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21 个结果
  • 简介:Onenewsesquiterpenecompound,namely,illihenlactoneA(1),andonenewprenylatedC6–C3compound,illihenryioneH(2),alongwiththreeknownsesquiterpenes(3–5)wereisolatedfromthestemsofIlliciumhenryi.Thestructuresof1and2wereelucidatedbyspectroscopicevidenceincludingNMR,HRESIMSandcirculardichroism(CD).Compound2exhibitedaweakinhibitoryratioforbglucuronidasereleaseinducedbyplatelet-activatingfactor(PAF)inratpolymorphonuclearleukocytes(PMNs)invitro.

  • 标签: 下线 服务 迁移
  • 简介:Inthispaper,weintroduceaconditionweakerthantheLpdifferentiability,whichwecallCpcondition.Weprovethatifafunctionsatisfiesthisconditionatapoint,thenthereexiststhebestlocalapproximationatthatpoint.WealsogiveanecessaryandsufficientconditionforthatafunctionbeLpdifferentiable.Inaddition,westudytheconvexityofthesetofclusterpointsofthenetofbestappoximationsoff,{Pe(f)}ase→0.

  • 标签: 最佳局部逼近 充分必要条件 函数 可微
  • 简介:Inthispaper,weapplythecontractionmappingtheoremtoestablishsomeboundedandunboundedadditiveperturbationtheoremsconcerninglocalC-semigroups.SomegrowthconditionsofperturbationsoflocalC-semigroupsarealsoestablished.

  • 标签: 扰动定理 局部C半群 映射定理 生长条件 有界
  • 简介:ThefirststarsintheearlyUniversewereformedabout400millionyearsafterthebigbang.VerificationoftheexistenceofthesestarsisimportantforourunderstandingoftheevolutionoftheUniverse[1].IthasbeenpredictedthatforPopulation-IIIstellarproductionyields,theabundancesofodd-Zelementsareremarkablydeficientcomparedtotheiradjacenteven-Zelements[2].Astronomersaresearchingforlong-lived,lowmassstarswiththeuniquenucleosyntheticpatternmatchingthepredictedyields[3].

  • 标签: FIRST DIRECT MEASUREMENT
  • 简介:TheeffectofacidcomponentincludingvariousconventionalacidsandtungsticcompoundsonglucosehydrogenationoveraseriesofbinarycatalystsystemcontainingRu/Ccatalystwasinvestigated.TheresultsshowedthatHCl,H2SO4,H3BO3,H3PO4,andHNO3hadnegligibleeffect,whileallthetungsticcompoundsimposedinhibitingeffectsonthehydrogenationofglucoseoverRu/Ccatalyst,andthesuppressingeffectfollowedtheorderofH2WO4>HPW>WO3>AMT>HSiW.Thisorderisthesameastheorderofethyleneglycol(EG)yieldsintheone-potconversionofglucosetoEG,suggestingtheimportantroleofcompetitionbetweenglucosehydrogenationandretro-aldolcondensationincontrollingtheselectivityofEG.

  • 标签: 葡萄糖加氢 催化剂体系 钨化合物 钌/碳催化剂 抑制效果 醛醇缩合
  • 简介:纸的目的是估计Wasserstein测量的密度功能或分发功能公制的,统计距离的一种典型类型,它通常在统计学习被要求。基于古典伯恩斯坦近似,一个计划被介绍。得到计划的错误估计,到为单调C1功能估计伯恩斯坦近似的L1标准的问题拐弯,它是很少在古典近似理论讨论了。最后,我们由统计距离得到概率估计。

  • 标签: 伯恩斯坦 函数估计 公制 统计距离 分布函数 密度函数
  • 简介:Inthispaper,weintroducegeneralizedcyclicC-contractionsthroughpnumberofsubsetsofaprobabilisticmetricspaceandestablishtwofixedpointresultsforsuchcontractions.InourfirsttheoremweusetheHadzictypet-norm.InournexttheoremweuseLukasiewiczt-norm.OurresultsgeneralizetheresultsofChoudhuryandBhandari[11].Acontrolfunction[3]hasbeenutilizedinoursecondtheorem.Theresultsareillustratedwithsomeexamples.

  • 标签: MENGER space CAUCHY sequence fixed point
  • 简介:Arylhalidesareakindofextremelyvaluablecompoundsusedintransition-metal-catalyzedcouplingreactions,aswellasimportantstructuremotifsinmanynaturalproductsandmanufactureddrugs[1,2].Theclassicalapproachforpreparationofhaloarenesiselectrophilicaromaticsubstitution(EAS)usingvarioushalogenatingreagentsoroxidativehalogenationswithhalogenatingreagentgeneratedinsitufromhalidesandoxidants,suchasperoxide,oxygenandmeta-cholorperoxybenzoicacid(mCPBA)[3,4].However,harshreactionconditionsarerequiredforhalogenationoflessactivearomatics.orthoMetalationfollowedbyhalogenquenchingisanotherapproachforhalogenationofaromatics[5].However,thereareobviousdrawbacksforthesemethods,suchaslowregioselectivity,harshconditionsandevendangerousprocedures.Therefore,thedevelopmentofanalternativeandpracticalwayremainschallengeinorganicsynthesis.

