学科分类
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32 个结果
  • 简介:金属nanostructures展览专辑光回声模式在材料从传导性的电子的subwavelength监禁发源。这些回声模式在光学和察觉到的申请由于他们的申请潜力代表一个强壮的研究焦点。在这短评论,我们这块地里的组的最近的成就被加亮。先进金属性的nanostructures的湿化学的途径合成将被介绍,他们由电场的准确的放和操作被显示出。下次,为小分子的察觉的这些nanostructures的申请将在几个例子被描述。另外,金属nanostructures能被用于亚波长光集中并且为有效精力联合进聚合物链,这将被显示出。

  • 标签: 遥感应用 纳米结构 生物传感 等离子 开发 能源
  • 简介:ThehighlydispersedPt–ReOX(x≤1)sitesca.0.5nminsizewereformedviaasuccessiveandstronginteractionoftheReprecursorwithtitaniaandthenofthePtcomplexwithdepositedlow-valentrheniumoxideclusters.Thesize,chargeandchemicalcompositionwerecharacterizedbymeansofHRTEM/STEMwithEDXmapping,XPS,andFTIRS.ThesesiteswithRe/Pt=2wereshowntobehighlyactiveandselectiveinthehydrogenationofcarboxylicacidtoalcoholunderverymildconditions(T=130°C,P=50bar).ThereactionrateconstantforthehydrogenationofhexanoicacidincreasedlinearlywiththePtcontent.Asforthehomogeneouspincer-typeRu-organiccomplexes,theactivePt–ReOXsitescandissociateheterolyticallythemolecularhydrogenwiththeformationofhydroxylgroupsandPthydrideforhydrogenationofthecarboxylicgroup.Indeed,TOFof20h-1andselectivityof98%–99%areapproachingthevaluestypicalofhomogeneouscatalysts.Thefirstorderkineticsdescribedwelltheexperimentaldataobtainedinawiderangeofreactionconditions.

  • 标签: 选择性加氢催化剂 铂络合物 活性位点 二氧化钛 再氧化 羧酸
  • 简介:Shortpulsedfiberlasershavebeenwidelymadeusingsingle-walledcarbonnanotubesasasaturableabsorber(SA).However,mostofthecurrentlyuseddevicescanonlyoperateinonedeterminedoperationstatewithanunchangeablemodulationSAdepthinthecavity,whichsignificantlylimitstheirapplicationinphotonicdevices.Inthispaper,well-alignedcarbonnanotubearraysaresynthesizedusingzeoliteAlPO4-5asatemplate,whichfeaturesanisotropicopticalabsorption.Thelinearopticalabsorptionoftheas-synthesizedcarbonnanotubearrayscaneasilybetunedbyadjustingapolarizationcontroller,thusprovidingatunablemodulationdepthforthecarbonnanotubeSA.ByexploitingthisSAinanerbium-dopedfiberlasercavity,bothQ-switchedandmodelockedpulsedlasersareachievedbysimplyadjustingapolarizationcontrollerunderafixedpumppowerof330mW.Inaddition,therepetitionrateoftheQ-switchingandpulsedurationofthemode-lockingcanbetunedaccordingtothevariationofmodulationdepth.Moreover,solitonmoleculescanbeobtainedwhenthemodulationdepthoftheSAis4.5%.

  • 标签: SA SWCNTS carbon NANOTUBES
  • 简介:使用活跃中心拍动的可能性控制方法,它是为一台单个阶段的压缩机的一个证明旋转货摊控制方法,到3阶段轴的压缩机试验性地被讨论,在复杂旋转货摊开始进程被观察的地方。研究压缩机是3阶段并且能为转子片和定子翼改变stagger角度背景。十六个转子片/定子翼配置模式被变化测试蹒跚为定子翼的角度。由表面压力变化的测量,货摊开始进程被调查,测量压力变化数据为旋转货摊被用作一个预兆的信号。货摊察觉系统在一台单个阶段的压缩机用于活跃中心拍动控制的试验性的结果表演能有用地与一个更复杂的货摊开始过程在一台3阶段压缩机被用于那。

  • 标签: 压缩机 方法 旋转式喷灌器 研究
  • 简介:Inthepresentstudy,weinvestigatedtheeffectofceriumanderbiumdopingofthezirconiumdioxidematrix.Wesynthesizeddopedsamplesusinghydrothermalprocess.Theamountsofdopantusedwere0.5%,1%and5%molar(rareearthoxideoverzirconiumdioxide)respectively.ThesampleshavebeenstudiedviaX-rayDiffractionmeasurementsforthestructuralcharacterization.UVvisiblediffusereflectancewasusedfortheopticalanalysis,Brunauer-Emmett-Teller(BET)modelforthemeasurementofthesurfacearea.Finallythesampleshavebeenanalysedviaelectronparamagneticresonance(EPR)fortheelectroniccharacterization.Thenwetestedthenewsynthetizedmaterialstodeterminetheirphotocatalyticactivityinthereactionofdegradationofmethyleneblueperformedunderirradiationbydiodes(LEDs)emittingexclusivelyvisiblelight.

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  • 简介:Anall-fiberacousto-opticmodulator(AOM),whichfeaturesacompactstructureandalow-drivingvoltage,isexperimentallydemonstratedfortheactivemode-lockingofafiberlaser.TheproposedAOMisbasedontheshortlengthofthecladding-etchedfiber,theendsofwhicharefixedonaslideglass.Ontopofthecladding-etchedfiber,apiezoelectrictransducerwasoverlaid.Achemicalwet-etchingtechnique,whichisbasedonamixedsolutionofNH4Fand(NH4)2SO4,isusedtoreducethefiberdiameterdownto~25μm,andthelengthoftheetchedsectionisonly0.5cm.Thefabricateddeviceexhibitedamodulationdepthof73.10%atanacousticfrequencyof918.9kHzandapeak-to-peakelectricalvoltageof10V,whilealaserbeamwascoupledat1560nm.ByusingthepreparedAOMwithinanerbium-doped-fiberringcavity,themode-lockedpulseswithatemporalwidthof2.66pswerereadilyobtainedatarepetitionrateof1.838MHz.

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  • 简介:NanosizedGa-containingZSM-5zeoliteswerepreparedviaisomorphoussubstitutionandimpregnationfollowedbycharacterizedusingvarioustechniques.Thecatalyticperformanceofthezeolitesforthearomatizationof1-hexenewasinvestigated.TheresultsindicatethatisomorphoussubstitutionpromotestheincorporationofGaheteroatomsintotheframeworkalongwiththeformationofextra-frameworkGaO+species([GaO+]a)thathavestrongerinteractionswiththenegativepotentialoftheframework.Inaddition,basedonthePy-IRresultsandcatalyticperformance,the[GaO+]aspecieswithstrongerLewisacidsitesproducedabettersynergismwithmoderateBr?nstedacidsitesandthusimprovedtheselectivitytoaromaticcompounds.However,theimpregnationresultsintheformationofGa2O3phaseandsmallamountsofGaO+speciesthataremainlylocatedontheexternalsurface([GaO+]b),whichcontributetoweakerLewisacidsitesduetoweakerinteractionswiththezeoliteframework.During1-hexenearomatization,thenanosizedGaisomorphouslysubstitutedZSM-5zeolitesamples(Gax-NZ5)exhibitedbettercatalyticperformancecomparedtotheimpregnatedsamples,andthehighestaromaticyield(i.e.,65.4wt%)wasachievedovertheGa4.2-NZ5sample,whichcontainedwiththehighestGacontent.

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