The Electroluminescence Characterization of Poly(p-phenyleneethynylene)——The π-conjugated Backbone Interrupted by a Butylene Unit

(整期优先)网络出版时间:2002-01-11
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π-Conjugatedpoly(p-phenyleneethynylene)withtheinterruptionoftheconjugationbyabutyleneunitwassynthesized.Itsabsorption,PLandELspectrawereinvestigatedrespectively.Thespectralpeaksshiftedtothehigherenergysidewiththeinterruptionoftheconjugationlengths.Themodelcompoundwassynthesized,bywhichtheresultswereproved.ThethermalcharacteristicsofthepolymerwasdeterminedbyDSCandTGA,indicatingthatthepolymerhasagoodthermalstability.Theelectroluminescence(EL)inthegreenregionofthespectrumwithamaximumat500nmwasobservedfromthepolymerfilmssandwichedbetweenindium-tin-oxideandanAlelectrode.