简介:Themechanicalpropertiesatelevatedtempera-turesofcorundum-mullitematerialsandtheeffectsofzirconiaandtitaniaadditionshavebeeninvesti-gated.Theresultsarecorrelatedwithchangesinmicrostructure,Basedontheresultsoftheseinvesti-gations,reaction-sinteredcorundum-mullite-zirco-niamaterialswithimprovedhotstrengthandther-malshockresistancehavebeendevelopedforrefractor-riesusage.
简介:Inthispaper,zirconiaisusedastopmoldmaterialforTiinvestmentcasting.Topmoldsamplesaremadebypropermoldbuildingtechnology.Theeffectofdifferentsinteringtemperatureonchemicalcomposition,microstructureandresidualbendingstrengthofthetopmoldsampleisstudied.Thevolumeandhomogeneityoftheairholesinthetopmoldaredeterminedbysinteringtemperature,andfinallydeterminedtheresidualbendingstrengthofthemoldsamplewasdetermined.
简介:Theelectronicstructureof(001)polarsurfaceofcubiczirconiawasstudiedbyGGA(WC)approximation.Wefoundthecubiclatticenear(001)surfaceshowedanintensivetendencytotransfertotetragonallattice.Themetallicstateappearedonboththeterminations.ForO-termination,someO2pstateswerevacatedandholecarriersconcentratedonsurfaceoxygen-ions.ForZr-ermination,someZr4dstatesbecamepartialoccupiedforthelossofO2pstates.Weobservedtheholestatesweremainlylocalizedatthecorrespondingionsonsurfaceforboththeterminations,whilethechargestatesonZr-terminationweredispersedonsurface.
简介:Yttria-stabilizecl-zirconia(YSZ)hollowspheresarewidelyutilizedfortheirnovelphysicalandchemicalproperties.However,developingasimpleandlow-costmethodforpreparingsuchhollowspheresstillremainsagreatchallenge.Inthispaper,anatmosphericplasmaspray(APS)methodisintroduced,andtheformationmechanismofhollow7YSZ(ZrO2-7wt%Y2O3)spheresispresented.Thehollowspheremorphologywasobservedbyscanningelectronmicroscopy(SEM)whenagglomeratedandsintered7YSZpowderswereused.Additionally,additivecompositionchanges,phasetransformations,andthethermalbehaviorof7YSZpowderswereanalyzedbyenergydispersivespectroscopy(EDS),X-raydiffractometry(XRD),thermogravimetricanalysis(TG)anddifferentialscanningcalorimeteranalysis(DSC).Furthermore,thephasetransformationsofagglomeratedandsintered7YSZpowders,7YSZhollowspheresthatannealedatvarioustemperaturesfordifferenttimesareanalyzed.
简介:InthispaperwepresenttheresultsofstudiesonmakingMgOzirconiasinteredparts(intendedtobeusedasmeteringnozzlesincontinuouscastingofsteel)frommonocliniczirconiaandMgOpowdersviaagranulationprocess.Thepartswerepressedandsinteredunderdifferentconditions,andanalysedforphysicalproperties,microstructureandphasecomposition.WefoundastronginfluenceoftheMgOconcentrationandthesinteringcycle,especiallythecoolingrateonthethermalshockresistance.Thepaperconcludeswithrecommendationsfortheproductionofzirconiameteringnozzlesinaneconomicway.
简介:掺杂物在在协议的sintering期间定制微观结构起一个关键作用。这些掺杂物可以在体积以内形成稳固的答案,或分离到谷物边界(GB)和稳固蒸汽的接口(免费表面),引起管理质量的一种不同精力充沛的情形的各个在densification和谷物生长期间搬运。在这个工作,控制掺杂物分发的力量,特别地在表面和GB的并发的分离的可能性,基于分离的各自的热含量被讨论。一个方程基于系统的最小的吉布斯精力被导出从试验性的接口精力数据决定分离的热含量,并且当氧化钇的接口energetics上的掺杂物在它sintering的最后的阶段期间稳定了氧化锆,结果适用描绘La的角色。La实质地减少,这被显示出GB和表面精力(不同地)当sintering进行,动态地在这个阶段影响它的驱动力,和作为结果的谷物生长和densification。
简介:Reactionsintereddensezirconia-mullitecompositeswerepreparedbyisostaticallypressingfromzirconflourandreactivealuminawithdifferentproportionsofTiO2andCr2O3additives.Thepressedcompactsweresinteredatdifferentelevatedtemperatureswithvariablesoakingtimes.Microstructuresandphasedevelopmentinthesinteredcompactswereanalysedtoassesstheinfluenceoftheadditivesonthepropertiesofthezirconiamullitecomposite.