简介：InordertoimprovethehydrogenationanddehydrogenationperformancesoftheMg2Ni-typealloys,MgwaspartiallysubstitutedbyLainthealloy,andmeltspinningtechnologywasusedforthepreparationoftheMg20-xLaxNi10(x=0,2,4,6)hydrogenstoragealloys.ThestructuresofthealloyswerestudiedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andhigh-resolutiontransmissionelectronmicroscopy(HRTEM).Itwasfoundthatnoamorphousphaseformedintheas-spunLa-freealloy,buttheas-spunalloyscontainingLaheldamajoramorphousphase.WhenLacontentx≤2,themajorphaseintheas-castalloyswasMg2Niphase,butwithfurtherincreaseofLacontent,themajorphaseoftheas-castalloyschangedintoLaNi5+LaMg3phase.Thermalstabilityoftheas-spunalloyswasstudiedbydifferentialscanningcalorimetry(DSC),showingthatspinningratewasanegligiblefactoronthecrystallizationtemperatureoftheamorphousphase.Thehydrogenabsorptionanddesorptionkineticsoftheas-castandas-spunalloysweremeasuredusinganautomaticallycontrolledSievertsapparatus,confirmingthatthehydrogenabsorptionanddesorptioncapacitiesandkineticsoftheas-castalloysclearlyincreasedwithrisingLacontent.ForLacontentx=2,theas-spunalloydisplayedoptimalhydrogendesorptionkineticsat200°C.

简介：采用水热法制备表面活性剂聚甲基丙烯酸-季戊四醇四-3-巯基丙酸酯(PTMP-PMAA)修饰的具有光热效应的纳米WO3-x粉末,通过X射线衍射(XRD)分析、透射电镜(TEM)观察、X射线光电子能谱(XPS)分析、傅里叶变换红外光谱(FT-IR)分析以及紫外-可见吸收光谱(UV-Vis谱)分析及光热性能测试等,研究所得纳米粉体材料的结构及其在不同浓度与pH值下的光热性能。结果表明,水热法制备的WO3-x粉末为球形的非整比结构的W17O47,粒径小于10nm。随WO3-x的pH值降低或质量浓度降低,粉末的紫外吸光度增加,光热效应提高。pH值为6.4、质量浓度为800μg/mL的WO3-x经光热转换后,可实现在5min内约19℃的温度上升。考虑到人体体温为37℃,肿瘤部位的pH值为6.0~6.5之间,此质量浓度下纳米WO3-x粉末可用于光热治疗并实现对肿瘤细胞的杀伤效果。

简介：通过对亚硫酸钠工艺和SUPCONJX－300X集散系统结构的介绍，论述控制难点及组态、调试过程中需注意的问题。

简介：不锈钢炼钢冶炼跨天车作为不锈钢炼钢的核心设备，天车板钩动滑轮片更换的检修时间长、检修难度大，因此考虑对天车板钩动滑轮片更换检修方案进行归类总结优化，以便缩短检修时间，提高检修效率。

简介：12月3日，中国稀土行业协会光功能材料分会座谈会在广东江门召开。中国稀土行业协会马荣璋秘书长，光功能材料分会万国江会长、吴虹秘书长，以及光功能材料分会伞体会员单位的代表参加了此次会议。

简介：以钛粉,硅粉和石墨粉为原料,采用放电等离子烧结技术制备密度为4.14g/cm^3的Ti3SiC2和密度为4.03g/cm^3的0.8Ti3SiC2＋0.2SiC复合材料,并以此为基础制备Ti/Ti3SiC2/0.8Ti3SiC2＋0.2SiC层状材料。通过扫描电镜（SEM）和X射线衍射仪（XRD）分析材料的显微结构与相组成。结果表明：该层状材料的界面结合紧密,没有明显的孔洞、裂纹等缺陷,各层的相组成符合设计要求。经800℃热处理40h后Ti/Ti3SiC2界面处生成稳定的TiC层,在高温下该层状材料的界面基本稳定。

简介：Duetotheremarkablemagnetoresistance(MR)effectonperovskite-typemanganite,magnetoelectronicsandspintronicshavebecomeattractivesubjectsofexperimentalandtheoreticalinvestigationsfortheapplicationpurpose.(La0.9Nd0.1)2/3Ca1/3Mn1-xFexO3(x=0,x=0.05)werepreparedsuccessfullybysol-gelmethod.Thestructure,magneticproperties,andtransportpropertiesofthecompoundswereinvestigated.Themagnetoresistanceeffectdependsonthecompositionandthetemperature.XRDpatternsshowthatthecompoundisasinglephasepolycrystalwithpseudocubicstructure.Alargenegativeisotropicmagnetoresistanceeffectinthesampleswereobservedatlowtemperatureregion.ThemaximumMRofthesampleswas77%and97%,respectively.Itwasmostlikelyduetothescatteringorthetunnelingtransportofspin-polarizedcarriersinlatticeunderstrongmagneticfield.

