简介:Acceleratingtheconvergencespeedandavoidingthelocaloptimalsolutionaretwomaingoalsofparticleswarmoptimization(PSO).TheverybasicPSOmodelandsomevariantsofPSOdonotconsidertheenhancementoftheexplorativecapabilityofeachparticle.Thusthesemethodshaveaslowconvergencespeedandmaytrapintoalocaloptimalsolution.Toenhancetheexplorativecapabilityofparticles,aschemecalledexplorativecapabilityenhancementinPSO(ECE-PSO)isproposedbyintroducingsomevirtualparticlesinrandomdirectionswithrandomamplitude.Thelinearlydecreasingmethodrelatedtothemaximumiterationandthenonlinearlydecreasingmethodrelatedtothefitnessvalueofthegloballybestparticleareemployedtoproducevirtualparticles.TheabovetwomethodsarethoroughlycomparedwithfourrepresentativeadvancedPSOvariantsoneightunimodalandmultimodalbenchmarkproblems.ExperimentalresultsindicatethattheconvergencespeedandsolutionqualityofECE-PSOoutperformthestate-of-the-artPSOvariants.
简介:Icewatercontent(IWC)playsimportantrolesinweatherandclimatechange.DeterminingtheIWCsofcirruscloudswithmillimeter-wavelengthradarcanbeproblematicduetoinfluencesoficeparticlerotationontheirbackscatteringcrosssections.Wehereintroducemodelstodescribetheradiationpatternsofsixnonsphericalparticlesofspecificsizes.SimulationsusingHFSSsoftwarewereappliedtodescribethedifferencesresultingfromdifferentorientationsandequivalentspheres.Adoubleexponentialfunctionwasusedforfittingtodescribetherelationshipbetweentheparticles’maximumsizesandbackscatteringcrosssections.Thebackscatteringcrosssectionsofnonsphericaliceparticleswerecomputedbythemethodofmoment,andthoseoftheequivalentsphericalparticleswerecomputedbyLorenz-Mietheoryforthreedifferentorientations:fixed,horizontal,andrandom.AssumingthatamixtureofnonsphericaliceparticlesfollowstheB-Hmixingmodel,thesizedistributionofcirrusparticlesobeystheexponentialdistributionmeasuredbyNASAin2007.BycomputingtheIWCsofcirrusclouds,whichfollowstheabovementionedB-Hmodelandexponentialdistribution,theradarreflectivityfactorsofnonsphericaliceparticlesandequivalentspheresatthreedifferentorientationscanbecomputed.Subsequently,theIWCresultscanbeacquiredbyinputtingtheradarreflectivityvariablesintothewell-knownIWC-Zformula.TheanalysisdescribedheredemonstratesthatwhenusingtheradarreflectivityZ,theorientationmustbeconsideredinordertodeterminetheIWC.Usingequivalentspheretheory,thederivedIWCsunderestimatetheactualIWCs.Theseresultsareimportantforaccuratelyretrievingthemicrophysicalparametersofcirrusclouds.
简介:Twofamiliesofcatalysts,basedonPdnanoparticlessupportedonceramicasymmetrictubularaluminamembranes,arestudiesinthedirectsynthesisofH_2O_2.TheyarepreparedbydepositingPdintwoways:(i)reductionwithN_2H_4inanultrasonicbathand(ii)byimpregnation-deposition.Thefirstpreparationleadstolargerparticles,withaveragesizeofaround11nm,whilethesecondpreparationleadstosmallerparticles,withaveragesizearound4nm.Thecatalyticmembranesweretestedasprepared,afterthermaltreatmentinairandafterfurtherpre-reductionwithH_2inmild(100℃)conditions.SampleswerecharacterizedbyTEM,CO-chemisorptionmonitoredbyDRIFTSmethodandTPR,whilecatalytictestshavebeenperformedinasemi-batchrecirculationmembranereactor.Experimentalcatalyticresultswereanalysedusingtwokineticsmodelstoderivethereactionconstantsfortheparallelandconsecutivereactionsofthekineticnetwork.SmallerparticlesofPdshowlowerselectivityduetothehigherrateofparallelcombustion,evenifthebetterdispersionofPdandthushighermetalsurfaceareainthesampleleadtoaproductivityinH_2O_2similarorevenhigherthanthesamplewiththelargerPdparticles.IndependentlyonthepresenceofsmallerorlargerPdnanoparticles,anoxidationtreatmentleadstoasignificantenhancementintheproductivity,althoughthecatalystprogressivelyreducesduringthecatalyticprocess.Theinhibitionoftheparallelcombustionreaction(towater)inducedfromthecalcinationtreatmentremainsafterthein-situreductionoftheoxidizedPdspeciesformedduringthepre-treatment.Thisislikelyduetotheeliminationofdefectsiteswhichdissociativelyactivateoxygen,andtentativelyattributedtoPdsitesabletogivethree-andfour-foldcoordinationofCO.
