简介:FractionsofplasmaproteinofmaleKunmingmice(bodyweight24.2±0.3g),treatedwithCisplatini.p.injectionindoseof10mg/kg,wereobtainedbyseparationonSephadex-G-50columns,bufferedwithammoniumacetatetopH5.7,TheXSRFexperimentswereperformedattheBEPC(BeijingElectronPositronCollider)synchrotronradiationfacility.Theelements(Pt,S,Ca,Fe,Ni,Cu,Zn,Se,BrandSr)inthefractionoftheplasmaproteins(>22KD)wereassayedusinghighlysensitiveSXRF.TherelativeconcentrationsofelementswerecalculatedbyanormalizationofCOmptonscatteringintensityaround22KeV,afterthenormalizationforcollectingtimeofX-rayspectrumandthecountingoftheionchamber,andsubractingthecontributionofthepolycarbonatefilmusedforsupportingthesamples.ThedeterminationcouldprovethattheelementPtinplasmawasboundwithmacro-molecularprotein.CuandSwerepresentinthefractionoftheproteininmicetreatedwithCisplatinandexhibitedanincrease,therationoftreated/controlwere1.66±0.06and1.78±0.33repectively,whereasZndecreasedtoaratioof0.78±0.09,OurresultsareinagreementwithotherswhichshowedthatCisplatinexposureleadstoamarkedlossofkidneycopper,andamoderateriseindidneyzinc.However,thisworkmainlyfocussedontheimplementationofthisanalyticalprocedure,butnotontheresultsoftheinvestigationsoftheeffectofCisplatinontraceelementsinplasmaprotein.
简介:Wedevelopedaone-dimensionalhybridmodeltosimulatetheDC/RFcombineddrivencapacitivelycoupledplasmaforargondischarges.ThenumericalresultsareusedtoanalyzetheinfluenceoftheDCsourceontheplasmadensitydistribution,ionenergydistributions(IEDs)andionangledistributions(IADs)onboththeRFandDCelectrodes.TheincreaseinDCvoltagedrivesmorehigh-energyionstotheelectrodeappliedtotheDCsource,whichmakestheIEDsattheDCelectrodeshifttowardshigherenergy,andthepeaksintheIADsshifttowardssmallangleregions.Atthesametime,italsodecreasestheionenergyattheRFelectrodeandenlargestheincidentanglesoftheions,whichstriketheRFelectrode.
简介:Removalofsinglecomponentandbinarymixturesofbenzeneandm-xyleneusingamulti-pin-meshreactorwasstudiedtofindthedecompositioncharacteristics,carbonbalanceandCO_2selectivity.Thedecompositionrateofbenzeneinmixturewasapproximately16%lowerthanthatofsinglecomponentbenzene.However,thedecompositionrateofm-xyleneinmixturewasslightlyhigherthanthatofsinglecomponentm-xylene.Carbonbalanceofthemixturedecompositionprocessachievedalowerlevelthanthatofsinglecomponentbenzene/m-xylene.IncreaseinthespecificinputenergywashelpfultoimproveCO_2selectivityinthesinglecomponentdecompositionprocess,whilethespecificinputenergyhadanegligibleeffectonCO_2selectivityinthemixturedecompositionprocess.Bychangingtheoxygencontentinbackgroundgas,wefoundthatdifferenttypesofradicalsshoweddifferentreactionactivitiestowardbenzeneandm-xylene.Benzenewasmorelikelytoreactwithnitrogen-containingradicals,whilem-xylenewasmorelikelytoreactwithoxygen-containingradicals.