisontotheoriginalPUsurface.Theanticoagulantactivityoffilmswasevaluatedbywholebloodclottingtime(CT)andprothrombintime(PT).Complementactivationwasassessedbydetectingcomplementfragment3aconcentrationsofserumexposedtothefilms.Theresultsrevealedthatthemicrowave-assistedheparin-immobilizedPUfilmshadexcellentantithrombogenicityandsuppressedcomplementactivation,indicatingimprovedbloodcompatibility.

  • 标签: SURFACE modification microwave IRRADIATION HEPARIN POLYURETHANE