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115 个结果
  • 简介:Silicaaggregateswerepreparedbybase-catalyzedhydrolysisandcondensationofalkoxidesinalcohol.Polyethyleneglycol(PEG)wasusedasorganicmodifier.ThesolswerecharacterizedusingSmallAngleX-rayScattering(SAXS)withsynchrotronradiationasX-raysource.Thestructureevolutionduringthesol-gelprocesswasdeterminedanddescribedintermsofthefractalgeometry.As-producedsilicaaggregateswerefoundtobemassfractals.Thefractldimensionsspannedtheregime2.1-2.6correspondingtomorebranchedandcompactstructures.BothRLCAandEdenmodelsdominatedthekineticgrowthunderbase-catalyzedcondition.

  • 标签: 硅溶胶 碱催化水解 聚乙二醇 SAXS 小角X射线散射分析 结构分析
  • 简介:1ScopeThisstandardspecifiestheglossaryanddefinition,marking,shapeanddimension,technicalrequirements,testmethod,qualityappraisalprocedure,packing,label,transportation,storageandqualitycertificationofsilicabrickforhotblaststove.

  • 标签: 热风炉 硅砖 耐火材料 品质
  • 简介:ThispaperreviewsthehistoryofdevelopmentandproductionofsilicabricksatLuoyangRefrac-tories(Group)Co.,Ltd,(FormerLuoyangRefrac-toriesFactory).Throughtheimprovementandin-troducingtechnologyfromabroadthecompany'smanagementandqualitystandardonsilicabricksproductionhasreachedahigherlevel.Thephysicalandchemicalspecifications,aswellastheappear-anceofsilicabricksforcokeovens,hotblaststovesandglasskilnshavereachedtheadvancedinterna-tionallevel.NowthecompanyhasbecomeproducingbaseandmainexportingbasevariouskindsofsilicabricksinChina.

  • 标签: 发展趋势 硅砖 耐火材料 物理性质 化学性质
  • 简介:TheannualoutputofChina'ssilicabrickamountsuptoover300thousandtons,whichaccountsformorethan70%ofthetotaloutputofsilicabricksintheworld.Besidessatisfyingdomesticmarkets,China'ssilicabrickshavebeenexportedtomanycountriesandregionssuchasJapan,USAetc.Inthispaper,thesituationofsilicabricksproduction,technology,salesandexportinghavebeendescribed.Alsosuggestionsonimprovementofsilicabricksqualityandexporting,corporationwithforeignpartnershavebeenputforwardinordertowinlargermarketsharebothathomeandabroad.

  • 标签: 中国 硅土砖 产量 市场 生产 耐火材料工业
  • 简介:SmallX-rayScattering(SAXS)experimentusingSynchrotronRadiationasX-raysourcewasusedtodeterminetheaveragewallthicknessofmesoporoussilicaprepardbycondensationoftetraethylorthosilicate(TEOS)usingnon-ionicalkylpolyethyleneoxide(AEO9)surfactantastemplates.Theresultsagreedwiththatofhigh-resolutionTEM(HRTEM)measurement.

  • 标签: 小角X射线散射分析 SAXS 中孔硅石 平均壁厚 结构分析
  • 简介:Dreippingelectrolytesintosilicasol,gellingreactionwilloccur,Theresearchindicates:thisisacomplicatedphysicemistrycourse,whichconsistsofapre-reactionandapolymerizaion,Theformercontrolsthewholecourse,andinwhichelectroniclayersofthesol'sparticlesbe-comemoreandmorethiner,butwithincresingofthesolconcentration,itscontrolforcewillbediminished,tillthefast-coagulation,thegellingcousebecomeso-controlled,Thelatterisanin-finitepolymericchani-reaction.Theresultofgelatinationistoproduceaverybigplymericmolecule-gel,whichinvolvesinallspace,includesallwater,anditsmolecularweightisin-definitebig.Theresearhalsoindicates:thedy-namiccourseofthegellingcouldbedescribedquantitaivelybyanexperienceformula:lgt=-nlgc+B,Allofthecharacteristicvalueshavedefinitephysicalmeaning,Electronicvalueofthecontrary-inosisthebiggestinfluentialfactor,thenaturesofthecontrary-ionsandthenaturesofthesame-electronic-inoshaveafewinfluentialforcesonthecharacteristicvalues,Thetemperatureincreasingmakesthegellingreactionfast.

