简介:<正>Inthisresearchwork,threekindsofactivatedbentoniteusedassolidacidcatalystshadbeensynthesizedandstudiedonremovalofolefinsfromthereformateoil.ActivatedbentonitesampleswereanalyzedusingtheBETandpyridine-FTIRmeasurementstoinvestigatetheirphysicalandchemicalproperties.Theresultsshowedthatbothtexturalpropertiesandsurfaceacidityofthebentonitecouldaffectthecatalyticactivity.Amongthecatalystsamples,onekindofbentonitepurchasedfromHubeiwithhighsurfacearea,highporevolumeandmoreacidsitesrevealedhighactivityinremovingolefinsfromthereformate.
简介:Thedensityofasphaltwasmeasuredwiththepycnometeranddensitometer.Creeppropertiesoftheasphaltwereinvestigatedwiththebendingbeamrheometerattemperaturesrangingfrom0℃to-36℃.Theasphaltdensitydatausedtocorrelatewiththecreeppropertieswerecalculatedfromtheregressionequationofdensityandtemperature.TheasphaltsampleusedtodeterminethecreeppropertywasagedbythestandardRTFOTtestandthePAVtest.Thetestresultsshowedthattheasphaltdensityhadalinearrelationshipwithtemperaturechanges.Thelogarithmofthecreepstiffnessandtheslopeofthelogarithmofthestiffnessat60secondsalldemonstratedalinearrelationshipwiththedensity,andtheregressioncoefficientofthesedatawasaround0.99.Thecreepstiffnessandtheslopeofthecreepstiffnesscanbecalculatedfromtheasphaltdensityatthesametemperature.
简介:Inordertostudytheflammabilityandexplosionpropertyofgasesduringthepropaneoxidationtoacrylicacidprocess,theexplosionlimitsandthesafetyoxygencontentofgasesattherecyclegascompressoroutlet,thereactorinlet,andthereactoroutletweretheoreticallycalculatedandexperimentallytested.Finally,theinertlimitwasalsodetermined.Itshowedthatgasesattherecyclegascompressoroutletandthereactoroutletwerenonflammablebasedonthreeindicators:theexplosionlimits,thesafetyoxygencontentandtheinertlimit.TheC3H6andO2contentswerehigheratthereactorinlet,whichmadethemixedgaseseasilyignitable.However,thelargeamountofinertgasessuppressedthepossibilityofexplosioneffectively.Asaconsequence,noexplosionphenomenonwouldhappeninallthreelocations.Butgasesatthereactorinletaremostdangerous,wheremoresupervisionontheconcentrationofgasesandmorestrictcontrolonthetemperatureandpressureshouldbeimplemented.Besidesthis,openflame,hotsurfacesandothersourcesofignitionareprohibitedinworkingspaces.Theexperimentalresultscanbeappliedtosimilarprocessforoxidationofpropane.