简介:题目:悬浮等离子体喷涂过程中微纳米颗粒撞击基板的动力学模拟目的:研究微纳米颗粒在流场中的运动和传热特性,确定颗粒绕流的临界尺寸以及微纳米颗粒合适的喷涂距离。创新点:1.建立微纳米颗粒的受力和运动模型;2.推导颗粒粒径和斯托克斯数的关系,确定颗粒绕流的临界尺寸;3.确定适于微纳米颗粒的喷涂距离。方法:1.通过颗粒运动和传热的三维模型,模拟颗粒在等离子体流场中的运动和传热过程;2.对流场采用欧拉法进行求解,对颗粒采用拉格朗日法进行求解;3.动态追踪颗粒的轨迹和空间分布,从而得到颗粒的速度、温度和空间分布。结论:1.布朗力会影响纳米颗粒的分布;现有模型可以很好地模拟微纳米颗粒的行为。2.可以用斯托克斯数和粒径表征微纳米颗粒绕流的临界尺寸;当前工况下,临界粒径约为800nm。3.基板会影响流场结构和颗粒的空间分布;在当前研究中,得出有利于纳米颗粒沉积的喷涂距离约为50mm;对微米颗粒来说,喷涂距离应适当增大。4.微纳米颗粒的空间分布呈现不同的特点;纳米颗粒的分布区间更大,布朗力对纳米颗粒的作用比对微米颗粒更为显著。5.微纳米颗粒的运动和传热过程呈现不同的特点;纳米颗粒的惯性和热容小,因此它们的速度和温度变化更迅速。
简介:Byinvestigatingthecross-spectraldensityofpartiallycoherentmulti-rotatingellipticalGaussianbeams(REGBs)thatpropagatethroughafocusingopticalsystem,weobtaintheradiationforceonaRayleighparticle.Theradiationforcedistributionisstudiedunderdifferentbeamindexes,coherencewidths,andellipticalratiosofthepartiallycoherentmultiREGBs.Thetransverseandthelongitudinaltrappingrangescanincreaseatthefocalplanebyincreasingthebeamindexordecreasingthecoherencewidth.Therangeofthetrappedparticleradiiincreasesastheellipticalratioincreases.Furthermore,weanalyzethetrappingstability.
简介:Tadpole-shapedAunano-particleswithcontrollabletailsaresuccessfullyfabricatedbysimplyusinglaserfragmentationofseparatedAunano-spheresinliquid.Theoptimumlaserpowerdensities(1.5–3GW∕cm~2)canenablepartoftheindividualAunano-spheretobere-melted,released,andultra-rapidlyrecondensed/crystallizedontheoutsideoftheoriginalregion.Wefindthatthelengthofthetailinatadpole-shapedAunano-particlesignificantlyincreasesfromabout10to25nmbyincreasingthelaserpowerdensity.Benefitingfromtheuniquestructuralfeatures,thelocalizedsurfaceplasmonresonance(LSPR)absorptionspectraofthetadpole-shapedAunano-particlesbecomebroaderbyincreasingthetaillength.Moreover,theLSPRabsorptionbandalsoexhibitsanoticeableredshiftfromabout520to650nm.Ourresultsprovideaconvenientandvaluablestrategytofabricatednovelanisotropic-shapednano-structureswithfascinatingproperties.
简介:空CuO-CeO2-ZrO2nano粒子被作为反溶剂把甲醇用作溶剂和supercritical二氧化碳与supercritical反溶剂仪器准备。二个关键因素(即,压力和温度)被调查探索催化剂结构和药品化学药品性质的效果(即,形态学,减少的性质,氧存储能力和特定的表面区域)。产生材料与X光检查衍射(XRD)被描绘,高决定传播电子显微镜学(HRTEM),Brunauer-Emmett-Teller(赌注),氢温度规划了减小(H2-TPR)和氧存储能力(振荡)测量分别地。试验性的结果证明更低的温度支持了空结构nano微粒的生产。粒子形态学也显著地变化了,即稳固的构造然后首先被转移到空结构回到稳固的建设。为获得空nano粒子的最佳的条件在45点被决定
简介:Amethodtothree-dimensionalpositionmovingparticleswithonelensandtwocamerasisproposed.Twoparticleimageswithdifferentdegreesofdefocusingareadoptedtosolvetheambiguousproblemofparticlepositions.Asingle-lensdual-camerasystemisdevelopedtosimultaneouslycapturethesetwoimagesforthemovingparticles.Themeasurementprinciplesandtheoreticalanalysisareintroducedfirst,andthensimulatedinvestigationsandexperimentalresearcharediscussed.Themeasurementerrorsinthesimulationsandexperimentsarelessthan1%and4%,respectively,in20timesthedepthoffieldofthesystem,whichvalidatesthefeasibilityofthismethod.