简介:通过电化学技术分析镁空气电池阳极Mg-Al-Pb-La合金的放电行为,并与Mg-Al-Pb合金的放电行为进行比较.结果表明,相对于Mg-Al-Pb合金,Mg-Al-Pb-La合金在开路电位下耐蚀性增强,表现出更好的放电活性.Mg-Al-Pb-La合金阳极的利用效率比商用Mg-Al-Zn(AZ)和Mg-Al-Mn(AM)合金阳极的利用效率高.由Mg-Al-Pb-La阳极和空气阴极组成的单个镁空气电池的平均放电电压为1.295V,在放电电流密度为10mA/cm2时其放电容量为1370mA·h/g,比Mg-Li合金作为空气电池阳极时的放电容量高.Mg-Al-Pb-La阳极放电性能的增强是由于显微组织的改变降低了自腐蚀,加速了电池放电过程中氧化产物的脱落.另外,分析了Mg-Al-Pb-La合金阳极在放电过程中的溶解机制.
简介:Mg-Al-Pb合金是一种新开发的海水激活电池材料。采用熔炼浇注法制备Mg-6Al-5Pb-0.5Mn系列合金和Mg-6Al-5Pb合金。其中,Mg-6Al-5Pb-0.5Mn系列合金是以Al-15%Mn、Al-30%Mn和Al-50%Mn中间合金为添加剂制备的。采用金相显微镜和扫描电子显微镜表征其组织,采用电化学方法、析氢法和失重法研究其性能。结果表明:以Al-50%Mn中间合金为添加剂制备的Mg-6Al-5Pb-0.5Mn合金具有最负的放电电位(-1.66V),最小的腐蚀电流密度(7μm/cm2)和自腐蚀速率(0.51mg·h-1·cm-2)。这可能是因为Al11Mn4相的存在,不仅有利于腐蚀产物的脱落和增大电化学反应面积,而且也提高电化学活性。
简介:在之中无铅焊接材料,Sn-Ag-Cu合金有许多优点优异界面的性质和高度例如好弄湿的性质,爬抵抗。在这篇文章,组织和Sn-Ag-Cu材料的焊接性能被调查。二合金的表面形态学被实体镜的显微镜观察并且扫描电子显微镜(SEM)。化学宪法被X光检查精力散的光谱学(版本)检验。Sn-Ag-Cu的机械性质焊接Sn-Cu与那些相比系统地被评估焊接。结果证明Sn-Ag-Cu焊接基于不同焊接垫不同焊接性质。在接口的金属间化合的化合物(IMC)的厚度与老化时间增加。为镀金的垫,有很多IMC图,并且在焊接连接它能减少电的连接的可靠性。Sn-Ag-Cu焊接关节表演在传统的Sn-Cu上的一个优异机械性质焊接。酒窝减少和洞的数字增加因为Sn-Cu0.7合金和Sn-Ag3.0-Cu0.5合金的破裂表面有同类地分布式的许多小尺寸酒窝。
简介:通过微弧氧化法在新型医用近β钛合金Ti-3Zr-2Sn-3Mo-25Nb表面制备一层含Ca、P多孔薄膜,再将其在胺基化溶液中活化处理以在薄膜表面引入NH-2。借助XRD、SEM和EDS研究该多孔复合薄膜的组成和表面形貌,并通过模拟体液浸泡实验、体外细胞培养实验和动物体内植入实验研究经上述表面改性处理后的Ti-3Zr-2Sn-3Mo-25Nb合金的骨诱导活性。结果表明:该薄膜主要由金红石型TiO2和锐钛矿型TiO2组成,是一种含有Ca、P的陶瓷混合物;薄膜在模拟体液中具有很好的生物活性,成骨细胞能够很好地在薄膜上分化、生长;表面覆膜处理的Ti-3Zr-2Sn-3Mo-25Nb合金的体内骨诱导活性优于未处理的Ti-3Zr-2Sn-3Mo-25Nb合金的。
简介:ZrO2-SnO2compositenanoparticleswerepreparedbyheatingthehydrateprecursorssynthesizedbythechemicalco-precipitationreactionofZrOCl2andSnCl4.Theprecursorswereexaminedbydifferentialthermalanalysis(DTA)andthermogravimetricanalysis(TGA).ThecompositepowderwascharacterizedusingX-raydiffraction(XRD),transmissionelectronmicroscopy(TEM)anddesorptionisotherm(Barrett-Joyner-Halendamethod).Theaveragecrystalsizeofthenanoparticlerangesfrom15to30nmforthesamplecontaining5%-25%ZrO2(massfraction).MostoftheporesintheZrO2-SnO2nanoparficlesareabout10-20nmindiameter.Thecompositepowderispromisingforchemicalsensors.
简介:Zinctinoxide(ZTO)thinfilms,withzincacetateandtributyltinchlorideasrawmaterials,weredepositedonglasssubstratesbythemethodofmetalorganicchemicalvapordeposition(MOCVD).Thecrystallization,microstructureandopticalpropertieswereinvestigatedbyscanningelectronicmicroscope(SEM),X-raydiffraction(XRD)andultraviolet-visible(UV-Vis)spectrophotometer.TheresultsshowthatwiththeincreaseinSn/Znratio,thecrystalchangesfromwurtzitetorutilephase.Whentheratioreaches11:18,theintensityofZn_2SnO_4peaksappearstobethestrongestandtheopticalbandgapisabout3.27eV.Calculatedbytheenvelopemethod,thethicknessoftheZTOthinfilmsis713.24nm.MeasuredbyUV-Visspectrophotometer,thetransmittanceoftheZTOthinfilmsreachesupto80%inthewavelengthrangeof400-1000nmwhentheSn/Znratiois7:18.
