学科分类
/ 1
20 个结果
  • 简介:Newmathematicaldiffusionmodelsforsolidstatehomogenizationofdendritesegregationwerepresentedtocalculatetheconcentrationevolutionofalloyingelementsduringsolid-statehomogenizationofdendritesegregationinanycrosssectionofathree-dimensionaldendritesystem.Withmathematicalaccumulation,alltheindividualconcentrationprofilesofeverydendritecanbeaccumulatedtoformaconcentrationequation,whichmayberequiredbysinemodelornot.Thendiffusionhomogenizationprocessesforanycrosssectionsofdendritesinsolidstatecanbecalculatedfromtheequation.TheonlyassumptionofthenewmodelswasthatanyindividualconcentrationprofileinadendritesystemcouldbesimulatedbyGaussequationofFick-2law.

  • 标签: 扩散 均匀性 树枝石 分离 合金冶炼
  • 简介:Thebondingofsteelplatetoaluminumliquidwasconductedusingrapidsolidification.Theinfluenceofdiffusiontimeoninterfacialstructurewasstudied.Theresultsshowedthatundertheconditionof750℃forthetemperatureofaluminumliquidand200℃forthepreheattemperatureofsteelplate,whendiffusiontimewasshorterthan4.3s,therewasonlyFe-Alsolidsolutionattheinterface.Whendiffusiontimewaslongerthan4.3s,Fe-Alcompoundbegantoformattheinterface.TherelationshipsbetweendiffusiontimetandthicknessofFe-AlcompoundlayerHareH=-9.72+2.62t-0.08t^2(4.3s≤t≤15s)andH=2.79+0.647t=0.033t^2(t>15s).

  • 标签: 焊接 快速凝固 结构 扩散时间
  • 简介:磨擦促使处理(FSP)作为在12修理裂缝的一个方法被调查?公里厚304L不锈钢板。愈合的可行性被用一个PCBN/W-Re工具处理一个逐渐变细的裂缝与表明一25?公里直径肩膀和6.4的大头针长度?公里。实验证明愈合是可能的开始的一个裂缝狭窄然后日益增多地长大到2的宽度?公里。板实验上的祷告被用来为创造发现最好的参数一巩固与贱金属相比与坚硬差别的最少的数量搅动地区。在一些标本的谷物精炼更高导致了大部分搅动地区坚硬,与贱金属相比。谷物尺寸对microhardness的一个阴谋显示出在谷物尺寸和坚硬之间的很强壮的反的关联,从Hall-Petch关系期望。腐蚀测试被执行以便在stir地区的潜在的促进感受性上评估FSP的效果。在1000以后?在在没有腐蚀产品在基础材料控制上或在任何磨擦上形成了,这被发现的房间温度的3.5%盐溶液的断断续续的沉浸的h搅动处理标本。

  • 标签: 不锈钢板 304L 裂缝 磨擦 修理 腐蚀测试
  • 简介:Becauseoftheexcellentmechanicalpropertiesof34C「NiMo6steel,itiswidelyusedinhigh-valuecomponents.Manyconventionalapproachestostrengthening-steelstypicallyinvolvethelossofusefulductility.Inthisstudy,34CrNiMo6Steelhavinghighstrengthandductilityisproducedbylasersolidforming(LSF)w让haquenching-tempering(QT)treatment.TemperingofbainiteismainlybysolidphasetransformationinthepreviousLSFlayersduringtheLSFprocess.ThestablemicrostructureofLSFconsistsofferriteandfinecarbides.Themicrostructuretransferstotemperedsorbiteafterheat-treatment.ThetensilepropertiesoftheLSFsteelmeetthoseofthewroughtstandard.TheUTSandelongationofLSFsampleat858MPa,19.2%,respectively,aregreaterthanthoseofthewrought.TheQTtreatmentenhancedtheultimatetensilestrengthandyieldstrengthoftheLSFsample.Theultimatetensilestrength,yieldstrength,reductioninarea,andelongationoftheLSF+QTsampleat980MPa,916MPa,58.9%,and13.9%,respectively,aregreaterthanthoseofthewroughtstandard.TheyieldstrengthoftheLSF+QTsampleisapproximately1.27timesthatofthewrought.TheLSFsamplesfailedinaductilefracturemode,whiletheLSF+QTsamplesshowedmixed-modefailure.ThedefectshaveonlyasmalleffectonthetensilepropertiesowingtotheexcellentductilityoftheLSFsample.

  • 标签: Laser solid FORMING High strength and
  • 简介:Quasi-solid-statedye-sensitizedsolarcells(DSCs)werepreparedusinggelelectrolytegelatedbypoly(ethylene-oxide)(PEO)withdifferentmolecularweight.WiththeincreaseinPEOmolecularweight,theshortcircuitcurrentdensities(Jsc)increasesignificantly,whichisrelatedtotheincreaseinI-diffusionduetotheincreaseinfreevolumeofgelelectrolyte.However,onlyaslightincreaseinopenvoltage(Voc)isobserved,whichisexplainedbythedecreaseindarkcurrentarisingfromthereductionoftriiodide(I3-)byconductionbandelectrons.

