简介:TheTiO2nanomembranedopedbyREionswerepreparedbymixingREionsintoTiO2solutionandthephoto-catalyticpropertiesofthecoatingglasswithTiO2membranedopedbyREionstomethylbenzenedegradationunderultravioletwereinvestigated.AFMphotoesshowthatthesurfaceofcoatingglasswithTiO2nanomembranedopedbyCe3+,Ce4+,Y3+arecomposedofparticleswithdiametersof30~50nm.Theresearchesonphoto-catalyticpropertiesprovethatthesurfaceofcoatingglasswithTiO2nanomembranedopedbyREionspossessesgoodphotocatalyticpropertiesunderultravioletandthedegradationpercentsofmethylbenzenearemorethan90%whenthedegradationtimeisshorterthan160min.WhenthemoleratioofCe3+,Y3+,Ce4+toTiO2is0.002thedegradationpercentsofmethylbenzenearerespectively92.85%,91.87%and91.15%under254~365nmultravioletin50μg·ml-1methylbenzenesolution.ThephotocatalyticabilityofthesurfaceofcoatingglasswithTiO2nanomembranedopedbyCe3+underultraviolettodegrademethylbenzeneincreasesastheconcentrationsofREionsincreaseandtheiroptimumpercentageofdegradationare98.50%,97.50%and96.35.5%respectively.Thehighertheconcentrationofmethylbenzenesolutionthelowerthepercentsofthemethylbenzenedegradationofthecoatingglassare,andthebiggertheratiooftheareasofcoatingglasstothevolumeofmethylbenzenesolutionthehigherthedegradationeffectofmethylbenzeneis.
简介:Ceriasphereswithdifferentsizesandsulfurizedproductswithcorrespondingmorphologywerepreparedbyhydrothermalandgas-solidreactionmethodat600–800°CunderCS2atmosphereforashorttime,respectively.Dimensionaleffectinpreparationofγ-Ce2S3wasfirstlyinvestigatedbymeansoftechniquessuchasscanningelectronmicroscopy(SEM),X-raydiffraction(XRD),thermalgravimetricanalysis(TGA)andspectrophotometer.Theresultsshowedthatwhenceriananoparticleswithsmallsizewereusedasprecursors,theγ-Ce2S3couldbepreparedatthelowertemperatureandthebadlysinteredproductswereobtained;whenceriananoparticleswithlargesizewereemployedasprecursors,pureγ-Ce2S3wasdifficultlyobtainedevenifthetemperaturewasupto800°Candtheproductstendedtokeeptheiroriginalsize.Theheat-resistancepropertyoftheγ-Ce2S3withlargesizewasbetterthanthesmallerone,andthepureγ-Ce2S3preparedfromprecursorwithsmallsizehadagoodpigmentaryperformance.
简介:CeO2nanoparticles(nano-CeO2p)wereaddedintolasercladdedNiCoCrAlYcoatingsonNi-basedsuperalloysubstratetoimprovethemicrostructureandproperties.Scanningelectronmicroscope(SEM),X-raydiffractometer(XRD),micro-hardnesstester,andheattreatmentfurnacewereemployedtoinvestigatetheirmorphologies,phases,micro-hardnessandthermalshockresistance,comparedwiththecoatingwithoutnanoparticlesadded.Theresultsshowedthatthemicrostructureandpropertiesofthecoatingswiththeaddition...
简介:AseriesofLa2O3/MCnylonnanocompositeswerepreparedviainsitupolymerization.Theeffectsofcontentofnano-La2O3onthemechanicalpropertiesofnanocompositeswerestudied.Dispersionofnano-La2O3inMCnylonmatrixwasobservedwithSEM.ThecrystalstructureofnanocompositeswascharacterizedbymeansofXRD.SEManalysisshowsthatLa2O3nanoparticlesareuniformlydispersedinMCnylonmatrixandlittleclusteringexistswhenthecontentofnano-La2O3islowerthan1%,however,whenthecontentofnano-La2O3ismorethan1%,itbeginstocluster.XRDanalysisindicatsthatnano-La2O3doesnotchangethecrystalstructureofMCnylon.Mechanicalpropertiestestsshowthatthetensilestrength,elongationatbreak,impactstrength,flexuralstrength,andflexuralmodulusofnanocompositesfirstincreasethendecreaseasthecontentofnano-La2O3isincreased.Whenthecontentofnano-La2O3is0.5%,thetensilestrengthandelongationatbreakofnanocompositesreachmaximum,whichare17.9%and52.1%higherrespectivelythanthoseofMCnylon.Whenthecontentofnano-La2O3is1.0%,theimpactstrength,flexuralstrengthandflexuralmodulusofnanocompositesreachmaximum,whichare36.6%,12.7%and16.3%higherrespectivelythanthoseofMCnylon.
简介:Anisotropicstructures,nanoneedles,andnanospindlesofrareearthhydroxychloride(RE(OH)2Cl)andoxychloride(REOCl)(rareearth=EuandTb)weresynthesized.Therareearthhydroxychloridenanostructureswereformedviaathermallyassistedhydrolysisoftherare-earthsesquioxidenanocrystals.Themorphologicalevolutionofthenanostructureswasstudiedusinghigh-resolutiontransmissionelec-tronmicroscopyandscanningelectronmicroscopy,whilethestructuralevolutionwasinvestigatedusingX-raydiffractiontechniques.Thethermalstabilityoftherareearthhydroxychlorideswasinvestigatedusingthermogravimetricanalysis.Therareearthoxychloridenanospin-dlesweresynthesizedviaasimpleheat-treatmentofrareearthhydroxychloridenanospindles.
简介:TheAu/CeO2catalystsweresynthesizedbyco-precipitation(CP),deposition-precipitation(DP)andmetalliccolloidsdeposition(MCD)method,andtestedforoxidationofvolatileorganiccompounds(VOCs).ItwasrevealedthattheAu/CeO2catalystpreparedbyDPmethodwasthemostefficientcatalysttowardsthetotaloxidationoftoluene.TheAu/CeO2catalystshadobviouslyhighcatalyticactivity,andthebestresultswasobtainedon3wt.%Au/CeO2catalystpreparedbyDPmethod.Thesecatalystswerechara...