  • 标签: 动力学 硅溶胶 凝胶层 耐火材料
  • 简介:Whenasilicaopticalfiberisusedfortransmittingultraviolet(UV)light,theproblemsassociatedwiththedamageandtransmissiondeteriorationofsilicafiberintheUVregionneedtobesolvedinthefabricationprocess.Inthispaper,animprovedsilicafiberfabricationprocesswaspresentedtoenhanceUVtransmission,whichcombinedtheUVpre-irradiationonhigh-OHconcentrationpreformwithheattreatmentwhiledrawingfiber.Theimpactofthestructuraldefectsandcolorcenterswasdiminishedgreatlybythenewmethodoffabrication.Theexperimentalresultsaccordedwiththetheoreticalanalysis,andtransmissionwasimprovedabout0.4-0.7dB/mforwavelengthfrom350to400nm.

  • 标签: 硅光纤 增强紫外线传输 制作工艺 波长
  • 简介:适当大小被需要控制钙离子内容并且在好矿物质粒子之中减少相互作用。在这份报纸,闪锌矿/硅石相互作用被希腊语的第六个字母潜在的大小和新奇希腊语的第六个字母潜在的分布(ZPD)学习在钙离子答案的不同集中的测量方法。到分子的学习矿物质表面和原子吸收状态,精力散光谱学(版本)和扫描电子显微镜(SEM)被使用。在矿物质表面上吸附的筹款试剂被相互作用地位分析。结果证明当钙离子集中在溶液高时,筹款试剂的那吸附不是导致的。减少钙离子集中是有效方法在肉减少粒子相互作用。特定的方法是钠碳酸盐的适当数量被增加进使过饱和石膏的答案。矿物质相互作用能被测量ZPD解释。

  • 标签: 闪锌矿 硅石 相互作用 希腊语的第六个字母潜在的分发 筹款试剂
  • 简介:Asmall-anglex-rayscattering(SAXS)techniqueusingsynchrotronradiationasthex-raysourcehasbeenemployedtocharacterizethemicrostructureofmesoporoussilicapreparedbyone-pottemplate-directedsynthesismethodology.ThescatteringofpuresilicaagreedwithPorod’slaw.thescatteringoforganomodifiedmesoporoussilicashowedanegativedeviationfromPorod’slaw,suggestingthataninterfaciallayerexistsbetweentheporesandsilicamatrix.Itwastheorganicgroupscomprisingtheinterface,asshownby^29Sicross-polarizationmagic-anglespinningnuclearmagneticresonanceimaging(^29SicpMAS/NMR)andFouriertransforminfraredspectroscopy(FTIR),thatcausedthisnegativedeviationofSAXSintensityfromPorod’slaw,andtheaveragethichnessoftheinterfaciallayercouldbededucedfromthisnegativedeviation.Copyright2001johnWileyandSons,Ltd.

  • 标签: SAXS 小角X射线散射分析 有机中孔硅石 结构分析 界面 负偏差
  • 简介:Thevariationsinnutrients(molarratios)andchlorophyllaintheJiaozhouBaywereexaminedbeforeandafteradiatombloominaperiodthatlastedfromNovember2003toMarch2004.Negativerelationshipsbetweennutrientconcentrations,Si/P,Si/Nratiosandchlorophyllacontentwerefoundduringthebloom,whichreflectedtherelationshipbetweennutrientconcentrations,phytoplanktonbiomassandgrowth.Largeincreaseinnutrientconcentrations,particularlySiO3-Siafterthelateautumn,isoneofmajorreasonsinducingthediatombloominwinter,andthebloomwasfinallycontrolledduetoSiO3-Sidepletionbyphytoplankton.ThebloomwasmainlycontrolledbySiO3-Si.Before1998,relativelylowlevelofSiO3-SikeptecologicalbalanceofeutrophicationwatersintheJiaozhouBay.Inrecentyears,however,humanactivitieshaveincreasedSiO3-Siconcentration,whichislikelyoneoftheprimarycausefortheincreaseddiatombloomsintheJiaozhouBay.Therefore,itisnecessarytocontrolSiO3-SiconcentrationintheJiaozhouBay.

  • 标签: 胶州湾 硅藻 水华 叶绿素A含量 营养盐浓度 浮游植物生物量
  • 简介:JC/T616-20031ScopeThisstandardspecifiestheclassification,technicalrequirements,testmethod,inspectionrules,marking,packing,transportation,storageandqualitycertificationofhighqualitysilicabricksforglassmeltingfurnace.Thisstandardisapplicabletothepressedhighqualitysilicabrickswithunitweight≥40kgforglassmeltingfurnace.