  • 标签: 聚氧化乙烯 太阳能电池 染料敏化 准固态 电池性能 分子质量
  • 简介:形成的激光固体(LSF)扔的Inconel718superalloys是在顺序(SITA热处理)与答案处理,中间的热处理(IHT)和二阶段的老化处理对待的热。微观结构,张力的性质和在500袠的LSFedInconel718superalloy的槽口敏感上的IHT温度的效果??

  • 标签: INCONEL 热处理温度 718合金 高温合金 固体激光 微观结构
  • 简介:Thestudyofthetriplejunctionsofthegrainboundariesinsomefccsolidsolutions,orderedalloysandintermetallicswithL12hasbeencarriedoutusingtheopticalmetallographyandTEMmethods.Two-typesofthetriplejunctionswerefoundinthealloysinvestigated(1),consistingoftheboundariesoftherandom(RT),and(2),consistingoftheRTboundaryandthespecialboundaries(ST).TherelativevaluesoftheRTandSTboundaryenergyweredeterminedonthebasisofthemeasurementsoftheanglesbetweenthegrainboundaryplanes.IthasbeenshownthattheenergyofSTboundariesincreaseswiththeincreaseofthestackingfault(SF)energy.TheenergyoftheRTboundariesdoesnotdependontheSFenergy.

  • 标签: 合金学 颗粒边界能量 稳定性 离子
  • 简介:ThedensityofNi-Alalloysinbothliquidstateandsolid-liquidcoexistencestatewasmeasuredwithamodifiedpycnometricmethod.ItwasfoundthatthedensityofNI-AlalloysdecreaseswithincreasingtemperatureandAlconcentrationinthealloys.ThemolarvolumeofliquidNi-AlbinaryalloysincreaseswiththeincreaseoftemperatureandAlconcentration.ThepartialmolarvolumeofAlinNI-Albinaryalloywascalculatedapproximately.ThemolarvolumeofliquidNI-Alalloydeterminedinthepresentworkshowsanegativedeviationfromtheideallinearmolarvolume.

  • 标签: 镍铝合金 密度 改性比重瓶测量法 克分子量 固液共存态
  • 简介:Thelargesize,crack-freeZr55Cu30Al10Ni5bulkmetallicglass(BMGs)withthediameterof54mmandtheheightof15mmwasbuiltbylasersolidformingadditivemanufacturingtechnology,whosesizeislargerthanthecriticaldiameterbycasting.Themicrostructure,tensileandcompressivedeformationbehaviorsandfracturemorphologyoflasersolidformedZr55Cu30Al10Ni5BMGswereinvestigated.Itisfoundthatthecrystallizationmainlyoccursintheheat-affectedzonesofdepositionlayers,whichconsistofAl5Ni3Zr2,NiZr2,ZrCu,CuZr2phases.Thecontentofamorphousphaseinthedepositisabout63%.Underthecompressiveloading,thedepositpresentsnoplasticitybeforefractureoccurs.Thefractureprocessismainlycontrolledbytheshearstressandthecompressiveshearfractureanglesofabout39.Thecompressivestrengthreaches1452MPa,whichisequivalenttothatofas-CastZr55Cu30Al10Ni5BMGs,andthereexistvein-likepatterns,river-likepatternsandsmoothregionsatthecompressivefractography.Underthetensileloading,thedepositpresentsthebrittlefracturepatternwithoutplasticdeformation.Thefractureprocessexhibitsnormalfracturemodel,andthetensileshearfractureangleofabout90°.Thetensilestrengthisonlyabout609MPa,andthetensilefractographymainlyconsistsofmicro-scaledcoresandvein-likepatterns,dimple-likepatterns,chocolate-likepatternsandsmoothregions.Theresultsfurtherverifiedthefeasibilityandlargepotentialoflaseradditivemanufacturingonfabricationandindustrialapplicationoflarge-scaleBMGsparts.

  • 标签: Zr-based BULK metallic glass Laser solid
  • 简介:Anitrate-citratecombustionroutetosynthesizeLa0.9Sr0.1Ga0.8Mg0.2O3-δpowderforsolidoxidefuelcellapplicationwaspresented.Thisrouteisbasedonthegellingofnitratesolutionsbytheadditionofcitricacidandammoniumhydroxide,followedbyanintensecombustionprocessduetoanexothermicredoxreactionbetweennitrateandcitrateions.TheoptimumtechnicalparametersarethatthepHvalueis5,andthemolarratioofcitricacidtothetotalmetallicionis1.5:1.X-raydiffractioncharacterizationofcalcinedgelshowsthatpurephasewassynthesizedaftercalcinationat1400℃for10h,andtheTEMresultshowsthecalcinedpowderwithaverageparticlesizeisabout150nm.Thegrainresistancecontributestothetotalresistanceofsinteredpelletbelow500℃.Theconductivityofthesinteredpellentat800℃was0.07S-1.cm-1higherthantheconductivityofYSZ(0.05S-1.cm-1at800℃)

  • 标签: La0.9Sr0.1Ga0.8Mg0.2O3-δ 固体氧化物燃料电池 工艺路线 硝酸盐 柠檬酸盐 合成