简介：通过分析三钢200m^2烧结机的点火现状及原因,提出了低负压点火烧结技术的改造方案。生产实践表明:改造后烧结料层厚度提高了54mm,烧结矿产量增加了4t/h,点火煤气消耗降低了159m^3/h,取得了良好的经济效益。

简介：Er~（3＋）andLa~（3＋）codopedY_2O_3nanocrystallinepowdersweresynthesizedbygelcombustionmethodandcharacterizedwiththermalanalysis,X-raydiffraction（XRD）,transmissionelectronmicroscopy（TEM）,high-resolutionTEM（HRTEM）techniquesandfluorescencespectroscopy.Afterbeingcalcinedat1200oC,the（Y_（1–x）La_x）_2O_3：Er~（3＋）powderswereconfirmedtobecubicY_2O_3phasewiththecrystallinegrainsizeintherangeof20–40nm.TheEr~（3＋）emissionat1.53μmfromthe~4I_（13/2）→~4I_（15/2）transitionwasobserved,whichwasfoundtobeenhancedbyintroducingLa~（3＋）ions.SuchenhancementcouldbeattributedtotheadjustmentofEr~（3＋）ions＇localenvironmentbythecodopingofLa~（3＋）ions,leadingtotheincreasedgroundstateabsorptioncrosssectionofEr~（3＋）ions.

简介：铟生产废水中含锌砷镉杂质较高,且含有机物的酸性溶液。铟生产废水处理过程中,首先用纯碱中和废水,至pH值为8左右,大部分杂质沉入中和渣中;然后用硫酸亚铁和双氧水净化,废水达到国家工业排水一级标准。废水处理后进行了回用,实现了零排放,锌富集到中和渣,回收利用。处理过程没有废气产生,工序简单,安全环保。

简介：EffectsofNbandZrsubstitutionsonthecrystal]izationbehaviorsandmagneticpropertiesofmelt-spun(Nd,Pr)2Fe14B/α-Fealloyswerestudied.Theresultsshowthatfor(Nd0.4Pr0.6)8.5Fe85.5B6ribbons,themetastable(Nd,Pr)3Fe62B14precipitatesaftertheinitialcrystallizationofα-Feanddecomposesintothefinalmixtureof(Nd,Pr)2Fe14Bandα-Fe.For(Nd0.4Pr0.6)8.5Fe84.5Zr0.5Nb0.5B6ribbons,however,(Nd,Pr)2Fe14Bandα-Fephasesprecipitatesimultaneously.ThisindicatesthatbothNbandZrdopingcanavoidtheformationofmetastablephaseand!

简介：针对GKD2型内燃机车电空接触器存在的烧损故障问题，结合电空接触器结构特点和电路原理从理论上进行了分析，提出了相应的改进措施和建议，保证了电空接触器无电状态下闭合和分断。对电空接触器触头的技术状态进行测试，开距、超程、压力和研距控制在规定的范围内，为确保机车正常运用发挥了重要作用。

简介：TheextractionofCe(Ⅳ)inH2SO4/H3PO4systemwasinvestigatedsystematicallyusingbifunctionalionicliquidextractants(Bif-ILES)[A336][P507],[A336][P204]and[A336][C272]inn-heptane.TheeffectsofH2SO4concentration,extractantconcentrationandsalting-outagentconcentrationwereobservedindetail.TheextractionmechanismofCe(Ⅳ)inH2SO4/H3PO4systemwasobtained.ThecomparisonwithotherextractantssuchasCyanex923,TBPwasalsostudied.Thermodynamicfunctionsoftheextractionreactionwerecalculated,showingthattheextractionwasanexothermicprocess.TheseparationofCe(Ⅳ)fromRE(Ⅲ)andTh(Ⅳ)wasalsoinvestigated.TheresultindicatedthatCe(Ⅳ)couldbeselectivelyextractedinthissystem.CePO4nanoparticleswereobtainedintheprocessofstrippingusingH2O2inH2SO4/H3PO4system.X-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andspectroscopywereadoptedforthecharacterizationofthesample.

简介：海关统计表明，1～7月，内蒙古自治区出口稀土2562．6吨，同比增加1．6倍，占同期我国稀土出口总量的23．6％；价值3106．2万美元，下降了0．2％，占同期出口总值的12．4％；出口均价每吨1．2万美元，下跌61．3％。全部以一般贸易方式出口；企业包括外商投资企业、私营企业和国有企业。

简介：15%Ag-addedcubicperovskitesSr0.9La0.1TiO3andRuddlesden-Popper(RP)phasesSr2.7La0.3Ti2O7werefabricatedviahydrothermalsynthesis,coldpressingandhigh-temperaturesintering.Thestructureandthermoelectricpropertieswerealsoinvestigatedforallsamples.TheresultsindicatedthatAgprecipitatedasasecondphase.AgadditionmadeelectricalconductivityandabsoluteSeebeckcoefficientenhanced,asaresult,theZTvalueswereenhancedbothfortwoseries.Comparedwithcubicperovskite,RPphasewassubjectedtosmallerimpactbyAgaddition.ThereasonsforenhancingZTvalueandthedifferentimpactfortwoseriesbyAgadditionwerealsodiscussed.

