SYNTHESIS AND THE FINE STRUCTURE-PROPERTY RELATIONSHIPS OF ION-CONTAINING BIOMEDICAL POLYETHERURETHANES

(整期优先)网络出版时间:1993-03-13
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Biomedicalsegmentedpolyetherurethane(SPEU)elastomersarecompositepoly-merswithmicrophaseseparationstructure.VariousattemptsofintroducingionicgroupsintoSPEUhavebeencarriedoutfortheimprovementoftheirbloodcompati-bilities.Weherereportthemechanicalandanticoagulantproperties.Twoseriesofsulfooctylpendantgroupscontainingsegmentedpolyetherurethaneswithwelldefinedfinestructurehavebeensynthesizedinourlab-oratory.ThesulfooctylgroupswereexactlylocatedatthehardsegmentswhentheSPEUswerepreparedfromthereactionofpolytetramethyleneglycol(PTMG)1000-4,4’diphenylmethanediisocyanate(MDI)oligomerswithN-sulfoalkyldiethanolamine