简介:利用平衡合金法,采用扫描电镜-能谱仪和X射线衍射方法对Al-Fe-Sn三元系973和593K等温截面的相关系进行实验测定。实验结果表明:在此两个截面上均未检测到三元化合物;973K时液相中Fe的最大固溶度为1.6%(摩尔分数),而593K时Fe和Al在液相中的最大固溶度分别为0.6%和5.1%(摩尔分数);在973和593K等温截面上,Sn在Fe-Al化合物中的最大固溶度分别为4.2%和2.3%(摩尔分数);Fe-Al化合物均能与液相保持平衡。
简介:ThemicrostructureandtensilepropertiesofSn-9Znsolderunderdifferentcoolingandagingconditionwerestudied.Duringsolidification,thedistributionofZn-richphasesandgrainsizeinthemicrostructureofSn-9Znsolderweredecidedbythecoolingrate.TheZn-richphaseinSn-9Znsolderunderfurnacecooling,aircoolingandwatercoolingmediawasseparatelyexistedascoarsendendriticandneedlelikeshape,fineneedlelikeshapeandveryfinerod-likeshape,respectively.Afteraging,thecoarsendendriticwasbrokenandthecoarsenneedlelikeZn-richphasewaspartlychangedintofinedistributionofZn-richphaseforSn-9Znsolderwithfurnacecooling,andtherod-likeZnphaseintheSn-9ZnsolderunderwatercoolingwaschangedtoconglomeratedZnwithneedleshape.DuringtensiletestingonSn-9Znsolder,tensilestrengthandductilityreachedthebestwithwatercooling,butdecreasedwithagingeffect.Meanwhile,theductilityofsolderwithaircoolingandthestrengthofsolderwithfurnacecoolingincreasedwithaging.Thefracturemodewasductileandwasindependentofcoolingmediaandagingeffect.Thesizeanddepthofdimplesdecreasedfromwater,furnacetoaircooling.Afteraging,numberandsizeofdimplesincreasedonthesolderwithfurnacecoolingandaircooling.ThechangeonthesizeofdimplesfortheSn-9Znsolderunderdifferentcoolingconditionandwithagingeffectwasaccordancetothetensileproperties.
简介:Chemicalreductionmethodwasemployedtopreparenano-sizedSn2SbNialloycompositesusedasanodematerialforrechargeablelithiumionbatteries.Thisstrategywasadoptedtocombinethevirtuesofbothactive/inactiveandactive/activealloystofabricateaSn2SbNialloypowderwithtwoactivecomponentsandoneinactivecomponent.Thetwoactivecomponentscanrealizethehighcapacityfeatureofelectrodeandcanmakethevolumechangeofelectrodetakeplaceinastepwisemannerduetothedifferentlithiationpotentialsoftwoactivecomponents,leadingtoastablecyclingperformance.Sn2SbNialloyprovidesareversiblespecificcapacityover640mA·h/gwithanexcellentcyclicability.TheSn-Sb-Nialloycompositematerialshowstobeagoodcandidateanodematerialforthelithiumionbatteries.
简介:研究Sb元素含量对Sn-Bi系焊料性能的影响。通过差示扫描量热法研究Sn-Bi-Sb焊料的熔化行为。采用铺展实验研究焊料在Cu基板上的润湿性。测试Sn-Bi-Sb/Cu结合界面的力学性能。结果表明:三元合金中含有包共晶反应形成的共晶组织,随着Sb含量的增加,共晶组织增多;在加热速率为5℃/min的条件下,三元合金显示出更高的熔点和更宽的熔程;添加少量Sb对Sb-Bi系焊料的铺展率有影响;在焊料铺展过程中形成反应过渡层,反应过渡层中存在Sb元素而无Bi元素,过渡层厚度随着Sb元素含量的增加而增大。Sn-Bi-Sb焊料的剪切强度随着Sb元素含量的增加而升高。
简介:[篇名]InfluenceofWCadditionanmicrostructuresoflaser-meltedNi-basedalloycoating,[篇名]MicrostructureanddryslidingwearbehavioroflasercladNi-basedalloycoatingwiththeadditionofSiC,[篇名]PreparationofAdvancedLithiumSecondaryBatterieswithTin-IronAlloyPlatingAnodesandTheirCharge-DischargeBehaviors,[篇名]SnAg-alloycoatingforconnectorsandsolderingapplications,[篇名]Structureandpropertiesofwear-resistanttitaniumcarbonitride-basedcoatings,[篇名]TheanalysisofthedepositionmechanismofZn/NialloyplatingusinganEQCM,[篇名]Theeffectofheattreatmentonwearresistanceofpartshavinghard-alloycoating.
简介:AdvancedLithiumSecondaryBatteriesUsingTin-IronAlloyNegativeElectrodesPreparedbyElectroplating;CavitationerosionofTi-Nishapememoryalloycoating;Effectsoffueldyeonthehotcorrosionresistanceofmarinegasturbinematerials;EffectsofphosphorouscontentsandambienthumidityonthefrictionandwearpropertiesofNi-W-PalloyplatingFrictionandwearofelectrolessNialloyplatedgearundernon-lubricationconditioninhighvacuum
简介:ACOUPLEDMACRO-MICROSIMULATIONFORTHEPREDICTIONOFMICROSTRUCTUREOFALALLOYCASTINGS,AstudyonporositydistributionofA356aluminumalloycastings,Diagnosisofoxidcfilmsbycavitationmicro-jetimpact,Effectofflyash(asanadditivetogreensand)onthesurfaceroughnessofAl-7%SialloycastingsusingTaguchiTechnique,EffectofSolidificationTimesonCrackOpeningDisplacementofAluminumAlloyCastings,EvaluationofinversesegregationinCu-8mass%Sialloyingotwithvisiblelightspectroscopy.