简介:碳nanofibers(CNF)的表面functionalization被执行,ie,CNF第一被氧化然后表面经由一个集会方法是由3-Aminopropyltriethoxysilane(APTES)的silanized。一种新类型高穿抵抗s-CNFs/epoxy合成被制作由在原处反应。FTIR光谱学被用来检测silane在CNF的表面上生产的功能的组的变化。tribological性质和微观结构修改,未修改的CNFs/epoxycomposites分别地被学习。expremental结果显示APTEScovalently成功地被连接到CNF的表面并且在环氧基树脂矩阵改进CNF的分散。磨擦系数和s-CNFs/epoxycomposites的wear率是比在一样的负担下面的u-CNFs/epoxycomposites的那些显然低的。调查也显示磨料穿主要为u-CNFs/epoxy穿机制合成,为在一样的滑动下面合成的s-CNFs/epoxy与细微粘合剂穿穿状况。
简介:λ-MnO2waspreparedbycolumnmethodfromnormalspinelLiMn2O4withpurityof99.38%.TheinfluenceofLiMn2O4grainsizeandacidityofleachingsolutiononthelithiumleachingprocesswasstudied.TheresultsshowthattheappropriaterangeofLiMn2O4grainsizewas60-160meshesandtheconcentrationofleachingsolutionHClwas0.1mol·L-1.TheadsorptioncapacityQofλ-MnO2forlithiumincreasedwiththeincreaseofpHandchangedmarkedlyatpH6.0-10.0.Itwas3.80mmol/gatpH12.0.ThedistributioncoefficientsKdofLi+andNa+were3.406×104and2.300respectively,andtheseparationcoefftcientaLiNawas1.481×104atpH6.5.Asaresult,λ-MnO2isahighperformanceion-sievematerialforlithiumion.
简介:Theelectronicstructureandbondingnatureofaseriesofcollectorsinthecalciumandmagnesiumcontainingmineralssystemarestudiedusingquan-tumchemistryCNDO/2method.Thedifferenceincol-lectingpropertiesisdiscussedbymeansofcharac-teristicparametersderivedfromthequantumchem-istrycalculations,andthedevelopingdirectionoffattyacidcollectorsispredicted.
简介:有公式La9.33Si6O26的磷灰石类型镧硅酸盐被大音阶的第五音胶化过程准备。答案的pH价值影响的大音阶的第五音的同质被调查。大音阶的第五音的粘性稍微增加第一然后因为占优势的反应机制从水解作用反应改变到冷凝作用反应,突然地增加。另外,为粘性的增加的发作时间从pH弄短1到pH4。冻结时间与增加答案的pH减少。因此,大音阶的第五音的pH应该是不到4形成胶化。有起始的pH的大音阶的第五音希腊语的第六个字母潜力和最大的稳定性的2表演最大值价值。为有起始的pH的样品2,在弄干的胶化被锻烧在以后,纯磷灰石类型镧硅酸盐La9.33Si6O26成功地被准备了1000
简介:Althoughin-situgrowingcarbonnanotubes(CNTs)oncarbonfiberscouldgreatlyincreasethematrix-dominatedmechanicalpropertiesofcarbon/carboncomposites(C/Cs),italwaysdecreasedthetensilestrengthofcarbonfibers.Inthiswork,CNTswereintroducedintounidirectionalcarbonfiber(CF)preformsbyelectrophoreticdeposition(EPD)andtheywereusedtoreinforceC/Cs.EffectsofthecontentofCNTsintroducedbyEPDontensilepropertyofunidirectionalC/Cswereinvestigated.ResultsdemonstratedthatEPDcouldbeusedasasimpleandefficientmethodtofabricatecarbonnanotubereinforcedC/Cs(CNT—C/Cs)withexcellenttensilestrength,whichpaysameaningfulwaytomaximizetheglobalperformanceofCNT—C/Cs.