简介：通过对精轧阶段不同组合的除鳞道次试验,采用SEM对钢板表面氧化皮及脱落氧化皮厚度进行对比研究。结果发现:精轧除鳞两道次且末道次不除鳞的条件下,氧化铁皮厚度未有明显变化,增加最后一道次除鳞后氧化铁皮厚度显著降低。

简介：

简介：NominalcompositionofCa1-xZnxTiO3:0.002Pr3+(x=0.000～0.200)phosphorswerepreparedbyconventionalsolidreactionroute.XRDandPLmeasurementswereusedtoinvestigatethesolid-solutionstructureandluminescencepropertiesofZn-dopedCa1-xZnxTiO3:0.002Pr3+phosphors.Theeffectofsolid-solutionstructureformedbysubstitutionbetweenCa2+andZn2+ionsontheluminescentpropertieswasanalyzed.Theresultsrevealthat,withtheincreaseofZnsubstitutioncontentbelow0.010,latticeparametersandtheintensityofexcitationpeakatboth260and330nmaswellasthecorresponding610nmemissionintensityaremonotonouslydecreasedquicklyinasimilartendency.Also,theevolutionofluminescenceintensityandcrystalcellparametersagainstZndopingconcentrationareingoodagreement.AboveresultsarecloselyrelatedwiththestructurechangewithinCa1-xZnxTiO3:0.002Pr3+solid-solutionphaseformedbytheZnionssubstitutionfortheCasites.Presentstudyrevealsthatthesolid-solutionstructureformedbysubstitutionbetweenCa2+andZn2+ionshassignificanteffectontheluminescencepropertiesofsinglephaseCa1-xZnxTiO3:0.002Pr3+phosphors.

简介：用X-射线荧光光谱法(XRF)[2-3]对锰矿中全锰、全铁、二氧化硅和磷元素进行分析,采用溴化锂做脱模剂,考虑到溴元素对锰的干扰,提出用溴元素来校正锰,取得了较好的分析效果。且该方法分析速度快,准确度高。

简介：德国知名设备制造商西马克集团前不久宣布获得了韩国浦项钢铁（POSCO）SNNC公司光阳厂所需的世界上最大的六电极埋弧炉设备订单。浦项钢铁SNNC公司是浦项钢铁集团旗下镍铁分公司，在韩国光阳生产镍铁。

简介：用溶胶-凝胶法制备镍锌共掺杂Z型锶钴铁氧体Sr3（NiZn）xCo2（1-x）Fe24O41（x=0～0.5）粉末。用X射线衍射（XRD）和扫描电镜（SEM）表征该铁氧体粉末的晶体结构和表面形貌，并测试其室温磁滞回线和室温电阻率。用微波矢量网络分析仪测定该粉末在2～18GHz微波频率范围的复介电常数和复磁导率，根据测量数据计算电磁损耗角正切及微波反射率，分析该材料的微波吸收性能与电磁损耗机理。结果表明：Sr3（NiZn）xCo2（1-x）Fe24O41粉末呈六角片状形貌，晶体结构为Z型，具有良好的软磁特性；x=0.3时该材料的电阻率最低，微波吸收效果最好，在13.5GHz频率的吸收峰为25.1dB，10dB频带宽度为7.7GHz，兼具强的磁损耗和弱的介电损耗。

简介：Whitelight-emittingYVO_4：1mol.%Dy~（3＋）,xmol.%Eu~（3＋）phosphorpowderswithordermorphologyandwellcrystallizationwerehydrothermallysynthesizedat180°C.Themicrostructure,white-lightemission,andlight-emittingmechanismofthepowderswerecarefullystudiedusingX-raydiffractometry,scanningelectronmicroscopyandphotoluminescencespectra.TheexcitationandemissionspectraofthephosphorpowdersindicatedthecoexistenceofefficientenergytransferfromEu~（3＋）toDy~（3＋）andinefficientenergytransferfromDy~（3＋）toEu~（3＋）besidestheenergytransferfromVO_4~（3–）toEu~（3＋）.IncreasingtheEu~（~（3＋））concentrationinitiallyenhancedandthenweakenedtheluminescentintensityofDy~（3＋）.Thewhite-lightemissionsofYVO_4：1mol.%Dy~（3＋）,xmol.%Eu~（3＋）phosphorpowderswerebothrelatedtotheenergytransferbetweenVO_4~（3–）andDy~（3＋）/Eu~（3＋）,aswellasbetweenEu~（3＋）andDy~（3＋）.TheinefficientenergytransferfromDy~（3＋）toEu~（3＋）wasfirstfound.