简介:将95%Mg+3%Ni+2%MnO2混合粉末在行星式高能球磨机中充氢反应球磨100h,利用X射线衍射(XRD)和扫描电镜(SEM)对球磨后的粉体进行表征,并研究其与水反应的动力学性能。结果表明,充氢球磨能对Mg-3Ni-2MnO2进行充分的氢化,Mg全部形成MgH2。制备的氢化态Mg-3Ni-2MnO2复合粉末的颗粒尺寸为0.1~5gm,晶粒尺寸在1~40nm之间。复合物在二次去离子水中水解时,随温度升高,放氢量增加,当温度为343K时,在20min内放出的氢气达到理论放氢量的91-3%,有望成为1种新的安全高效氢源技术。Avrami指数的数值变化表明,氢化态Mg-3Ni-2MnO2复合粉体的水解过程中,不同阶段其水解机理有所不同。
简介:Awhitelong-lastingphosphorCa2MgSi2O7:Dy3+waspreparedbythesolid-statereaction.Astrongbandpeakedat260nmwasshownintheexcitationspectrumof578nmemission,whichmightbeattributedtotheoxygendeficiencyofthehost.Afterirradiatedwith254nmfor4min,thewhiteafterglowofthesamplecouldbeseenfor3h.Moreover,thedepthsandfrequencyfactorsoftrapcenterswerecal-culatedfromthethermo-luminescencecurveofthesample,whichindicatedthatthetrapcenterscorrespondingtothe414Kbandweremorehelpfultothelong-lastingphosphorescence.
简介:TheTiO2nanomembranedopedbyREionswerepreparedbymixingREionsintoTiO2solutionandthephoto-catalyticpropertiesofthecoatingglasswithTiO2membranedopedbyREionstomethylbenzenedegradationunderultravioletwereinvestigated.AFMphotoesshowthatthesurfaceofcoatingglasswithTiO2nanomembranedopedbyCe3+,Ce4+,Y3+arecomposedofparticleswithdiametersof30~50nm.Theresearchesonphoto-catalyticpropertiesprovethatthesurfaceofcoatingglasswithTiO2nanomembranedopedbyREionspossessesgoodphotocatalyticpropertiesunderultravioletandthedegradationpercentsofmethylbenzenearemorethan90%whenthedegradationtimeisshorterthan160min.WhenthemoleratioofCe3+,Y3+,Ce4+toTiO2is0.002thedegradationpercentsofmethylbenzenearerespectively92.85%,91.87%and91.15%under254~365nmultravioletin50μg·ml-1methylbenzenesolution.ThephotocatalyticabilityofthesurfaceofcoatingglasswithTiO2nanomembranedopedbyCe3+underultraviolettodegrademethylbenzeneincreasesastheconcentrationsofREionsincreaseandtheiroptimumpercentageofdegradationare98.50%,97.50%and96.35.5%respectively.Thehighertheconcentrationofmethylbenzenesolutionthelowerthepercentsofthemethylbenzenedegradationofthecoatingglassare,andthebiggertheratiooftheareasofcoatingglasstothevolumeofmethylbenzenesolutionthehigherthedegradationeffectofmethylbenzeneis.
简介:Ceriasphereswithdifferentsizesandsulfurizedproductswithcorrespondingmorphologywerepreparedbyhydrothermalandgas-solidreactionmethodat600–800°CunderCS2atmosphereforashorttime,respectively.Dimensionaleffectinpreparationofγ-Ce2S3wasfirstlyinvestigatedbymeansoftechniquessuchasscanningelectronmicroscopy(SEM),X-raydiffraction(XRD),thermalgravimetricanalysis(TGA)andspectrophotometer.Theresultsshowedthatwhenceriananoparticleswithsmallsizewereusedasprecursors,theγ-Ce2S3couldbepreparedatthelowertemperatureandthebadlysinteredproductswereobtained;whenceriananoparticleswithlargesizewereemployedasprecursors,pureγ-Ce2S3wasdifficultlyobtainedevenifthetemperaturewasupto800°Candtheproductstendedtokeeptheiroriginalsize.Theheat-resistancepropertyoftheγ-Ce2S3withlargesizewasbetterthanthesmallerone,andthepureγ-Ce2S3preparedfromprecursorwithsmallsizehadagoodpigmentaryperformance.
