简介：Theeffectsofinterfacialmodifieronthemechanicalpropertiesofkaolin-filledpolyamide6(PA6)havebeenstudied.Theinterracialinteractionbetweenpolyamide6andkaolinhasbeencharacterizedbymeansofinfraredspectroscopy(IR)andscanningelectronmicroscopy(SEM).TheresultsshowthattheroleoftheinterracialmodifierliesinforminganelasticinterlayerwithgoodadhesionbetweenkaolinandPA6.Acompositewithhighimpactstrength,hightensilestrengthandhighelasticmoduluscanbeobtainedbyinsertingtheelasticinterfacialmodifierintotherigid-particle-filledpolymersystem.

简介：Thestraininducedcrystallizationbehaviourinpolyimidefrom1,4-bis(3’,4’-dicarboxyphenoxy)benzeneand4,4’-oxydianiline(PEI-E)hasbeeninvestigatedbyWAXD,DSCandFTIR.TheresultsobtainedshowthatcrystallizationinPEI-Edidtakeplacejustaftertensileyielding.Meanwhile,theeffectofstraininducedcrystallizationonthethermomechanicalpropertieswasstudiedbyDMAandTMA,theresultsofwhichindicatethatthecrystallizationandhotstretchinghaveacertaininfluenceonthedynamicmechanicalproperties,suchasweakeningtheβrelaxationanddecreasingtheglasstransitiontemperature.TheTMAresultsconfirmtheshiftingofglasstransitiontemperaturetolowertemperatureregionafterhotstretching.ThisphenomenoncouldbewellexplainedbytheeffectofresidualstressaccordingtoEyring’stheory.

简介：ThewastewaterfromnaphtholAs-EproductionprocesswastreatedwithmacroporouspolymericadsorbentNDA-222.NaphtholAs-Eand2,3-acidinthewastewatercouldberemovedcompletelyandtheTotalOrganicCarbon(TOC)ofthewastewaterwasdecreasedmorethan98%from1655mg/Ltolessthan30mg/L.TheadsorbatescouldbedesorbedcompletelywithNaOHaqueoussolution.

简介：EscherichiacoliL-asparaginasewasmodifiedwithO-car-boxymethylatedchitosanusingglutaraldehydeasacouplingagent.Theresultingcoujugateretainedmorethan50%ofitsoriginalenzymeactivityundertheprotectionofitsnormalsubstrateorproductandshowedmarkedresistancetoproteolysisbytrypsinandchymotrypsin.

简介：Segmentedblockcopolymerbasedonnylon6(N6)andpolyethyleneoxide(PEO)withstochiometricratiowassynthesizedviaatwo-stepprocess.ThefirststeprepresentsendcappingofN6inthepresenceofadipicacidleadingtocarboxyterminatedN6,andthesecondoneispolycondensationofthelatterproductwithPEOinthepresenceofcatalystandthermostabilizertoformahighmolecularweightmulti-blockcopolymer.SeveralmethodswereappliedtocharacterizethesynthesizedcopolymersuchasFouriertransforminfraredspectroscopy,protonnuclearmagneticresonancespectroscopy,differentialthermalanalysis,differentialscanningcalorimetry,X-raydiffractionandatomicforcemicroscopy.Theobtainedresultsconfirmedthemulti-blockstructureforcopolymerwithaveryhighdegreeofmicro-phaseseparation.Atomicforcemicroscopymicrographsindicatedthatthemorphologywasthedispersionofhighstiffnessnanostructuredpolyamide(PA)domainsintheamorphousregionofPEOmatrix,whichcanbeveryimportantintheirperformanceformembraneprocesses.

简介：包含磷氮(MSMM-Al-P)的新奇包含的火焰retardant被与聚酰胺66包含准备(PA66-MSMM-Al-P)为聚酰胺6的火焰延迟(PA6)。结构和PA66-MSMM-Al-P的热性质被Fourier变换红外线的光谱学，X光检查光电子光谱学和thermogravimetric分析描绘。包含火焰retardants(MSMMAl-P和PA66-MSMM-Al-P)的PA6易燃被限制的氧索引测试，垂直燃烧测试和锥热量计调查。火焰retardancy和锥calorimetric分析在flame-retardantPA6建议了在PA66和MSMM-Al-P之间的synergistic效果。flame-retardantPA6的热稳定性也被调查。

简介：基于的二naphthalimide的技术性质分散尼龙6上的染料和聚酯纤维面对脲被调查。基于的二naphthalimide驱散染料被综合。染料被净化然后充分描绘了使用1H-NMR，FTIR和融化的点分析。染料的分散在水里被准备并且在尼龙6上适用并且宠物纤维。染料在底层上提供了好逐渐增加性质。为了增加，染底层的吸附，脲被增加进dyebath。由增加脲，聚酯的染料吸附显著地被增加，当尼龙6的增加是不显著的时。染料在底层上显示出好迅速性质。

简介：PolysaccharidecoatedPLAnanoparticlesbearingaldehydegroupswerepreparedbydialysisofDMSOsolutionofcholesterolhydrophobic-modifieddextranpolyaldehydeandPLAagainstwater.Theaveragediameterofthenanoparticleswasabout160nm,andthesizedistributionwasnearlyhomogenous.ThenanoparticleswerefunctionalizedsimultaneouslywithCD71andEGFRantibodythroughtheSchiff'sbasereaction,andthenradiolabeledwith~(99m)Tc.Afterperfusedtheradiolabelednanoparticlesintotumor-bearing...