简介：(Cu60Zr30Ti10)98Y2bulkmetallicglass(Φ4mm×70mm)wasobtainedsuccessfullybycoppermouldcoolingandspraying-casting,andsomesampleswereisothermallyannealedattemperaturesof473and623K,whichwaslowerthantheglasstransitiontemperature(Tg)for1h.Microstructureandpropertiesofas-castandannealedsampleswerestudied.Crystallizationphases(Cu10Zr7andCuZr)wereobservedinannealedsamples,andthespeciesandfractionofthesephasesincreasedwithincreasingannealingtemperature.Mic...

简介：Selectivecatalyticoxidation(SCO)ofammoniawascarriedoutoverCu-MncompoundscatalystsmodifiedwithtrivalentrareearthoxideCe2O3andLa2O3respectively.TiO2wasusedassupportanddifferentratioofO2weretestedinordertofindanappropriateO2concentration(vol.%),andtheresultsshowedthat1%O2(vol.%)waspropitioustoSCOofammonia.TheeffectsofthetworareearthoxidesmodifiedcatalystsCe2O3-Cu-Mn/TiO2andLa2O3-Cu-Mn/TiO2onthecatalyticactivityandselectivityofammoniaoxidationwereinvestigatedunderthereactionconditionof500ppmammonia,1%O2(vol.%),atthetemperaturefrom125to250oC.TheresultsrevealedthebeneficialroleofCe2O3andLa2O3incatalyticactivityatlowtemperatureandleanoxygenconcentration,whilethemodificationwithCe2O3andLa2O3ledtothenegativeinfluenceonN2selectivity.ForthecatalystsmodifiedwithCeshowedlowerNOandN2OselectivitythanthecatalystsmodifiedwithLa,thentheeffectsofdifferentCeloadingsoncatalyticactivityandselectivitywerealsoconsidered,incombinationwithcatalystspreparationmethods,whichincludeincipientwetimpregnation,sol-gelmethodandco-precipitation.Resultsrevealedthatthecatalystspreparedbysol-gelmethodobtainedpreferablecatalyticactivitycomparedwiththeothers,reaching99%ammoniaat200oC,whereas96%NOwasdetected.Italsoindicatedthatdifferentcatalystpreparationmethodsignificantlydeterminedproductiondistribution.

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简介：太原钢铁集团公司和成都无缝钢管公司双方利用各自装备优势，通过合作解决了生产大口径不锈钢冷拔无缝钢管的关键－大型不锈钢管坯和热穿孔。详细介绍了Φ１８０×１５冷拔不锈钢无缝管的管坯制造、热穿孔、冷拔（扩）、热处理等生产工艺和产品的良好市场前景。

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简介：一系列立方的稀土元素sesquioxidesRE2O3的拉曼系列(RE=Eu，Gd，Dy，惊讶，嗯，Tm，Yb，陆，Sc和Y)被拉曼光谱学与532和785根nm激光线调查。丰富的另外的乐队由于激光激动的光被观察。为Eu2O3，Dy2O3，Ho2O3，Er2O3，Tm2O3和Yb2O3，，光主要为Gd2O3，Lu2O3，Sc2O3和Y2O3来自内在的三价的lanthanide离子，他们的光被归因于象Eu3+，Nd3+和Er3+那样的另外的光lanthanide离子的踪迹杂质。这调查为检测踪迹作为一个有用工具证实了拉曼光谱学光lanthanide杂质。

简介：NominalcompositionofCa1-xZnxTiO3:0.002Pr3+(x=0.000～0.200)phosphorswerepreparedbyconventionalsolidreactionroute.XRDandPLmeasurementswereusedtoinvestigatethesolid-solutionstructureandluminescencepropertiesofZn-dopedCa1-xZnxTiO3:0.002Pr3+phosphors.Theeffectofsolid-solutionstructureformedbysubstitutionbetweenCa2+andZn2+ionsontheluminescentpropertieswasanalyzed.Theresultsrevealthat,withtheincreaseofZnsubstitutioncontentbelow0.010,latticeparametersandtheintensityofexcitationpeakatboth260and330nmaswellasthecorresponding610nmemissionintensityaremonotonouslydecreasedquicklyinasimilartendency.Also,theevolutionofluminescenceintensityandcrystalcellparametersagainstZndopingconcentrationareingoodagreement.AboveresultsarecloselyrelatedwiththestructurechangewithinCa1-xZnxTiO3:0.002Pr3+solid-solutionphaseformedbytheZnionssubstitutionfortheCasites.Presentstudyrevealsthatthesolid-solutionstructureformedbysubstitutionbetweenCa2+andZn2+ionshassignificanteffectontheluminescencepropertiesofsinglephaseCa1-xZnxTiO3:0.002Pr3+phosphors.