简介:Thedifferencesofreductionbehaviorsbetweenironorelumpandpelletswerestudiedbyconductinglowtemperaturereductiondegradation,staticloadreductionanddroplettests.Thesetestssimulatedtheconditionsofreductiontemperatureandhydrogen-containinggasinCOREX.Duetoitsdensestructureandlowporositycomparedwithpellets,lumporepossessespoorreductiondegradationindex(RDI)andslowerreductionrateinearlyandmediumreactionstages,showingsignsoflowerstrength,lowersofteningandmeltingtemperatures,aswellasawidermeltingzoneandhigherΔP.Thatprovidessomebasistoexplainthephenomenaofdifferentialpressurerise,metallizationdeclineandmorestickingaftertheusageoflumporeinCOREXplant.
简介:CeO2nanoparticles(nano-CeO2p)wereaddedintolasercladdedNiCoCrAlYcoatingsonNi-basedsuperalloysubstratetoimprovethemicrostructureandproperties.Scanningelectronmicroscope(SEM),X-raydiffractometer(XRD),micro-hardnesstester,andheattreatmentfurnacewereemployedtoinvestigatetheirmorphologies,phases,micro-hardnessandthermalshockresistance,comparedwiththecoatingwithoutnanoparticlesadded.Theresultsshowedthatthemicrostructureandpropertiesofthecoatingswiththeaddition...
简介:Inthepresentstudy,sampleswereextensivelycollectedthroughoutthestainlesssteelmanufacturingprocess.Thethree-dimensionalmorphologyofinclusionswasrevealedbynon-aqueoussolutionelectrolysis.Thehighconcentrationofaluminuminferrosiliconcausedtheincrementof[Al]sinsteelandAl2O3ininclusions,whichledtothehighermeltingtemperatureofinclusions.ItwasconcludedthattheapplicationoflowAlferrosiliconandcalciumtreatmentcouldpreventtheformationofAl2O3-richinclusions.
简介:AseriesofLa2O3/MCnylonnanocompositeswerepreparedviainsitupolymerization.Theeffectsofcontentofnano-La2O3onthemechanicalpropertiesofnanocompositeswerestudied.Dispersionofnano-La2O3inMCnylonmatrixwasobservedwithSEM.ThecrystalstructureofnanocompositeswascharacterizedbymeansofXRD.SEManalysisshowsthatLa2O3nanoparticlesareuniformlydispersedinMCnylonmatrixandlittleclusteringexistswhenthecontentofnano-La2O3islowerthan1%,however,whenthecontentofnano-La2O3ismorethan1%,itbeginstocluster.XRDanalysisindicatsthatnano-La2O3doesnotchangethecrystalstructureofMCnylon.Mechanicalpropertiestestsshowthatthetensilestrength,elongationatbreak,impactstrength,flexuralstrength,andflexuralmodulusofnanocompositesfirstincreasethendecreaseasthecontentofnano-La2O3isincreased.Whenthecontentofnano-La2O3is0.5%,thetensilestrengthandelongationatbreakofnanocompositesreachmaximum,whichare17.9%and52.1%higherrespectivelythanthoseofMCnylon.Whenthecontentofnano-La2O3is1.0%,theimpactstrength,flexuralstrengthandflexuralmodulusofnanocompositesreachmaximum,whichare36.6%,12.7%and16.3%higherrespectivelythanthoseofMCnylon.
简介:CO2emissionofthesteelindustrytakesupagreatproportionofthetotalemissionoftheworld.ItisnecessarytoreducetheCO2intensityofsteelproductsinordertosaveenergy,protecttheenvironmentandkeepasustainabledevelopmentinthesteelindustry.Basedontheresearchofsteelproducts'lifecycleinventory,thosewhoconductedthisresearchhavefocusedontheanalysisofCO2emissionfactorsandmeasures.Adoptingthelifecycleinventorymodelofacertainsteelmakingsite,togetherwiththeTornadoChart,theresearchershaveidentifiedsignificantfactors,providedsomeexplanation,andsuggestedsomepossiblemeasurestoreduceCO2emission.TheresultshaveshownthatthemostimportantfactorsaretheCO2intensityofblastfurnacegas(BFG),hotmetalratioofbasicoxygenfurnace(BOF)andthematerialutilizationefficiency.Accordingly,somemeasuressuchasremovingCO2inBFG,decreasingthehotmetalproportioninBOF,andimprovematerialutilizationefficiencyineachprocess,maybetakentodecreaseCO2emission.