  • 标签: 玻璃 熔化炉 硅化砖 耐火材料
  • 简介:Poly(bis(phenoxy)phosphazene)(SPBPP)/phosphotungsticacid(PWA)/silicacompositemembranesforfuelcellswereprepared.ThecompositemembraneswerecharacterizedbyusingFTIR,TGAandSEMtechniquies.IncorporationofPWAparticlesandsilicaparticlesintotheSPBPPpolymermatrixandaspecificinteractionbetweenthemwereconfirmedbyFTIRspectra.TGAresultsshowedthatthecompositemembraneshadhighthermalstability.HomogeneousdistributionofPWAandsilicaparticleswithintheSPBPPmatrixwasverifiedbySEMmicrographs.Thedopedmembranesshowedincreasedwateruptakeandprotonconductivity.

  • 标签: 二氧化硅粒子 复合膜 磷钨酸 聚磷腈 掺杂 FTIR光谱
  • 简介:分散硅石的NiMohydrodesulfurization催化剂被免职降水方法综合。为比较目的,体积NiMo催化剂被一起沉淀获得。分散硅石的NiMo催化剂有高度活跃的金属内容。硅石被采用为活跃部件的完整的利用驱散活跃金属。赌注分析证明分散硅石的NiMo催化剂有一个高表面区域(147.0m2/g)和毛孔体积(0.27mL/g),而体积NiMo催化剂展出了一个很低的表面区域(87.5m2/g)。传播电子显微镜学结果证明活跃部件在SiO2底层上被驱散。分散硅石的NiMo催化剂和体积NiMo催化剂的X光检查衍射模式被索引到NiMoO4。分散硅石的NiMo催化剂的hydrodesulfurization活动比引用催化剂的高得多并且能直到比那些两次大商业NiMo支持氧化铝的系统每催化剂的克。测试结果的活动也证明分散硅石的NiMo催化剂是有效hydrodesulfurization催化剂。

  • 标签: 加氢脱硫催化剂 二氧化硅 分散 合成 透射电子显微镜 比表面积
  • 简介:Waveguidingpropertiesofsilicananowiresinvariousenvironmentsarestudiedbysolvingtheeigenvalueequationsofacircularcross-sectionwaveguidenumericallyincylindricalcoordinates.Thesingle-modecondition,propagationconstants,poyntingvectorandpowerdistributioninsideandoutsidesilicananowirearecalculated.Theresultsshowthatsilicananowiresinwater,comparedwithsilicananowiresinair,havehigherfractionoftheevanescentfields.Duetothesensitivitytosurroundingenvironment,silicananowiresareverysuitableforsensingelements,whichcanbeusedtoimplementasingle-modefiberopticevanescentwavesensingelementofhighlysensitiveandaccuratemeasurement.

  • 标签: 硅纳米线 周围环境 波导 应用 属性 单模光纤
  • 简介:Ascokeovenbecominglarger,silicabrickforcokeovenisrequiredtobeofhighuqality,LuoyangRefractories(Grop)Co.Ltd.(LRCO)hasre-searchedthemineralizerwhichcontainsCa^2+,R^+,Al^3+,F^-,emphaticallyandproposedtheprincipleofcompositemineralizerbasdonthepropertiesofrawmaterialsused.Highperformancesiliabrickwhichischaracterizedbylowthermalexpansionrate,goodhightemperatureproperties,residualquartz<0.5%,truedensity2.31,andhighbulkdensitysilicabrickforcarbonizationroomwithapparentporosity13%,bulkdensityl.96g/cm^3havebeendevelopedandproducedsuccessfullybyLR-CO.Thequalityofthebrickshasreachedtheinter-nationaladvencedlevel.

  • 标签: 发展趋势 高硅砖 二氧化硅 耐火材料 焦炉 LRCO
  • 简介:Acolloidalsilicasolbondedproductrangeisintroducedbyanexampletargetinghightemperatureapplicationsinsteelmaking.Placementandsettingcharacteristicsareshown.Thethermalmechanicalpropertiesandresultingadvantagesarepresentedaswellastheperformanceenhancementincorrosionresistance.PropertiesarecomparedtoacommonULCCproduct.Resultsoftheindustrialtrialphasearediscussed.

  • 标签: 二氧化硅溶胶 胶体 应用 高温 浇注料 热机械性能