简介：ThephaseandmorphologytransformationduringthehydrothermaltreatingprocessofY2O3wasevaluatedwithX-raydiffcrcnce(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),particlesizeandspecificsurfaceareadetermination.TheresultsshowedthatthecubicY2O3didnottransferintohexagonalY(OH)3inpurewater.Therefore,purehexagonalY(OH)3withnanotubeandmicrorodmorphologieswereobtainedbyhydrothermaltreatingY2O3at150℃for12hin15mlof2mol/LNaOHsolutionwithandwith-outPVAorPEGItwassuggestedthatthecharacteristicpreferentialgrowthofY(OH)3wasattributedtothestructureanisotropyofhexahedronY(OH)3.TheadditionofPVAorPEGcouldpromotetheformingprocessofnanotubesbyselectiveadsorptionondifferentcrystalplanes,whichalteredthegrowthratealongdifferentdirectionsandresultedinthediffusionlimitofconstructingionsinthecentertopofrods.Finally,Y(OH)3:EuandY2O3:Eunanotubeswerealsosynthesizedbyusingthismethod,andtheirphotoluminescencepropertieswereevaluated.

简介：MeltspinningtechnologywasusedtopreparetheMg2Ni-type(Mg24Ni10Cu2)100–xNdx(x=0,5,10,15,20)alloysinordertoobtainananocrystallineandamorphousstructure.TheeffectsofNdcontentandspinningrateonthestructuresandelectrochemicalhydrogenstorageperformancesofthealloyswereinvestigated.ThestructurecharacterizationsofX-raydiffraction(XRD),transmissionelectronmicroscopy(TEM)andscanningelectronmicroscopy(SEM)linkedwithenergydispersivespectroscopy(EDS)revealedthattheas-spunNd-freealloydisplayedanentirenanocrystallinestructure,whereastheas-spunNd-addedalloysheldananocrystallineandamorphousstructureandthedegreeofamorphizationvisiblyincreasedwiththerisingofNdcontentandspinningrate,suggestingthattheadditionofNdfacilitatedtheglassformingoftheMg2Ni-typealloy.TheelectrochemicalmeasurementsindicatedthattheadditionofNdandmeltspinningimprovedtheelectrochemicalhydrogenstorageperformancesofthealloyssignificantly.Thedischargecapacitiesoftheas-castandspunalloysexhibitedmaximumvalueswhenNdcontentwasx=10,whichwere86.4,200.5,266.3,402.5and452.8mAh/gcorrespondingtothespinningrateof0(As-castwasdefinedasthespinningrateof0m/s),10,20,30and40m/s,respectively.Thecyclestability(S20,thecapacitymaintainrateat20thcycle)oftheas-castalloyalwaysrosewiththeincreasingofNdcontent,andthoseoftheas-spunalloysexhibitedthemaximumvaluesforNdcontentx=10,whichwere77.9%,83.4%89.2%and89.7%,correspondingtothespinningrateof10,20,30and40m/s,respectively.

简介：Whitelight-emittingYVO_4：1mol.%Dy~（3＋）,xmol.%Eu~（3＋）phosphorpowderswithordermorphologyandwellcrystallizationwerehydrothermallysynthesizedat180°C.Themicrostructure,white-lightemission,andlight-emittingmechanismofthepowderswerecarefullystudiedusingX-raydiffractometry,scanningelectronmicroscopyandphotoluminescencespectra.TheexcitationandemissionspectraofthephosphorpowdersindicatedthecoexistenceofefficientenergytransferfromEu~（3＋）toDy~（3＋）andinefficientenergytransferfromDy~（3＋）toEu~（3＋）besidestheenergytransferfromVO_4~（3–）toEu~（3＋）.IncreasingtheEu~（~（3＋））concentrationinitiallyenhancedandthenweakenedtheluminescentintensityofDy~（3＋）.Thewhite-lightemissionsofYVO_4：1mol.%Dy~（3＋）,xmol.%Eu~（3＋）phosphorpowderswerebothrelatedtotheenergytransferbetweenVO_4~（3–）andDy~（3＋）/Eu~（3＋）,aswellasbetweenEu~（3＋）andDy~（3＋）.TheinefficientenergytransferfromDy~（3＋）toEu~（3＋）wasfirstfound.