简介:Silicide涂层被泥浆包硬化进程为把SiO2用作纯艾尔Si来源的12h在1173K在铜矩阵上在electro-deposited镍层上作好准备作为reducer搽粉,NaF+NH4Cl和蛋白(鸡蛋白人)是连贯的代理人。微观结构,性质和silicide涂层的siliconizing机制被讨论。有220μm厚度的silicide涂层主要是的试验性的结果表演Ni2Si阶段和Ni31Si12阶段。它的吝啬的微坚硬(HV790)比铜底层(HV70)的是十次。磨擦的系数从0.8纯铜减少到大约0.3硅Z样品。SiF2,SiCl2和SiCl3在泥浆包装硬化过程期间为Si的交通和免职负责。
简介:Anovelsolubleπ-conjugatedpolymer,poly[(3-acetylpyrrole-2,5-diyl)p-(N,N-dimethylamino)azobenzylidene](PAPDMAABE),wassynthesizedbycondensationof3-acetylpyrrolewith4-aldehyde-4'-dimethylaminoazobenzene(ADMAA).ThechemicalstructureofPAPDMAABEwascharacterizedbyFouriertransforminfraredspectroscopy(FTIR),1H-NMR,andUV-Vis-NIRspectra.Transmissionelectronmicroscope(TEM)analysisforPAPDMAABEindicatesthatpartofPAPDMAABEisincrystalstate,duetotheshort-rangeorderofthepolymer.Thermogravimetricanalysis(TGA)curveshowsthatthepolymerhasgoodthermalstabilityanditsdecompositiontemperatureis248℃.TheopticalbandgapofPAPDMAABEobtainedfromtheopticalabsorptionspectrumisabout1.73eV.Theresonantthird-ordernonlinearopticalpropertyofPAPDMAABEat532nmwasstudiedusingdegeneratefour-wavemixing(DFWM)technique.Theresonantthird-ordernonlinearopticalsusceptibilityofthepolymerisabout7.48×10-8esu.
简介:ThecompositenanofibersofSrTiO3/SrFe12O19withamolarratioof1:1anddiameterabout120nmwerepreparedbyelectrospinning.Effectsofcalcinationtemperatureontheformation,crystallitesize,morphologyandmagneticpropertywerestudiedbyinfraredspectroscopy,X-raydiffraction,scanningelectronmicroscopyandvibratingsamplemagnetometer.Thebinaryphaseofstrontiumferriteandtitanatewasformedafterbeingcalcinedat900℃for2handthecompositenanofiberswerefabricatedfromnanograinsofSrTiO3about24nmandSrFe12O19around33nm.ThecrystallitesizesforthenanofibersincreasewithincreasingcalcinationtemperatureandtheadditionofSrTiO3hasanobvioussuppressioneffectonSrFe12O19graingrowth.Thespecificsaturationmagnetizationandremanencetendtoincreasewiththecrystallitesize.Withincreasingcalcinationtemperaturefrom900to1050℃,thecoercivityincreasesinitially,achievingamaximumvalueof520.2kA·m-1at950℃,andthenshowsareductiontendency.
简介:biomagnesium合金被认为由于它的好机械相容性,生物相容性,生物安全和可被细菌破坏的特征是最潜在的可被细菌破坏的金属材料之一。然而,在生理的环境和低机械性质的高降级率的二个主要问题阻止biomagnesium合金的发展。在现在的工作,Mg-Zn-Y-Nd合金的样品被周期的挤出压缩(CEC)和相等的隧道准备尖紧迫(ECAP)。微观结构,合金的机械性质和它在模仿的身体液体(SBF)的腐蚀行为被评估。结果表明那Mg-Zn-Y-Nd合金与测微计尺寸和缩放nano的秒阶段的同类的分发由equiaxial罚款谷物结构组成,它被动态再结晶在ECAP和CEC期间引起。合金的腐蚀抵抗被改进。张力并且腐蚀抵抗被改进,特别处理合金展览制服腐蚀表演和减少的腐蚀评价。这将作为脉管的stent申请为Mg-Zn-Y-Nd合金提供理论地面。