  • 标签: 芳基卤化物 苯甲酸 琥珀酰亚胺 卤代 过渡金属催化 区域选择性
  • 简介:Toeffectivelysolvetheagglomerationproblemsinthesolidstatereactionprocess,pre-addingglucoseisadoptedtothesynthesisofLiFePO4/CenergymaterialsusingFe–Pwasteslag.Theaverageparticle&grainsizeofLiFePO4/Cdecreases,andtheimpuritiesinLiFePO4/Ccompositesreducetoagreatextent.Itmakesgreatsensetothemassindustrialproduction.Theoptimumsynthesisconditionsdeterminedinthisworkarebasedontheorthogonalexperiments.Thesamplessynthesizedinascaleof500gexhibithighpurity,excellentelectrochemicalperformance,highreactionactivity,goodreversibility,andlowpolarizationlevel.Thedischargecapacitiesare145,134,117,and102mAh/gatthecurrentdensitiesof0.1C,0.2C,0.5Cand1C,respectively.ThisworkputsforwardapracticalsuggestionformassproducingenvironmentalbenignandlowcostLiFePO4/Cascathodematerialsoflithiumionbatteries.

  • 标签: 材料使用 工业生产 磷渣 能源 最佳合成条件 锂离子电池
  • 简介:若无限长均匀带电直导线(线电荷)与接地平板系统的电场是二维静电场,当求解区域可视为为多边形时,则可应用S-C映射法和电像法为统一模型,求解出线电荷在求解区域所激发的电势。

  • 标签: S-C映射 电像法 接地平板系统 电势
  • 简介:Theroleofpulseparametersonnanoparticlepropertyisinvestigatedself-consistentlybasedonacoupleoffluidmodelandaerosoldynamicsmodelinacapacitivelycoupledparallel-plateacetylene(C2H2)discharge.Inthismodel,themasscontinuityequation,momentumbalanceequation,andenergybalanceequationforneutralgasaretakenintoaccount.Thus,thethermophoreticforceariseswhenagastemperaturegradientexists.Thetypicalresultsofthismodelarepositiveandnegativeiondensities,electronimpactcollisionsrates,nanoparticledensity,andchargedistributions.Thesimulationisperformedfordutyratio0.4/0.7/1.0,aswellaspulsemodulationfrequencyfrom40kHzto2.7MHzforpureC2H2dischargesatapressureof500mTorr.Wefindthatthepulseparameters,especiallythedutyratio,haveagreataffectonthedissociativeattachmentcoefficientandthenegativedensity.Moreimportantly,bydecreasingthedutyratio,nanoparticlesstarttodiffusetothewall.Undertheactionofgasflow,nanoparticledensitypeakiscreatedinfrontofthepulseelectrode,wherethegastemperatureissmaller.

  • 标签: 脉冲参数 C2H2 纳米颗粒 凝固模拟 电容耦合 自放电
  • 简介:本文讨论矩阵方程ATX+xTA=C的一般解及其最佳逼近解的正交投影迭代解法.首先,利用矩阵的结构特点及相关性质,并借助矩阵空间的相关理论,给出求该矩阵方程一般解正交投影迭代算法;其次,根据奇异值分解、F-范数正交变换不变性证明算法的收敛性并推导出算法的收敛速率估计式,当方程相容时,该算法收敛于问题的极小范数解,且对该算法稍加修改,就可得到相应最佳逼近解;最后,用数值实例验证算法的有效性.

  • 标签: Lyapunov矩阵方程正交投影迭代法 最佳逼近解收敛速率极小范数解
  • 简介:本文证明第二种服务可选的M/M/1排队模型的主算子的点谱包含一个区间(-α,0),α〉0.此结果表明该主算子生成的C_0-半群不是紧算子,甚至不是最终紧算子.本文的结果与我们以前的结果合并后得到:(i)该C_0-半群的本质增长界为0.从而,该C_0-半群不是拟紧算子.(ii)该模型的时间依赖解不可能指数收敛于其稳态解.(iii)该C_0-半群的本质谱半径等于1.

  • 标签: 第二种服务可选的M/M/1排队模型 特征值 几何重数 C_0-半群 本质增长界
  • 简介:Theoreticalmodelsofstellarevolutionpredictnegligiblequantitiesof6Li,9Be,and11Binthehydrogenburningphasesofastar’sevolution[1].TheprimordialBig-Bangnucleosynthesis(BBN)modelmightbemoregenerousinitsproductionoftheseelements[2].Theradiative-capturecrosssectionforprotoncaptureon11Bleadingto12CissmallatastrophysicallyinterestingenergiesbecauseofthelargeCoulombbarrier.

  • 标签: FACTORS LOW ENERGIES
  • 简介:Pt/WO3/CnanocompositeswithparallelWO3nanorodsweresynthesizedandappliedasthecathodecatalystforprotonexchangemembranefuelcells(PEMFCs).Electrochemicalresultsandsinglecelltestsshowthatanenhancedactivityfortheoxygenreductionreaction(ORR)isobtainedforthePt/WO3/CcatalystcomparedwithPt/C.ThehighercatalyticactivitymightbeascribedtotheimprovedPtdispersionwithsmallerparticlesizes.ThePt/WO3/Ccatalystalsoexhibitsagoodelectrochemicalstabilityunderpotentialcycling.Thus,thePt/WO3/CcatalystcanbeusedasapotentialPEMFCcathodecatalyst.

  • 标签: 质子交换膜燃料电池 阴极催化剂 纳米复合材料 WO3 纳米棒 电化学稳定性
  • 简介:Radiotherapyisacommontreatmentmodalityforheadandneckcancers,nasopharyngealcancers,primarybraintumorsandbrainmetastases.Alargenumberofpatientsintheworldwithprimaryormetastaticbraintumorswillrequirelargevolumeorwholebrainirradiationeveryyear.However,therapeuticirradiationnotonlykillstumorcells,butalsoinjuresnormalbraintissue,whichiscommonlyassociatedwithsignificantfunctionalmorbidityanddecreasedqualityoflifeinpatientstreatedwithbrainradiotherapy[1].

  • 标签: Protective Effects Hydroxysaffor