简介：Insitucompatibilizationoflowdensitypolyehylene(LDPE)(30%)andnylon-6(70%)blendsthroughone-stepreactiveextrusionusingt-BuOOHasaninitiatorandlowmolec-ularweightinterfacialagentsascompatibilizerswasstudied.Thecompatibilizercontainedalongchainbydrocarbon,doublebondandtwopolarfunctionalgroupswhichwascapableofreactingwithbothLDPEandnylon-6inthepresenceofinitiatortoformacopolymerattheinterfaceofthetwopolymerphases.Theextrudedblendsexhibitedsignificanten-hancementintheircompatibilitybasedonmorphological,thermalanalysisandmechanicalstudies.Theeffectofthehydrocarbonchainlengthandstructureofthefunctionalgroupofthecompatibilizerwasalsoexamined.Itwasfoundthatblendspreparedbyusingthecompatibilizercontaininglongerhydrocarbonchainandamidegrouphadbettermechanicalproperties.

简介：LigandeffectofthecatalyticsystemWCl6-Et2AlClforringopeningmetathesispolymerization(ROMP)ofdicyclopentadiene(DCPD)wasinvestigated.Theexperimentalresultsshowthataddingstericallyhinderedphenol-2.6-di-tert-butylcresylol(DTBC)inthecatalyticsystemnotonlycanobviouslyincreasethemonomerconversionofpolymerizationbutalsoimprovethemechanicalproperties,suchasnotchedimpactstrength(NIS),tensilestrength(TS)ect.,ofthesynthesizedpolydicyclopentadiene(PDCPD),Asimilareffectcanbeobservedbyusingastericallyhinderdpolymericphenol-linearphenolformaldehyderesin(LPF)asaligand.

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简介：AmethodforremovimgglucorapheninfromtheextractofRadishpigmentbyanionexchangeresin201×7wasstudied.Theadsorptioncapacityof201×7resinforglucorapheninwas72.8mg/mlresin,theequilibriumtime55minutes,andtheoptinumpH5.5.Allglucorapheninthathadbeenadsorbedon201×7resinwaselutedby1.5BV.hr^-1,eluentinwhincconcentrationofNaOHwas0.05mol·L^-1attheflowrateof1.5BV/h.Extractingsolutionofdeglucorapheninwasenrichedbyvacuumandspraydrying.ApowderproductofRadishpigmentwasobtainedandE1cm^1%=4.30.

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简介：HeBinglinwasbornonAugust24,1918inFanyuCounty,GuangdongProvince.HegraduatedfromtheChemistryDepartmentofSouthwestAssociatedUniversityin1942.AftergraduationheworkedinChongqingCentralInstituteofIndustryforoneyearasanassistantengineerandthenreturnedtohisAlmaMaterUniversity

简介：TheA-Bblockcopolymerof0634-chloroethylglycidyletherwithstyrenecanbegotbytheeasymethodofone-steppolymerization.ThestructureofA-Bblockcopolymerwasconfirmedbytheelementaryanalysis,turbiditytitration,molecularweightmeasurement,IR-spectra,13C-NMR,1H-NMRandDTAinvestigationoftheproducts.Also,theeffectsofsolvents,reactiontimeandtemperatureonthecomposition,Mnandyieldofcopolymerhavebeenstudied.

简介：Averymildandextremelyefficienthydrolysismethodfortransformationofpolystyrene-b-poly(tert-butylacrylate)(PS-b-PtBA)topolystyrene-b-poly(acrylicacid)(PS-b-PAA)wasdesignedandcarriedoutusingmoreconvenientandinexpensivechlorotrimethylsilane/sodiumiodideasreagents.Thehydrolysisproductcanself-assembleinaqueousmediatogiveregularmicelleswithPSblockformingthecoreandPAL4blockformingthecorona,orintetrahydrofuran(THF)togivereversemicelleswiththehydrophilicblockinthecore.

简介：Inthiswork,DSCandSEMstudiesindicatethation-ligandinteractioncanbeutilizedtoenhancetheinteractionofpoly(styrene-block-2-vinylpyridine)[P(S-b-2VP)]andpolyethylenebasedionomer(Surlyn).Thecompatibilityforthisblendingsystemcanbeimprovedbythisspecialinteractionand20/80wtistheoptimumblendingcompositionwithgoodcompatibility.FTIRresultsfurthercertifythatstronginteractionsexistintheblendingsystem.

简介：Kineticsofchloride/sulfate,chloride/nitrateandnitrate/sulfateforwardexchangesandreverseexchangesatsolutionconcentrationsof1N,0.2Nand0.02Non201×7strongbaseanionexchangeresin,respectively,havebeenexaminedat25℃.Itisfoundthattheforwardandthereverseexchangeratesofthetwogivenionsatlowsolutionconcentration,respectively,underidenticalconditionscanbecontrolledbydifferentmechanisms,whilethoseathighsolutionconcentrationareallcontrolledbyparticlediffusion.Theternaryexchangeratesofsulfate/(chloride+nitrate)andnitrate/(chloride+sulfate)havealsobeenexamined.

简介：Dithia-monoaza18-Crown-6anditsimmobilizationproduct,silica-bound1,7-dithia-4-aza-10,13,16-trioxa-cyclooctadecaneviaaspacerofthreecarbonatoms,anditsplatinumcomplexhavebeensynthesized.Itisfoundthattheplatinumcomplexisanefficienthydrosilylationcatalystforolefins.TheXPSdataoftheplatinumcomplexarereported.