简介：ThepolymerizationofMMAinitiatedbycopper(Ⅱ）chelatingresins/CCl4systemwasstudied.Fromthekineticdata,thekineticequationofpolymerizationcanbeexpressedasRp=Ke^-56400/RT[MMA]^1.57[CCl4]^m[RESIN-Cu]^0.18wherem:3-4.5,when[CCl4]0.1-6.93M.Thefreeradicalpolymerizationmechanismisproposed.Theprimaryradicalsareformedbytheprocessofcomplexation-chlorinetransformationamongthecopper(Ⅱ)chelatingresin,CCl4andmethacrylate.

简介：Cobaltporphyrincomplexes(TPPCo~ⅢX)(TPP=5,10,15,20-tetraphenyl-porphyrin;X=halide)incombinationwithbis(triphenylphosphine)iminiumchloride(PPNCl)wereusedforthecopolymerizationofcyclohexeneoxideandCO_2.Thehighestturnoverfrequencyof67.2h~(-1)wasachievedafter13hat20℃,andtheobtainedpoly(1,2-cyclohexylenecarbonate)(PCHC)showednumberaveragemolecularweight(M_n)of10×10~3.ThoughtheobtainedPCHCshowedatacticstructure,them-centeredtetradscontentreached58.1%atCO_2pressureof1.0MPa,anddecreasedto51.9%atCO_2pressureof6.0MPa,indicatingthatitwasinclinedtoformatacticpolymerathighCO_2pressure.

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简介：Cobaltandnickelcomplexes(1a-1dand2a-2d,respectively)supportedby2-imidate-pyridineligandsweresynthesizedandusedfor1,3-butadienepolymerization.ThecomplexeswerecharacterizedbyIRandelementanalysis,andcomplex1awasfurthercharacterizedbysingle-crystalX-raydiffraction.Thesolidstatestructureofcomplex1adisplayedadistortedtetrahedralgeometry.Uponactivationwithethylaluminumsesquichloride(EASC),allthecomplexesshowedhighactivitiestoward1,3-butadienepolymerization.Thecobaltcomplexesproducedpolymerswithhighcis-1,4contentsandhighmolecularweights,whilethenickelcomplexesdisplayedlowcis-1,4selectivityandtheresultingpolymershadlowmolecularweights.Thecatalyticactivitiesofthecomplexeshighlydependedontheligandstructure.Withtheincrementofpolymerizationtemperature,thecis-1,4contentandthemolecularweightoftheresultingpolymerdecreased.

简介：Theaqueouspolymerizationofmethylmethacrylateintiatedbycopperpolypropylene-basedpoly(oxime-imidodiacetate)(P-Cu)-sodiumsulfitesystemhasbeeninvestigated.Theoverallrateofpolymerization(Rp)wasfoundtobeRp=5.8×10^12e^-84.1KJ/RT[MMA]^1.4[P-Cu]^0[Na2SO3]^0.50Amechanismof“coordination-protontransfer”fortheproductionofinitiatingspecieswasproposedanddiscussed.